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Luminescence of doped CdS nanocrystals: effect of doping and capping agent

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Cu and Fe doped cadmium sulfide nanoparticles were prepared with a wet chemical synthesis by mixing the reactants in double distilled water solvent. Thioglycerol (TG) was employed as the capping agent and also the reaction catalyst. The estimated particle size of prepared samples was found in the range 3-4 nm. Properties of particles were investigated using photoluminescence spectroscopy (PL) and X-ray diffraction analysis (XRD). XRD pattern of samples reveals a hexagonal crystal structure at room temperature. We have studied effect of doping and TG concentration on the luminescence of doped CdS nanocrystals. There is a noticeable increase of the PL intensity when TG concentration increased. The PL spectra include two bands, due to emission of traps and surface state.
Czasopismo
Rocznik
Strony
921--928
Opis fizyczny
Bibliogr. 25 poz.
Twórcy
  • Department of Physics, Faculty of Science, Islamic Azad University, Takestan Branch, Takestan, Iran
Bibliografia
  • [1] MURAI H., ABE T., MATSUDA J., SATO H., CHIBA S., KASHIWABA Y., Improvement in the light emission characteristics of CdS:Cu/CdS diodes, Applied Surface Science 244(1–4), 2005, pp. 351–354.
  • [2] GRUS M., SIKORSKA A., Characterization of the absorption edge in crystalline CdS:Cu powder by use of photoacoustic and reflection spectroscopy, Physica B 266(3), 1999, pp. 139–145.
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  • [6] SARKAR R., TIWARY C.S., KUMBHAKAR P., BASU S., MITRA A.K., Yellow-orange light emission from Mn2+-doped ZnS nanoparticles, Physica E 40(10), 2008, pp. 3115–3120.
  • [7] CRUZ A.B., SHEN Q., TOYODA T., Studies on the effect of UV irradiation on Mn-doped ZnS nanoparticles , Materials Science and Engineering C 25(5–8), 2005, pp. 761–765.
  • [8] DENZLER D., OLSCHEWSKI M., SATTLER K., Luminescence studies of localized gap states in colloidal ZnS nanocrystals, Journal of Applied Physics 84(5), 1998, pp. 2841–2845.
  • [9] KEZUKA T., KONISHI M., ISOBE T., SENNA M., Preparation and properties of nanocrystalline ZnS:Mn-polymer composite films, Journal of Luminescence 87–89, 2000, pp. 418–420.
  • [10] FELTIN N., LEVI L., INGERT D., PILENI M.P., Magnetic properties of 4-nm Cd1–y MnyS nanoparticlesdiffering by their compositions, y, Journal of Physical Chemistry B 103(1), 1999, pp. 4–10.
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  • [12] LEVY L., FELTIN N., INGERT D., PILENI M.P., Three dimensionally diluted magnetic semiconductor clusters Cd1–y MnyS with a range of sizes and compositions: Dependence of spectroscopic properties on the synthesis mode, Journal of Physical Chemistry B 101(45), 1997, pp. 9153–9160.
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  • [16] CHESTNOY N., HARRIS T.D., HULL R., BRUS L.E., Luminescence and photophysics of cadmium sulfide semiconductor clusters: The nature of the emitting electronic state, Journal of Physical Chemistry 90(15), 1986, pp. 3393–3399.
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  • [20] YOUSEFI M.H., KHOSRAVI A.A., RAHIMI K., NAZESH A., Comparing the luminescence of ZnS:Mn/CdS:Mn quantum dots, The European Physical Journal – Applied Physics 45(1), 2009, pp. 10602–10605.
  • [21] MARANDI M., TAGHAVINIA N., SEDAGHAT Z., IRAJI ZAD A., MAHDAVI S.M., Thermochemical growth of Mn-doped CdS nanoparticles and study of luminescence evolution, Nanotechnology 19(22), 2008, p. 225705.
  • [22] NANDA K.K., SAHU S.N., Photoluminescence of CdS nanocrystals: Effect of ageing, Solid State Communications 111(12), 1999, pp. 671–674.
  • [23] UNNI C., PHILIP D., GOPCHANDRAN K.G., Studies on optical absorption and photoluminescence of thioglycerol-stabilized CdS quantum dots, Spectrochimica Acta, Part A 71(4), 2008, pp. 1402–1407.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0019-0050
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