Heavy metal glasses and transparent glass-ceramics: preparation, local structure and optical properties

• Autorzy: Pisarska J. , Goryczka T. , Zur L. , Pisarski W. A.
• Języki publikacji: PL

Abstrakty

EN

Heavy metal oxide and oxyfluoride lead silicate glasses doped with rare-earth ions were prepared. Next, they were heat treated in order to obtain transparent glass-ceramics. The rare-earths as optically active ions were limited to trivalent Eu3+ and Dy3+. Correlation between the local structure and the luminescence properties of Eu3+ and Dy3+ ions in the studied glass and glass-ceramic systems was examined using X-ray diffraction, FT-IR and optical measurements. Especially, the ratio of integrated emission intensity of the 5D0-7F2 transition to that of the 5D0-7F1 transition of Eu3+, defined as the luminescence intensity ratio R (Eu3+) as well as the ratio of integrated emission intensity of the 4F9/2-6H13/2 transition to that of the 4F9/2-6H15/2 transition of Dy3+, defined as the luminescence intensity ratio Y/B (Dy3+), have been analyzed in details. Their values are reduced due to part incorporation of rare-earth ions into cubic ?-PbF2 crystalline phase. The excitation and luminescence spectra of rare-earth ions in glass samples before and after heat treatment are presented and discussed in relation to potential application in optoelectronics.

Słowa kluczowe

EN

heavy metal glasses; glass-ceramics; heat treatment; rare-earth ions; luminescence

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2012
• Tom: Vol. 42, nr 2
• Strony: 381--386
• Opis fizyczny: Bibliogr. 16 poz.

Twórcy

autor

Pisarska J.

autor

Goryczka T.

autor

Zur L.

autor

Pisarski W. A.

• University of Silesia, Institute of Chemistry, Szkolna 9, 40-007 Katowice, Poland

Bibliografia

• [1] BETTINELLI M., SPEGHINI A., BRIK M.G., Spectroscopic studies of emission and absorption properties of 38PbO–62SiO2:Nd 3+ glass, Optical Materials 32(12), 2010, pp. 1592–1596.
• [2] CAPOBIANCO J.A., PREVOST G., PROULX P.P., KABRO P., BETTINELLI M., Upconversion properties of Er3+ doped lead silicate glasses, Optical Materials 6(3), 1996, pp. 175–184.
• [3] KARMAKAR B., DWIVEDI R.N., FT-IRRS, UV–Vis–NIR absorption and green upconversion in Er3+doped lead silicate glass, Journal of Non-Crystalline Solids 342(1–3), 2004, pp. 132–139.
• [4] WANG J., REEKIE L., BROCKLESBY W.S., CHOW Y.T., PAYNE D.N., Fabrication, spectroscopy and laser performance of Nd 3+-doped lead-silicate glass fibers, Journal of Non-Crystalline Solids 180(2–3), 1995, pp. 207–216.
• [5] FANQING ZENG, GUOZHONG REN, XIANNIAN QIU, QIBIN YANG, JINGWU CHEN, The effect of PbF2 content on the microstructure and upconversion luminescence of Er3+-doped SiO2–PbF2–PbO glass ceramics, Journal of Non-Crystalline Solids 354(29), 2008, pp. 3428–3432.
• [6] TIKHOMIROV V.K., FURNISS D., SEDDON A.B., REANEY I.M., BEGGIORA M., FERRARI M., MONTAGNA M., ROLLI R., Fabrication and characterization of nanoscale, Er3+-doped, ultratransparent oxy-fluoride glass ceramics, Applied Physics Letters 81(11), 2002, pp. 1937–1939.
• [7] GONZALEZ-PEREZ S., MARTIN I.R., JAQUE D., HARO-GONZALEZ P., CAPUJ N., Control of the local devitrification on oxyfluoride glass doped with Er3+ ions under diode laser irradiation, Journal of Applied Physics 108(10), 2010, article 103103.
• [8] PISARSKI W.A., PISARSKA J., DOMINIAK-DZIK G., RYBA-ROMANOWSKI W., Transition metal (Cr3+) and rare earth ions (Eu3+, Dy3+) used as a spectroscopic probe in compositional-dependent lead borate glasses, Journal of Alloys and Compounds 484(1–2), 2009 pp. 45–49.
• [9] PISARSKA J., ŻUR L., PISARSKI W.A., Transparent glass-ceramics containing Eu3+ and Dy3+ ions for visible optoelectronics, Proceedings of SPIE 8010, 2011, article 80100N.
• [10] FELLER S., LODDEN G., RILEY A., EDWARDS T., CROSKREY J., SCHUE A., LISS D., STENTZ D., BLAIR S.,KELLEY M., SMITH G., SINGLETON S., AFFATIGATO M., HOLLAND D., SMITH M.E., KAMITSOS E.I., VARSAMIS C.P.E., IOANNOU E., A multispectroscopic structural study of lead silicate glasses over an extended range of compositions, Journal of Non-Crystalline Solids 356(6–8), 2010, pp. 304–313.
• [11] DRIESEN K., TIKHOMIROV V.K., GORLLER-WALRAND C., Eu3+ as a probe for rare-earth dopant site structure in nano-glass-ceramics, Journal of Applied Physics 102(2), 2007, article 024312.
• [12] DALIANG ZHAO, XVSHENG QIAO, XIANPING FAN, MINQUAN WANG, Local vibration around rare earth ions in SiO2–PbF2 glass and glass ceramics using Eu3+ probe, Physica B 395(1–2), 2007, pp. 10–15.
• [13] BUENO L.A., GOUVEIA-NETO A.S., DA COSTA E.B., MESSADDEQ Y., RIBEIRO S.J.L., Structural and spectroscopic study of oxyfluoride glasses and glass-ceramics using europium ion as a structural probe, Journal of Physics: Condensed Matter 20(14), 2008, article 145201.
• [14] BABU P., KYOUNG HYUK JANG, EUN SIK KIM, LIANG SHI, HYO JIN SEO, RIVERA-LOPEZ F., RODRIGUEZ--MENDOZA U.R., LAVIN V., VIJAYA R., JAYASANKAR C.K., RAMA MOORTHY L., Spectral investigations on Dy3+-doped transparent oxyfluoride glasses and nanocrystalline glass ceramics, Journal of Applied Physics 105(1), 2009, article 013516.
• [15] BABU P., KYOUNG HYUK JANG, EUN SIK KIM, LIANG SHI, VIJAYA R., LAVIN V., JAYASANKAR C.K., HYO JIN SEO, Optical properties and energy transfer of Dy3+-doped transparent oxyfluoride glasses and glass-ceramics, Journal of Non-Crystalline Solids 356(4–5), 2010, pp. 236–243.
• [16] PISARSKA J., ŻUR L., PISARSKI W.A., Optical spectroscopy of Dy3+ ions in heavy metal lead-based glasses and glass-ceramics, Journal of Molecular Structure 993(1–3), 2011, pp. 160–166.