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Copper and cerium partially substituted anionic clay was synthesized by the coprecipitation method. The XRD analysis and N2 adsorption at 77 K indicated that calcination destroys the layered matrix of the clay, giving rise to mixed oxides having a high surface area and mesoporous characteristics; SEM analysis showed that the new formed mixed oxides consist of ensembles of highly agglomerated, interconnected nanoparticles. It results from XPS that copper and cerium both contribute to establish the specific redox properties on the surface.
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Tom
Strony
909--917
Opis fizyczny
Bibliogr. 22 poz.
Twórcy
autor
autor
autor
autor
autor
- Faculty of Chemical Engineering and Environmental Protection, Technical University "Gh. Asachi" of Iasi, Iasi 700554, Romania
Bibliografia
- [1] AVGOUROPOULOS G., IOANNIDES T., Appl. Catal., B, 67 (2006), 11.
- [2] ZHENG X.C., WANG S.P., WANG S.R., ZHANG S.M., HUANG W.P., WU S.H., Mater. Sci. Eng., C, 25 (2005), 516.
- [3] RIVES V., Layered Double Hydroxides: Present and Future, Nova Sci. Pub. Inc., New York, 2001.
- [4] CAVANI F., TRIFIRO F., VACCARI A., Catal. Today, 11 (1991), 173, and references therein.
- [5] ARCO M., GUTIERREZ S., MARTIN C., RIVES V., ROCHA J., J. Solid State Chem., 177 (2004), 3954.
- [6] VACCARI A., Appl. Clay Sci., 14 (1999), 161.
- [7] CARJA G., NAKAMURA R., AIDA T., NIIYAMA H., J. Catal., 218 (2003), 104.
- [8] KANNAN S., DUBEY A., KNOZINGER H., J. Catal., 2312 (2005), 381.
- [9] REICHLE W.T., YANG S.Y., EVERHARDT S.D., J. Catal., 10 (1986), 352.
- [10] BRUNAUER S., EMMETT P.H., TELLER E., J. Am. Chem. Soc., 60 (1938), 309.
- [11] SING K.S.W., EVERETT D.H., HAUL R.A.W., MOSCOU L., PIEROTTI R.A., ROUQUEROL J., SIEMIENIEWSKA T., Pure Appl. Chem., 57 (1985), 603.
- [12] GREGG S.J., SING K.S.W., Adsorption, Surface Area and Porosity, 2nd Ed., Academic Press, London, 1982.
- [13] DEFFOSE C., [in:] Chemical Industries, F. Dellany (Ed.), Marcel Dekker, New York, 1984, p. 225.
- [14] SHANNON R.D., Acta Crystallogr., Sect. A: Found. Crystallogr., 32 (1976), 751.
- [15] MOGENSENA M., SAMMES N.M., TOMPSETT G.A., Solid State Ionics, 129 (2000), 63.
- [16] ZARĘBA-GRODŹ I., MIŚTA W., SIKORA A., GOTSZALK T., STRĘK W., HERMANOWICZ K., MARUSZEWSKI K., Mater. Sci., 23 (2005), 147.
- [17] HUTSON N.D., Chem. Mater., 16 (2004), 4135.
- [18] TAKEHIRA K., KAWABATA T., SHISHIDO T., MURAKAMI K., OHI T., SHORO D., HONDA M., TAKAKI K., J. Catal., 231 (2005), 92.
- [19] CARJA G., NAKAMURA R., NIIYAMA H., Microporous Mesoporous Mater., 83 (2005), 147.
- [20] WAGNER C.D., RIGGS W.N., DAVIS L.E., MOULDER J.F., MUILENBERG G.E., Handbook of X-Ray Photoelectron Spectrometry, Perkin-Elmer, Eden Praine, 1979.
- [21] LAACHIR A., PERRICHON V., BADRI A., LAMOTTE J., CATHERINE E., LAVALLEY J.C., FALLAH J., HILAIRE L., NORMAND F., QUEMERE E., SAUVION G.N., TOURET O.J., J. Chem. Soc., Faraday Trans., 87 (1991), 1601.
- [22] GROEN J.C., PEFFER L.A.A., PEREZ-RAMIREZ J., Microporous Mesoporous Mater., 60 (2003), 1.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0011-0146