Synthesis, spectroscopy and magnetic properties of transition-metal complexes with aminophosphonate derivatives of pyridine

Żurowska, B.; Boduszek, B.

Artykuł - szczegóły

Tytuł artykułu

Synthesis, spectroscopy and magnetic properties of transition-metal complexes with aminophosphonate derivatives of pyridine

Autorzy

Żurowska B. , Boduszek B.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

The compounds of general formula [ML2](ClO4)2 [M = Cu(II), Ni(II), Co(II)]; L = diethyl 3-pyridylmethyl[N-(butyl)amino]phosphonate (3-pmape) or diethyl 4-pyridylmethyl[N-(butyl)amino]phosphonate (4-pmape) were prepared. The new complexes were identified and characterized by elemental analysis, infrared, electronic spectral studies and magnetic measurements. The complexes are sixcoordinate. Metal ions are octahedrally surrounded by two pyridine and two amine nitrogens, and two oxygens of the phosphoryl groups. The results of the magnetic studies suggest polymeric chain structure of the above complexes and indicate weak antiferromagnetic interaction between the magnetic centers. The magnetic behavior of Co(II) complexes is characteristic for cobalt(II) system with an important orbital contribution via spin-orbit coupling.

Słowa kluczowe

aminophosphonate ligand transition metal complexes spectroscopy magnetism

Wydawca

De Gruyter

Czasopismo

Materials Science Poland

Rocznik

2011

Tom

Vol. 29, No. 2

Strony

105--111

Opis fizyczny

Bibliogr. 52 poz.

Twórcy

autor

Żurowska B.

autor

Boduszek B.

Faculty of Chemistry University of Wrocław 14 F. Joliot-Curie St. 50-383 Wrocław Poland

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BPW7-0019-0059