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Physically and chemically bound H2O in the gyrolite structure

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Synthetic pure gyrolite prepared under hydrothermal conditions (32 h, 200 °C) from a stoichiometric composition (CaO/SiO2 = 0.66) of calcium oxide and a fine-grained SiO2onH2O mixture can easily adsorb water vapour. The equilibrium quantity of adsorbed water vapour was estimated from desorption thermograms. It was determined that the thermal effect of desorption is close to the steam-heat of water vapour at temperatures up to 175 °C. This part of water vapour adsorption can be described by a physical adsorption model, only a small quantity of water vapour being chemisorbed. The crystal structure of gyrolite under a pressure of water vapour and at low temperatures (-197 °C) was stable.
Wydawca
Rocznik
Strony
255--263
Opis fizyczny
Bibliogr. 19 poz.
Twórcy
autor
  • Department of Silicate Technology, Kaunas University of Technology, Radvilenu 19, LT - 50270 Kaunas, Lithuania
Bibliografia
  • [1] MERLINO S., BONACCORSI E., ARMBRUSTER T., Am. Miner., 84 (1999), 1613.
  • [2] TAYLOR H.F.W., Cement Chemistry, Thomas Telford Publishing, London, 1997.
  • [3] GARBEV K., PhD. Thesis, Faculty of Geology and Geography, St. Kliment Ohridski University,Sofia, 2004.
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  • [7] SHAW S., HENDERSON C.M.B., CLARK S.M., Am. Mineral., 87 (2002), 533.
  • [8] GARD J.A., MITSUDA T., TAYLOR H.F.W., Mineral. Mag., 43 (1975), 325.
  • [9] KALOUSEK G.L., NELSON E.B., Cem. Concr. Res., 8 (1978), 283.
  • [10] ŠTEVULA L., PETROVIČ J., Cem. Concr. Res., 13 (1983), 684.
  • [11] OKADA Y., MASUDA T., ISHIDA H., J. Ceram. Soc. Japan., 103 (1995), 124.
  • [12] BALTAKYS K., SIAUCIUNAS R., J. Mater. Sci., 41 (2006), 4799.
  • [13] BALTAKYS K., SIAUCIUNAS R., Mater. Sci.-Poland, 25 (2007), 185.
  • [14] ALLEN A.J., THOMAS J.J., JENNINGS H.M., Nature Materials, 6 (2007), 311.
  • [15] EL-KORASHY S.A., J. Ion Exchange, 15 (2004), 2.
  • [16] EL-KORASHY S.A., AL-WAKEEL E.I., EL-HEMALY S.A., RIZK M.A., Egypt J. Chem., 45 (2002), 723.
  • [17] WINTERS M.A., RICHTER J.D., SAGAR S.L., LEE A.L., LANDER R.J., Biotechnol. Prog., 19 (2003), 440.
  • [18] CHEARY R.W., COELHO A.A., Programs XFIT and FOURYA, deposited in CCP14 Powder Diffraction Library, Engineering and Physical Sciences Research Council, Daresbury Laboratory, Warrington,England, (1996) (http://www.ccp14.ac.uk/tutorial/xfit-95/xfit.htm).
  • [19] MERLINO S., Mineral. Mag., 52 (1988), 377.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0011-0082
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