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The paper presents the results of laboratory studies of ammonia sorption from air by fibrous ionexchange materials containing acidic groups in concentration of 3-5 mmoles per gram as a function of the ammonia concentration (3-30 ppm), relative air humidity, air flow rate and the thickness of filtering layer. It follows from our experiments that non-woven fabrics with the thickness of above 2 mm and surface density of -0.3 kg m(-2) can efficiently reduce ammonia concentration in air to <1 ppm at flow rates of <0.2 m s-1. The sorbent can be regenerated with acid solution to obtain salts that can be used as mineral fertilizers.
Czasopismo
Rocznik
Tom
Strony
293--304
Opis fizyczny
bibliogr. 24 poz.
Twórcy
autor
autor
autor
autor
- Lublin University of Technology, Faculty of Environmental Engineering, ul. Nadbystrzycka 40B, 20-618 Lublin, hwasag@wis.pol.lublin.pl
Bibliografia
- [1] BOLTO B.A., PAWLOWSKI L., Wastewater Treatment by Ion Exchange, E. & F.N. Spon, London, 1987.
- [2] Chemical Filters, Technical Bulletin of M+W Zander Ltd, Stuttgart, 2005, Germany, info@mwzander. com
- [3] Clear Air Ltd Smoking Room, Technical Bulletin, Oy Cl;ea Air AB PL55, 07900 Loviisa, Finland, 2001.
- [4] ELINSON I.S., OMELCHENKO T.N., MARTINOVICH V.I., POLIKARPOV A.P., TSIGANKOV V.I., SOLDATOV V.S., Preparation of fibrous carboxylic acid cation exchangers by radiation graft polymerization of acrylic acid into polypropylene fibers, Proceedings of the National Academy of Sciences of Belarus, Chemical Series, 2001, No. 2, 32–37.
- [5] GOSTOMCZYK M.A., Application of ion exchanger resins for air purification, Environmental Protection Engineering, 1977, 1–2, 135–144.
- [6] HASHIDA J., NISHIMURA M., Adsorption of sulfur dioxide by porous ion exchangers, Journal of Chemical Society of Japan, Chemistry and Industrial Chemistry, 1973, No. 6, 1195–1200.
- [7] HAYES E.T., CURRAN T.P., DODD V.A., Odour and ammonia emissions from intensive poultry units in Ireland, Bioresource Technology, 2006, No. 7, 940–948.
- [8] KOKOTOV Y.U.A., ZOLOTAREV P.P., EL’KIN G.E., Theoretical Foundations of Ion Exchange, Leningrad, 1986, Khimia, 105.
- [9] KOSANDROVICH E.H., Sorption of Ammonia and Sulfur Dioxide by Fibrous Ion Exchangers, PhD thesis, Minsk, 2005, Belarus (in Russian).
- [10]MILLS B., Review of methods of odour control, Filtration and Separation, 1995, No. 2, 147–152.
- [11] PEET-SCHWERING C.M.C., Van der AARNINK A.J.A., ROM H.B., DOURMAD J.Y., Ammonia emissions from pig houses in the Netherlands, Denmark and France, Livest. Prod. Scienci., 1999, No. 58, 265–269.
- [12] POLKHOVSKI E.M., SOSINOVICH Z.I., SOLDATOV V.S., Non-exchange sorption of acids by the strong base ion exchanger Dowex 1X8, Proceedings of the National Academy of Sciences of Belarus, Chemical Series, 2003, No. 1, 29–32.
- [13] POLKHOVSKI E.M., SOLDATOV V.S., Non-exchange sorption of electrolytes by ion exchangers: II. Sorption of sulfuric acid and lithium sulfate by Dowex 1X8 resin, Reactive Functional Polymers, 2004, No. 60, 49–54.
- [14] PRIGOZHAEVA L.M., POLIKARPOV A.P., SHUNKEVICH A.A., SOLDATOV V.S., The influence of additives of bi-functional co-monomers on the grafting of acrylic acid into polypropylene fibers, Proceedings of the National Academy of Sciences of Belarus, Chemical Series, 2005, No. 3, 44–49.
- [15] SOLDATOV V.S., ELINSON I.S., SHUNKEVICH A.A., Application of fibrous ion exchangers in air purification from acidic impurities, Proceedings of International Symposium Hydrometallurgy ’94, Chapman & Hall, London, Glasgow, Weinhem, New York, Tokyo, Melbourne, Madras, 1994, 837–855.
- [16] SOLDATOV V.S., ELINSON I.S., SHUNKEVICH A.A., PAWLOWSKI L., WASAG H., Air pollution control with fibrous ion exchangers, [in:] Chemistry for the Protection of the Environment, Pawlowski L., Lacy W.J., Uchrin C., Dudzinska M. (eds.), Plenum Press, New York and London, 1996, No. 2, 55–66.
- [17] SOLDATOV V.S., PAWLOWSKI L., SHUNKEVICH A.A., WASAG H., New Materials and Technologies for Environmental Engineering, Part I. Syntheses and structure of ion exchange fibers, Lublin (Poland), Monographs of the Polish Academy of Sciences, 2004, No. 21, 127.
- [18] SOLDATOV V.S., SERGEEV G.I., MARTSINKEVICH R.V., POKROVSKAYA A.I., SHUNKEVICH A.A., Sorption of copper(II) by fibrous ion exchange material containing groups of substituted 2-imidazoline, Dokl. Akad. Nauk Belar., 1984, No. 28, 1099–1011.
- [19] SOLDATOV V.S., SHUNKEVICH A.A., SERGEEV G.I., Synthesis, structure and properties of new fibrous ion exchangers, Reactive Polymers, 1988, No. 7, 159–172.
- [20] SOLDATOV V.S., TSIGANKOVA A.V., ELINSON I.S., TSIGANKOV V.I., SHUNKEVICH A.A., Chemical, osmotic and cold resistance of strong base fibrous ion exchanger FIBAN A-1, J. Appl. Chem-USSR + 61, 1988, 2465–2473.
- [21] VULIKH A.I., ALOVIAJNIKOV A.A., NIKANDROV G.A., A new area of applications of ion exchangers – gas purification, [in:] Ion Exchange, M.M. Seniavin (ed.), Moscow, 1981, 214–229, (in Russian).
- [22] VULIKH A.I., BOGATYRIOV V.L., ALOVIAJNIKOV A.A., Application of ion exchange resins for absorption and purification of gases, Journal of All-Union Mendeleev Society, 1970, No. 4, 425–429.
- [23] website http://ifoch.bas-net.by 10.07.2007
- [24] YOSHIOKA T., SHIMAMURA M., Studies of polystyrene based ion exchange fiber. I. The preparation and fundamental characteristics of polystyrene based ion exchange fibers, B. Chem. Soc. Jpn., 1983, No. 56, 3726–3729.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW8-0009-0102