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The effectiveness of the advanced oxidation process (UV/H2O2) in decolorizing real textile wastewater polluted with commercial reactive dyes - Reactive Yellow 84 and Reactive Red 141 - was investigated. All the experiments were performed in a lab-scale reactor with the original high pH of the wastewater. The dyeing wastewater was decolorized in 5 hours. After its acidification to pH 3 the decolorization process was more efficient. Full decolorization was then achieved in 2 hours and the decrease in COD exceeded 70%. The reaction rate constants obtained were as follows: at pH 11.4, 0.0065 min(-1); at pH 7, 0.0044 min(-1), and at pH 3, 0.019 min(-1), which testified to pH importance for UV/H2O2 oxidation process.
Czasopismo
Rocznik
Tom
Strony
167--178
Opis fizyczny
bibliogr. 24 poz.
Twórcy
autor
autor
autor
- Department of Water Management, Vilnius Gediminas Technical University, Lithuania, Justina.Racyte@ap.vgtu.Lt
Bibliografia
- [1] ALATON I.A., BALCIOGLU I.A., Advanced oxidation of raw and biotreated textile industry wastewater with O3, H2O2/UV–C and their sequential application, Journal of Chemical Technology & Biotechnology, 2001, Vol. 76, Issue 1, 53–60.
- [2] ALATON I.A., BALCIOGLU I.A., BAHNEMANN D.W., Advanced oxidation of a reactive dyebath effluent: comparison of O3, H2O2/UV–C and TiO2/UV–A processes, Water Research, 2002, Vol. 36, 1143–1154.
- [3] APHA, Standard methods for the examination of water and wastewater, 19th edition, American Public Health Association, Washington, D.C., 1995.
- [4] ARSLAN I., BALCIOGLU I.A., BAHNEMANN D.W., Advanced chemical oxidation of reactive dyes in simulated dyehouse effluents by ferrioxalate – Fenton/ UV–A and TiO2 /UV-A processes, Dyes and Pigments, 2000, Vol. 47, 207–218.
- [5] AZBAR N., YONAR T., KESTIOĞLU K., Comparison of various advanced oxidation processes and chemical treatment methods for COD and color removal from a polyester and acetate fibber dyeing effuent, Chemosphere, 2004, Vol. 55, 35–43.
- [6] BLACKBURN R.S., BURKINSHAW S.M., A greener approach to cotton dyeing with excellent wash fastness, Green Chemistry, 2002, Vol. 4, Issue 1, 47–52.
- [7] Color index. Society of dyer and colorists’ publication, Bradford, England. Revised 3rd edn., 1976, 6073–6101.
- [8] FELIS E., ALDER A.C., SURMACZ-GÓRSKA J., MIKSCH K., Advanced oxidation of the polycyclic musk fragrances with using UV and UV/H2O2 processes, Archives of Environmental Protection, 2008, Vol. 34, No 1.
- [9] GALINDO C., KLAT A., UV- H2O2 oxidation of monoazo dyes in aqueous media: a kinetic study, Dyes and Pigments, 1998, Vol. 40, 27–5.
- [10] GULTEKIN I., INCE N.H., Degradation of reactive azo dyes by UV/H2O2: Impact of radical scavengers, Journal of Environmental Science and Health, 2004, Vol. 39, Issue 4, 1069–1081.
- [11] INCE N.H., HASAN D.A., ÜSTÜN B., TEZCANLI G., Combinative dyebath treatment with activated carbon and UV/H2O2: a case study on Everzol Black-GSP, Water Science and Technology, 2002, Vol. 46, Issue 4–5, 51–58.
- [12] KANG W.Y., CHO M.-J., HWANG K.-Y., Correction of hydrogen peroxide interference on standard chemical oxygen demand test, Water Research, 1999, Vol. 33, Issue – 5, 1247–125.
- [13] KURBUS T., SLOKAR Y.M., LE MARECHAL A.M., VONCINA D.B., The use of experimental design for the evaluation of the influence of variables on the H2O2/UV treatment of model textile wastewater, Dyes and Pigments, 2003, Vol. 58, Issue 2, 171–178.
- [15] KUSIC H., KOPRIVANAC N., LONCARIC-BOZIC A., PAPIC S., PETERNEL I., VUJEVIC D., Reactive dye degradation by AOPs; development of a kinetic model for UV/H2O2 process, Chem. Biochem. Eng., 2006, Vol. 20, Issue 3, 293–300.
- [16] KUSVURAN E., IRMAK S., YAVUZ H.I., SAMIL A., ERBATUR O., Comparison of the treatment methods efficiency for decolorization and mineralization of Reactive Black 5 azo dye, Journal of Hazardous Materials, 2005, Volume B119, 109–116.
- [17]MALIK P.K., SANYAL S.K., Kinetics of decolourisation of azo dyes in wastewater by UV/H2O2 process, Separation and Purification Technology, 2004, Vol. 36, 167–175.
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- [19]MURUGANANDHAM M., SWAMINATHAN M., Advanced oxidative decolourisation of Reactive Yellow 14 azo dye by UV/TiO2, UV/H2O2, UV/H2O2/Fe2 processes, Separation and Purification Technology, 2006, Vol. 48, 297–303.
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- [22] RAJKUMAR D., KIM J.G., Oxidation of various reactive dyes with in situ electro – generated active chlorine for textile dyeing industry wastewater treatment, Journal of Hazardous Materials, 2006, Vol. 136, 203–212.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW8-0009-0092