Structure and characterization of copper(II) perchlorate with diethyl(pyridin-2-ylmethyl) phosphonate (2-pmpe) ligand: [Cu(2-pmpe)2(ClO4)2]

• Autorzy: Żurowska B. , Białońska A. , Ochocki J.
• Języki publikacji: EN

Abstrakty

EN

Copper(II) mononuclear compound [Cu(2-pmpe)2(ClO4)2] (2-pmpe = diethyl(pyridin-2-ylmethyl) phosphonate was synthesized and studied. Examination of the crystal structure by the X-ray diffraction method revealed two crystallographically unrelated molecules, [Cu(1)(2-pmpe)2(ClO4)2] (1) and [Cu(2)(2-pmpe)2(ClO4)2] (2) in an asymmetric part of the unit cell. The geometry about the Cu(1) and Cu(2) chromophores shows elongated octahedra, resulting from the didentate N,O-bonded two chelate 2-pmpe ligands and two coordinated perchlorate ions around the Cu(II) cations (CuN2O4 chromophore). Similarly to 1, molecules 2 are linked to each other by weak C-HoooO hydrogen bonds and ?ooo? stacking interactions. Additionally, both 1 and 2 molecules are linked to each other through weak C-HoooO hydrogen bonds and C-Hooo? contacts, resulting in a 3D polymeric network arrangement. Magnetic data indicate a very weak intermolecular exchange interaction between copper(II) ions (zJ´ = -0.20 cm-1) transmitted through non-covalent interactions in the crystal lattice. The spectral properties are in accordance with the structural and magnetic data.

Słowa kluczowe

EN

copper(II); phosphonic acid ester; crystal structure; spectroscopy; magnetism

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2009
• Tom: Vol. 27, No. 4/1
• Strony: 987--998
• Opis fizyczny: Bibliogr. 42 poz.

Twórcy

autor

Żurowska B.

autor

Białońska A.

autor

Ochocki J.

• Faculty of Chemistry University of Wroclaw Joliot-Curie 14 50-383 Wrocław, Poland

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