Coordination properties of the diethyl (pyridin-3-ylmethyl)phosphonate ligand (3-pmpe) with nitrate transition metal salts

• Autorzy: Żurowska B. , Kotyński A. , Ochocki J.
• Języki publikacji: EN

Abstrakty

EN

A new series of nitrate transition metal complexes containing diethyl(pyridin-3-ylmethyl)phosphonate (3-pmpe) as a ligand, having a general formula [M(3-pmpe)2(H2O)2](NO3)2 (M = Cu, Co and Ni) and [Zn(3-pmpe)2](NO3)2 were prepared. The complexes were identified and characterized by the elemental analysis, spectroscopic and magnetic studies. Ligands containing two donor atoms, heterocyclic nitrogen and phosphoryl oxygen atoms bind in a bidentate bridging manner via the pyridine nitrogen and the phosphoryl oxygen atoms. The magnetic behaviour in the temperature range 1.8-300 K) of the Cu(II), Ni(II), Co(II) complexes as well as their spectroscopic properties suggest polymeric structure of all complexes and the existence of a weak antiferromagnetic exchange coupling between paramagnetic centres inside the dibridged linear chains [M(3-pmpe)2M]n.

Słowa kluczowe

EN

N,O ligand; transition metal complexes; spectroscopy; magnetism

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2009
• Tom: Vol. 27, No. 4/1
• Strony: 999--1007
• Opis fizyczny: Bibliogr. 38 poz.

Twórcy

autor

Żurowska B.

autor

Kotyński A.

autor

Ochocki J.

• Faculty of Chemistry University of Wroclaw Joliot-Curie 14 50-383 Wrocław, Poland

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