Borate glasses with PbO and PbCl2 containing Dy3+ ions

• Autorzy: Pisarska J.
• Języki publikacji: EN

Abstrakty

EN

Oxychloroborate glasses containing Dy3+ ions in the B2O3–PbCl2–PbO–Al2O3–WO3 system were studied using X-ray diffraction, Raman, FT-IR, absorption, excitation and luminescence spectroscopy. The results concerning glass preparation, short-range order structure and optical properties are reported. X-ray diffraction analysis evidently indicates that the fully amorphous system was prepared. Coexistence of trigonal BO3 and tetrahedral BO4 units was evidenced by Raman and FT-IR spectroscopy. The electronic states belonging to the 4f9 configuration of trivalent Dy3+ were determined from the absorption and excitation spectra. The luminescence bands at 480, 573 and 662 nm were registered in oxychloride glasses, which correspond to transitions originating from the 4F9/2 state to the 6HJ/2 (J = 11, 13, 15) states of Dy3+.

Słowa kluczowe

EN

glasses; dysprosium ions; optical properties

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2010
• Tom: Vol. 40, nr 2
• Strony: 367--374
• Opis fizyczny: Bibliogr. 24 poz.

Twórcy

autor

Pisarska J.

• University of Silesia, Institute of Chemistry, Szkolna 9, 40-007 Katowice, Poland

Bibliografia

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