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Optical properties of SiO2/TiO2 thin layers prepared by sol-gel method

Wybrane pełne teksty z tego czasopisma
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Języki publikacji
EN
Abstrakty
EN
In this investigation, SiO2/TiO2 thin films were prepared on glass and quartz glass substrates by dip coating sol-gel technique. The films were calcinated at 500 °C for 1 hour. Thickness of the films was estimated by ellipsometric measurements and it was in the range from about 30 nm to 700 nm. Refractive index of the films was also established. Chemical composition of the samples was studied by photoelectron spectroscopy. Transmittances of the samples were characterized using UV-VIS spectrophotometer. Subsequently, band gap energy (Eg) was estimated for these films. It was found that band gap energy increases with thickness of the films and their value depends on sodium diffusing from glass substrate.
Słowa kluczowe
Czasopismo
Rocznik
Strony
979--987
Opis fizyczny
Bibliogr. 20 poz.
Twórcy
autor
autor
autor
  • AGH - University of Science and Technology, Department of Material Science and Ceramic, 30-059 Kraków, al. Mickiewicza 30, Poland,
Bibliografia
  • [1] TURNER R.H., BOERIO F.J., Molecular structure of interfaces formed with plasma-polymerized silica-like primer films: Part III. Mechanical strength and environmental durability of the primer/aluminum and primer/titanium interfaces, The Journal of Adhesion 78(6), 2002, pp. 495–504.
  • [2] NOGE S., UNO T., SHIMOTORI H., FUJITSUKA S., Behavior of metal-doped silica thin films with artificial-lattice structure B: Luminescence, Ferroelectrics 338(1), 2006, pp. 225–232.
  • [3] VAN POPTA A.C., CHENG J., SIT J.C., BRETT M.J., Birefringence enhancement in annealed TiO2 thin films, Journal of Applied Physics 102, 2007, p. 013517.
  • [4] ZHANG X., ZHENG H., Synthesis of TiO2-doped SiO2 composite films and its applications, Bulletin of Materials Science 31(5), 2008, pp. 787–790.
  • [5] YAMASHITA H., NISHIO S., IMAOKA S., SHIMADA M., MORI K., TANAKA T., NISHIYAMA N., Photo-induced surface property on transparent mesoporous silica thin films containing single-site photocatalyst, Topics in Catalysis 47(3–4), 2008, pp. 116–121.
  • [6] FALARAS P., XAGAS A.P., Roughness and fractality of nanostructured TiO2 films prepared via sol–gel technique, Journal of Material Science 37(18), 2002, pp. 3855–3860.
  • [7] NAGAI H., AOYAMA S., HARA H., MOCHIZUKI CH., TANAKO I., BABA N., SATO M., Rutile thin film responsive to visible light and with high UV light sensitivity, Journal of Material Science 44(3), 2009, pp. 861–868.
  • [8] WANG C.M., LIN S.Y., Electrochromic properties of sputtered TiO2 thin films, Journal of Solid State Electrochemistry 10(4), 2006, pp. 255–259.
  • [9] WON D.-J., WANG C.-H., JANG H.-K., CHOI D.-J., Effects of thermally induced anatase-to-rutile phase transition in MOCVD-grown TiO2 films on structural and optical properties, Applied Physics A 73(5), 2001, pp. 595–600.
  • [10] TERJO-VALDEZ M., JENOUVRIER P., FICK J., LANGLET M., Characterization of optically active and photocurable ORMOSIL thin films deposited using the Aerosol process, Journal of Material Science 39(8), 2004, pp. 2801–2810.
  • [11] STIR M., NICULA R., BURKEL E., Pressure–temperature phase diagrams of pure and Ag-doped nanocrystalline TiO2 photocatalysts, Journal of the European Ceramic Society 26(9), 2006,pp. 1547–1553.
  • [12] TIAN X.B., WANG Z.M., YANG S.Q., LUO Z.J., FU R.K.Y., CHU P.K., Antibacterial copper-containing titanium nitride films produced by dual magnetron sputtering, Surface and Coatings Technology 201(19–20), 2007, pp. 8606– 8609.Optical properties of SiO2/ TiO2 thin layers... 987
  • [13] ZHANG H.J., WEN D.Z., Antibacterial properties of Sb–TiO2 thin films by RF magnetron co-sputtering, Surface and Coatings Technology 201(9–11), 2007, pp. 5720– 5723.
  • [14] ANPO M., NAKAYA H., KODAMA S., KUBOKAWA Y., DOMEN K., ONISHI T., Photocatalysis over binary metal oxides. Enhancement of the photocatalytic activity of titanium dioxide in titanium–silicon oxides, Journal of Chemical Physics 90, 1986, pp. 1633–1636.
  • [15] WAGNER C.D., RIGGS W.M., DAVIS L.E., MOULDER J.F., MUILENBERG G.E., [In] Handbook of X-Ray Photoelectron Spectroscopy, Perkin-Elmer, 1976.
  • [16] LEI GE, MINGXIA XU, Fabrication and characterization of TiO2 photocatalytic thin film prepared from peroxo titanic acid sol, Journal of Sol-Gel Science and Technology 43(1), 2007, pp. 1– 7.
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  • [18] MEI F., LIU C., ZHANG L., REN F., ZHOU L., ZHAO W.K., FANG Y.L., Microstructural study of binary TiO2 :SiO2 nanocrystalline thin films, Journal of Crystal Growth 292(1), 2006, pp. 87–91.
  • [19] NURDIWIJAYANTO L., PURWASASMITA B.S., Optical properties of (100) preferred oriented titanium--doped zinc oxide thin films and their electron trapping phenomena, Journal of Materials Science and Engineering, November 4(11), 2010, serial no. 36.
  • [20] VISWANATH R.N., RAMASAMY S., Study of TiO2 nanocrystallites in TiO2–SiO2 composites, Colloids and Surfaces A 133(1–2), 1998, pp. 49–56.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0019-0056
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