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Heavy metal lead borate glasses doped with rare earth ions were examined. The influence of heavy metal oxide PbO and activator concentration on luminescence properties of rare earth ions are discussed. Rare earth ions were limited to Eu3+, Dy3+ and Tb3+ which are emitting in the visible light. Increasing concentration of lead oxide in relation to boron oxide causes an increase in R (Eu3+), Y/B (Dy3+) and G/B (Tb3+) spectroscopic factors which correspond to the relative integrated luminescence intensities of 5D0-7F2/5D0-7F1, 4F9/2-6H13/2/4F9/2-6H15/2 and 5D4-7F5/5D4-7F6 transitions, respectively. Moreover, the influence of heavy metal oxide and activator concentration on luminescence decays from excited states of rare earth ions was examined in details.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
345--352
Opis fizyczny
Bibliogr. 20 poz.
Twórcy
autor
autor
autor
- University of Silesia, Institute of Chemistry, Szkolna 9, 40-007 Katowice, Poland
Bibliografia
- [1] NACHIMUTHU P., VITHAL M., JAGANNATHAN R., Absorption and emission spectral properties of Pr3+,Nd3+, and Eu3+ ions in heavy-metal oxide glasses, Journal of the American Ceramic Society 83(3), 2000, pp. 597–604.
- [2] KASSAB L.R.P., COURROL L.C., MORAIS A.S., MENDES C.M.S.P., TATUMI S.H., WETTER N.U., GOMES L., SALVADOR V.L.R., Spectroscopic properties of lead fluoroborate and heavy metal oxide glasses doped with Yb3+, Journal of Non-Crystalline Solids 304(1–3), 2002, pp. 233–237.
- [3] COURROL L.C., KASSAB L.R.P., FUKUMOTO M.E., WETTER N.U., TATUMI S.H., MORIMOTO N.I., Spectroscopic properties of heavy metal oxide glasses doped with erbium, Journal of Luminescence 102–103, 2003, pp. 91–95.
- [4] CASCALES C., BALDA R., FERNANDEZ J., ARRIANDIAGA M.A., FDEZ-NAVARRO J.M., Site selective spectroscopy of Eu3+ in heavy-metal oxide glasses, Journal of Non-Crystalline Solids 352(23–25), 2006, pp. 2448–2451.
- [5] PISARSKI W.A., PISARSKA J., LISIECKI R., GROBELNY Ł., DOMINIAK-DZIK G., RYBA-ROMANOWSKI W., Erbium-doped oxide and oxyhalide lead borate glasses for near-infrared broadband optical amplifiers, Chemical Physics Letters 472(4–6), 2009, pp. 217–219.
- [6] PISARSKI W.A., PISARSKA J., RYBA-ROMANOWSKI W., Structural role of rare earth ions in lead borate glasses evidenced by infrared spectroscopy: BO3 ↔BO4 conversion, Journal of Molecular Structure 744–747, 2005, pp. 515–520.
- [7] PISARSKA J., LISIECKI R., DOMINIAK-DZIK G., RYBA-ROMANOWSKI W., GORYCZKA T., GROBELNY Ł., PISARSKI W.A., Influence of PbX2 (X = F, Cl, Br) content and thermal treatment on structure and optical properties of lead borate glasses doped with rare earth ions, Optica Applicata 40(2), 2010, pp. 351–358.
- [8] JAYASANKAR C.K., VENKATRAMU V., SURENDRA BABU S., BABU P., Luminescence properties of Dy3+ ions in a variety of borate and fluoroborate glasses containing lithium, zinc, and lead, Journal of Alloys and Compounds 374(1–2), 2004, pp. 22–26.
- [9] LAKSHMINARAYANA G., BUDDHUDU S., Spectral analysis of Sm3+ and Dy3+:B2O3–ZnO–PbO glasses, Physica B: Condensed Matter 373(1), 2006, pp. 100–106.
- [10] PISARSKA J., Optical properties of lead borate glasses containing Dy3+ ions, Journal of Physics: Condensed Matter 21(28), 2009, article 285101.
- [11] PISARSKA J., ŻUR L., PISARSKI W.A., Visible luminescence of dysprosium ions in oxyhalide lead borate glasses, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 79(4), 2011, pp. 705–707.
- [12] VENKATRAMU V., NAVARRO-URRIOS D., BABU P., JAYASANKAR C.K., LAVIN V., Fluorescence line narrowing spectral studies of Eu3+-doped lead borate glass, Journal of Non-Crystalline Solids 351(10–11), 2005, pp. 929–935.
- [13] VENKATRAMU V., BABU P., JAYASANKAR C.K., Fluorescence properties of Eu3+ ions doped borate and fluoroborate glasses containing lithium, zinc and lead, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 63(2), 2006, pp. 276–281.
- [14] THULASIRAMUDU A., BUDDHUDU S., Optical characterization of Eu3+ and Tb3+ ion doped zinc lead borate glasses, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 66(2), 2007, pp. 323–328.
- [15] LAKSHMINARAYANA G., BUDDHUDU S., Spectral analysis of Eu3+ and Tb3+:B2O3–ZnO–PbO glasses, Materials Chemistry and Physics 102(2–3), 2007, pp. 181–186.
- [16] JAMALAIAH B.C., SURESH KUMAR J., MOHAN BABU A., SASIKALA T., RAMA MOORTHY L., Study on spectroscopic and fluorescence properties of Tb3+-doped LBTAF glasses, Physica B: Condensed Matter 404(14–15), 2009, pp. 2020–2024.
- [17] PISARSKA J., Borate glasses with PbO and PbCl2 containing Dy3+ ions, Optica Applicata 40(2), 2010, pp. 367–374.
- [18] PISARSKI W.A., Thermal stability and concentration effect in erbium-doped lead fluoroborate glasses, Journal of Materials Science: Materials in Electronics 17(4), 2006, pp. 245–249.
- [19] PISARSKA J., PISARSKI W.A., RYBA-ROMANOWSKI W., Laser spectroscopy of Nd3+ and Dy3+ ions in lead borate glasses, Optics and Laser Technology 42(5), 2010, pp. 805–809.
- [20] DUHAMEL-HENRY N., ADAM J.L., JACQUIER B., LINARES C., Photoluminescence of new fluorophosphate glasses containing a high concentration of terbium (III) ions, Optical Materials 5(3), 1996, pp. 197–207.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0023-0020