Coordination properties of diethyl (pyridyn-2-ylmethyl)phoshate ligand with chloride transition metal salts

Żurowska, B.; Kalinowska-Lis, U.; Ochocki, J.

Artykuł - szczegóły

Tytuł artykułu

Coordination properties of diethyl (pyridyn-2-ylmethyl)phoshate ligand with chloride transition metal salts

Autorzy

Żurowska B. , Kalinowska-Lis U. , Ochocki J.

Wybrane pełne teksty z tego czasopisma

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Języki publikacji

Abstrakty

A new series of chloride transition metal complexes containing a diethyl (pyridyn-2-ylmethyl) phosphate (2-pmOpe) ligand, of the general formula [M(2-pmOpe)2Cl2] (M = Cu, Ni, Mn) and [M(2-pmOpe)Cl2] (M = Co, Zn), were synthesized and studied. The stoichiometry and stereochemistry of the compounds were confirmed by elemental analysis, spectroscopic and magnetic studies. The ligand containing two donor atoms, heterocyclic pyridyl nitrogen and phosphoryl oxygen atoms, binds in a didentate chelate manner in all complexes. The octahedral (Cu, Ni, Mn) and tetrahedral (Co, Zn) coordination sphere complete chloride ions included in coordination. The magnetic behaviour (for paramagnetic centres) and spectroscopic analyses of the complexes indicate a mononuclear structure and suggest existence of a very weak exchange coupling between the metal centres in the crystal lattice.

Słowa kluczowe

transition metal complexes N,O-donor ligand spectroscopy magnetism

Wydawca

De Gruyter

Czasopismo

Materials Science Poland

Rocznik

2010

Tom

Vol. 28, No. 3

Strony

749--755

Opis fizyczny

Bibliogr, 40 poz.

Twórcy

autor

Żurowska B.

autor

Kalinowska-Lis U.

autor

Ochocki J.

Faculty of Chemistry University of Wroclaw 14 F. Joliot- Curie St. 50-383 Wroclaw Poland

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BPW7-0014-0062