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Oxychloroborate glasses containing Dy3+ ions in the B2O3–PbCl2–PbO–Al2O3–WO3 system were studied using X-ray diffraction, Raman, FT-IR, absorption, excitation and luminescence spectroscopy. The results concerning glass preparation, short-range order structure and optical properties are reported. X-ray diffraction analysis evidently indicates that the fully amorphous system was prepared. Coexistence of trigonal BO3 and tetrahedral BO4 units was evidenced by Raman and FT-IR spectroscopy. The electronic states belonging to the 4f9 configuration of trivalent Dy3+ were determined from the absorption and excitation spectra. The luminescence bands at 480, 573 and 662 nm were registered in oxychloride glasses, which correspond to transitions originating from the 4F9/2 state to the 6HJ/2 (J = 11, 13, 15) states of Dy3+.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
367--374
Opis fizyczny
Bibliogr. 24 poz.
Twórcy
autor
- University of Silesia, Institute of Chemistry, Szkolna 9, 40-007 Katowice, Poland
Bibliografia
- [1] JAYASANKAR C.K., RUKMINI E., Spectroscopic investigations of Dy3+ ions in borosulphate glasses, Physica B: Condensed Matter 240(3), 1997, pp. 273–288.
- [2] TANABE S., KANG J., HANADA T., SOGA N., Yellow/blue luminescences of Dy3+-doped borate glasses and their anomalous temperature variations, Journal of Non-Crystalline Solids 239(1–3), 1998, pp. 170–175.
- [3] BABU P., JAYASANKAR C.K., Spectroscopic properties of Dy3+ ions in lithium borate and lithium fluoroborate glasses, Optical Materials 15(1), 2000, pp. 65–79.
- [4] SRIVASTAVA P., RAI S.B., RAI D.K., Optical properties of Dy3+ doped calibo glass on addition of lead oxide, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 59(14), 2003, pp. 3303–33111.
- [5] JAYASANKAR C.K., VENKATRAMU V., SURENDRA BABU S., BABU P., Luminescence properties of Dy3+ions in a variety of borate and fluoroborate glasses containing lithium, zinc, and lead, Journal of Alloys and Compounds 374(1–2), 2004, pp. 22–26.
- [6] MAHATO K.K., RAI A., RAI S.B., Optical properties of Dy3+ doped in oxyfluoroborate glass, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 61(3), 2005, pp. 431–436.
- [7] JAYASIMHADRI M., MOORTHY L.R., KOJIMA K., YAMAMOTO K., WADA N., WADA N., Optical properties of Dy3+ ions in alkali tellurofluorophosphate glasses for laser materials, Journal of Physics D:Applied Physics 39(4), 2006, p. 635.
- [8] ZHONGCHAO DUAN, JUNJIE ZHANG, LILI HU, Spectroscopic properties and Judd–Ofelt theory analysis of Dy3+ doped oxyfluoride silicate glass, Journal of Applied Physics 101(4), 2007, p. 043110.
- [9] LAKSHMINARAYANA G., VIDYA SAGAR R., BUDDHUDU S., Emission analysis of Dy3+ and Pr3+:Bi2O3––ZnF2–B2O3–Li2O–Na2O glasses, Physica B: Condensed Matter 403(1), 2008, pp. 81–86.
- [10] PRAVEENA R., VIJAYA R., JAYASANKAR C.K., Photoluminescence and energy transfer studies of Dy3+-doped fluorophosphate glasses, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 70(3), 2008, pp. 577–586.
- [11] PIRAMIDOWICZ R., KLIMCZAK M., MALINOWSKI M., Short-wavelength emission analysis in Dy:ZBLAN glasses, Optical Materials 30(5), 2008, pp. 707–710.
- [12] DWIVEDI Y., RAI S.B., Spectroscopic study of Dy3+ and Dy3+/Yb3+ ions co-doped in barium fluoroborate glass, Optical Materials 31(10), 2009, pp. 1472–1477.
- [13] SURENDRA BABU S., BABU P., JAYASANKAR C.K., TRÖSTER TH., SIEVERS W., WORTMANN G., Optical properties of Dy3+-doped phosphate and fluorophosphate glasses, Optical Materials 31(4), 2009, pp. 624–631.
- [14] BABU P., KYOUNG HYUK JANG, EUN SIK KIM, LIANG SHI, HYO JIN SEO, RIVERA-LÓPEZ F., RODRÍGUEZ-MENDOZA U.R., LAVÍN V., VIJAYA R., JAYASANKAR C.K., RAMA MOORTHY L., Spectral investigations on Dy3+-doped transparent oxyfluoride glasses and nanocrystalline glass ceramics,Journal of Applied Physics 105(1), 2009, p. 013516.
- [15] BASAVAPOORNIMA CH., JAYASANKAR C.K., CHANDRACHOODAN P.P., Luminescence and laser transition studies of Dy3+:K–Mg–Al fluorophosphate glasses, Physica B: Condensed Matter 404(2),2009, pp. 235–242.
- [16] SHIQING XU, DAWEI FANG, ZAIXUAN ZHANG, ZHONGHONG JIANG, Effect of OH – on upconversion luminescence of Er3+-doped oxyhalide tellurite glasses, Journal of Solid State Chemistry 178(6),2005, pp. 2159–2162.
- [17] SUN H., ZHANG L., WEN L., LIAO M., ZHANG J., HU L., DAI S., JIANG Z., Effect of PbCl2 addition on structure, OH – content, and upconversion luminescence in Yb3+/Er3+-codoped germanate glasses,Applied Physics B: Lasers and Optics 80(7), 2005, pp. 881–888.
- [18] PRADEESH K., OTON C.J., AGOTIYA V.K., RAGHAVENDRA M., VIJAYA PRAKASH G., Optical properties of Er3+ doped alkali chlorophosphate glasses for optical amplifiers, Optical Materials 31(2), 2008,pp. 155–160.
- [19] PISARSKA J., Novel oxychloroborate glasses containing neodymium ions: Synthesis, structure and luminescent properties, Journal of Molecular Structure 887(1–3), 2008, pp. 201–204.
- [20] SOUZA FILHO A.G., MENDES FILHO J., MELO F.E.A., CUSTODIO M.C.C., LEBULLENGER R., HERNANDES A.C., Optical properties of Sm3+ doped lead fluoroborate glasses, Journal of Physics and Chemistry of Solids 61(9), 2000, pp. 1535–1542.
- [21] HONGTAO SUN, JUNJIE YANG, LIYAN ZHANG, JUNJIE ZHANG, LILI HU, ZHONGHONG JIANG, Composition dependent frequency upconversion luminescence in Er3+-doped oxychloride germanate glasses, Solid State Communications 133(12), 2005, pp. 753–757.
- [22] SINHA S.P., Complexes of the Rare Earth, Pergamon Press, Oxford, 1966.
- [23] CARNALL W.T., FIELDS P.R., RAJNAK K., Electronic energy levels of the trivalent lanthanide aquo ions. IV. Eu3+, Journal of Chemical Physics 49(10), 1968, pp. 4450–4455.
- [24] LAKSHMINARAYANA G., BUDDHUDU S., Spectral analysis of Sm3+ and Dy3+: B2O3–ZnO–PbO glasses, Physica B: Condensed Matter 373(1), 2006, pp. 100–106.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0012-0157