Photolytic degradation of 4-tert-octylphenol in aqueous solution

• Autorzy: Błędzka D. , Gryglik D. , Miller J. S.
• Języki publikacji: EN

Abstrakty

EN

4-tert-octylphenol (OP), the endocrine disrupting compound, in aqueous solution was degraded by polychromatic UV lamp. It was found that the rate of OP depletion depends on light intensity, pH of the reaction mixture, initial compound concentration and the presence of natural water constituents. Nitrate addition seemed to give the best results in terms of OP decay rate. The time of 50% OP degradation in the presence of NO3- (2 mg l -1) was about 8 times shorter in comparison to degradation without any additives.

Słowa kluczowe

EN

degradation; 4-tert-octylphenol; decay rate; UV lamps

PL

degradacja; 4-tert-oktylofenol; szybkość rozpadu; lampy UV

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2009
• Tom: Vol. 35, nr 3
• Strony: 235--247
• Opis fizyczny: bibliogr. 26 poz.

Twórcy

autor

Błędzka D.

autor

Gryglik D.

autor

Miller J. S.

• Faculty of Process and Environmental Engineering, Technical University of Łódź, ul. Wólczanska 213, 90-924 Łódz,

Bibliografia

• [1] AHEL M., GIGER W., Aqueous solubility of alkylphenols and alkylphenol polyethoxylates, Chemosphere, 1993a, 26, 1461–70.
• [2] AHEL M., GIGER W., Partitioning of alkylphenols and alkylphenol polyethoxylates between water and organic solvents, Chemosphere, 1993b, 26, 1471–8.
• [3] BERGFALD et al., Co on behalf of the Norwegian Pollution Control Authority, 2005. A study of the priority substances of the Water Framework Directive Monitoring and need for screening, TA-2140/2005, ISBN 82-7655-276-5.
• [4] BLACKBURN M.A., WALDOCK M.J., Concentrations of alkylphenols in rivers and estuaries in England and Wales, Water Research, 1995, Vol. 29, No. 7, 1623–1629.
• [5] BRAND N., MAILHOT G., SARAKHA M., BOLTE M., Primary mechanism in the degradation of 4-octylphenol photoinduced by Fe(III) in water-acetonitrile solution, Journal of Photochemistry and Photobiology A: Chemistry, 2000, 135, 221–228
• [6] CAMPBELL C.G., BORGLIN S.E., GREEN F.B., GRAYSON A., WOZEI E., STRINGFELLOW W.T., Biologically directed environmental monitoring, fate, and transport of estrogenic endocrine disrupting compounds in water: A review, Chemosphere, 2006, 65, 1265–1280.
• [7] FERREIRA-LEACH A.M.R., HILL E.M., Bioconcentration and distribution of 4-tert-octylphenol residues in tissues if the rainbow trout (Oncorhynchus mykiss), Marine Environmental Research, 2001, 51, 75–89.
• [8] GADZAŁA-KOPCIUCH R., FILIPIAK A., BUSZEWSKI B., Isolation, purification and determination of 4-nnonylphenol and 4-tert-octylphenol in aqueous and biological samples, Talanta, 2008, 74, 655–660.
• [9] GIBS J., STACKELBERG P.E., FURLONG E.T., MEYER M., ZAUGG S.D., LEE LIPPINCOTT R., Persistence of pharmaceuticals and other organic compounds in chlorinated drinking water as a function of time, Science of the Total Environment, 2007, 373, 240–249.
• [10] JOHNSON A.C., WHITE C., BHARDWAJ L., JURGENS M.D., Environmental chemistry – potential for octylphenol to biodegrade in some English rivers, Environmental Toxicology and Chemistry, 2000, 19(10), 2486–2492.
• [11] LINTERMANN J., KATAYAMA A., KURIHARA N., SHORE L., WENZEL A., Endocrine disruptors in the environment. (IUPAC Technical Report), Pure Applied Chemistry, 2003, Vol. 75, No. 5, 631–681.
• [12]MACK J., BOLTON J.R., Photochemistry of nitrite and nitrate in aqueous solution: a review. Journal of Photochemistry and Photobiology A: Chemistry, 1999, 128, 1–13.
• [13]MAZALLIER P., LEVERD J., Transformation of 4-tert-octylphenol by UV irradiation and by an H2O2/UV process in aqueous solution, Photochemistry & Photobiology Science, 2003, 2, 946– 953.
• [14]MILLER J.S., OLEJNIK D., Photolysis of polycyclic aromatic hydrocarbons in water, Water Research, 2001, Vol. 35, No. 1, 233–243.
• [15]MUROV S.L., CARMICHAEL I., HUG G.L., Handbook of Photochemistry, 2nd ed. Dekker, 1993.
• [16] NEAMTU M., FRIMMEL F.H., Photodegradation of endocrine disrupting chemical nonylphenol by simulated solar UV-irradiation, Science of the Total Environment, 2006, 369, 295–306.
• [17] NING B., GRAHAM N.J.D., ZHANG Y., Degradation of octylphenol and nonylphenol by ozone – Part I: Direct reaction, Chemosphere, 2007a, 68, 1163–1172.
• [18] NING B., GRAHAM N.J.D., ZHANG Y., Degradation of octylphenol and nonylphenol by ozone – Part II: Indirect reaction, Chemosphere, 2007b, 68, 1173–1179.
• [19] NOMURA S., DAIDOJI T., INOUE H., YOKOTA H., Differential metabolism of 4-n- and 4-tertoctylphenol in perfused rat liver, Life Sciences, 2008, 83, 223–228.
• [20] OECD, 2000. OECD Guideline for testing chemicals. Phototransformation of Chemicals in Water – Direct and Indirect Photolysis. (www.oecd.org)
• [21] OSPAR Commission, 2006 Update. Hazardous Substances Series: Octylphenol. Background document on octylphenol. Publication Number: 273/2006 (www.ospar.org)
• [22] POPA A., NEAMTU M., FRIMMEL F.H., Photodegradation of octylphenol using simulated sunlight radiation, Acta Universitatis Cibiniensis Series E: Food Technology, 2007, Vol. XI, No.2.
• [23] UNEP Publications, 1995. Phenol, 4-(1,1,3,3-tetramethylbutyl)- CAS N°: 140-66-9. OECD SIDS Initial Assessment Report (www.inchem.org)
• [24] QUEDNOW K., PUTTMANN W., Endocrine disruptors in freshwater streams of Hesse, Germany: Changes in concentration levels in the time span from 2003 to 2005, Environmental Pollution, 2008, 152, 476–483.
• [25] YAMAZAKI S., MORI T., KATOU T., SUGIHARA M., Photocatalytic degradation of 4-tert-octylphenol in water and the effect of peroxydisulfate as additives, Journal of Photochemistry and Photobiology A: Chemistry, 2008, 199, 330–335.
• [26] YING G., WILLIAMS B., KOOKANA R., Environmental fate of alkylphenols and alkylphenol ethoxylates – a review, Environment International, 2002, 28, 215– 226.