Vibrational spectra, electronic excited states and magnetic properties of the copper(II) ions in alkylaminoacetylurea complexes

• Autorzy: Ciurla H. , Hanuza J. , Talik Z. , Korabik M. , Mrozinski J.
• Języki publikacji: EN

Abstrakty

EN

Copper(II) complexes with alkylaminoacetylurea ligands were synthesized and studied by means of IR, Raman, electron absorption and luminescence spectroscopies, as well as by ESR and magnetic methods. The spectroscopic and magnetic studies were performed in the 4-300 K and 1.9-300 K temperature ranges, respectively. The Cu2+ ions in these complexes are four coordinated having distorted squareplanar surroundings. The dependence of the spectroscopic parameters on the alkyl radical of the ligand is discussed. At low temperatures, very weak ferromagnetic interactions are observed for the C3 and C5 alkyls, and an antiferromagnetic one is observed for the remaining complexes, with C4 and C6-C18 alkyls.

Słowa kluczowe

EN

copper(II) complexes; alkylaminoacetylureas; IR; Raman; UV absorption spectra; luminescence; ESR; magnetic properties

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2009
• Tom: Vol. 27, No. 1
• Strony: 5--21
• Opis fizyczny: Bibliogr. 41 poz.

Twórcy

autor

Ciurla H.

autor

Hanuza J.

autor

Talik Z.

autor

Korabik M.

autor

Mrozinski J.

• Department of Bioorganic Chemistry,Institute of Chemistry and Food Technology, Faculty of Engineering and Economics,University of Economics, 53-345 Wrocław, Poland

Bibliografia

• [1] MILLER E.V., Chemistry of the Plants, Reinheld, New York, 1957.
• [2] GEISSLER P.R., ROSENBLATT T.M., US Patent 1970, 3, 523, 018.
• [3] ZHENG M., KHANGULOV S.V., DISMUKES G.C., BARYNIN V.V., Inorg. Chem., 33 (1994), 382, and references therein.
• [4] RILEY D.P., WEISS R.H., J. Am. Chem. Soc., 116 (1994), 387, and references therein.
• [5] LINDSEY J.S., PRATHAPAN S., JOHNSON T.E., WAGNER R.W., Tetrahedron, 50 (1994), 8941.
• [6] REICHWEIN A.M., VERBOOM W., REINHOUDT D.N., Recl. Trav. Chim. Pays-Bas., 112 (1993), 595.
• [7] SHIONOYA M., KIMURA E., SHIRO M., J. Am. Chem. Soc., 115 (1993), 6730 and references therein.
• [8] MURAKAMI Y., KIKUCHI J., MIYAJIAMA T., HISAEDA Y., Chem. Lett. (1994), 55.
• [9] HORWITZ P., Chem. Matter, 1 (1989), 463.
• [10] COLLIN J.P., SAUVAGE J.P., J. Chem. Soc. Chem. Commun., (1987), 1075.
• [11] BEDIOUI F., MOISY P., DEVYNK J., SALMON L., BIED-CHARRETON C., J. Mol. Catal., 56 (1989), 267.
• [12] LELIJ F., MORELLI G., RICCARDI G., ROMANELLI M., ROSA A., OTTAVIANI M.F., Polyhedron, 16 (1991), 1911.
• [13] SMITH C.I., CRAYSTON J.A., HAY R.W., J. Chem Soc. Dalton Trans., (1993), 3267.
• [14] FUJITA E., HAFF J., SANZENBACHER R., ELIAS H., Inorg. Chem., 33 (1994), 4627.
• [15] BALZANI V., Tetrahedron, 48 (1992), 10443.
• [16] FUJITA E., BRUNSCHWIG B.S., OGATA T., YANAGIDA S., Coord. Chem. Rev., 132 (1994), 195.
• [17] BIGNOZZI C.A., BORTOLINI O., CHIORBOLI C., INDELLI, M.T., RAMPI M.A., SCANDOLA F., Inorg. Chem., 31 (1992), 172.
• [18] SETH J., PALANIAPPAN V., JOHNSON T.E., PRATHAPAN S., LINDSEY J.S., BOCIAN D.F., J. Am. Chem. Soc., 116 (1994), 10578.
• [19] ODOBEL F., SAUVAGE J.P., New J. Chem., 18 (1994), 1139.
• [20] YAWNEY D.G.W., DOEDENS R.J., Inorg. Chem., 9 (1970), 1626.
• [21] KISHITA M., INOUE M., KUBO M., Inorg. Chem., 3 (1964), 237.
• [22] BULLOCK J., J. Inorg. Nucl. Chem., 29 (1967), 2257.
• [23] DALLOEY N.K., MUELLER M.H., SIMONSEN S.H., Inorg. Chem., 11 (1972), 1840.
• [24] TALIK T., TALIK T.W., TALIK Z., Chemia Stosowana, 34 (1990), 301 (in English).
• [25] TALIK T., TALIK Z., PUSZKO A., Scientific Works of Wroclaw Academy of Economics, Technology, 749 (1997), 67.
• [26] CIURLA H., HANUZA J., TALIK T., TALIK Z., KORABIK M., MROZIŃSKI J., J. Alloys Comp., 341 (2002), 111.
• [27] KÖNIG E., Magnetic Properties of Coordination and Organometallic Transition Metal Compounds, Springer, Berlin, 1966.
• [28] CIURLA H., MICHALSKI J., HANUZA J., MACZKA M., TALIK T., TALIK Z., Spectrochim. Acta, A 64 (2006), 34.
• [29] DROŻDŻEWSKI P., KORDON E., Spectrochim. Acta, A 54 (1998), 947.
• [30] DROŻDŻEWSKI P., KORDON E., Spectrochim. Acta, A 56 (2000), 1299.
• [31] DROŻDŻEWSKI P., PAWLAK B., GŁOWIAK T., J. Coord. Chem., 55 (2002), 735.
• [32] DROŻDŻEWSKI P., BROŻYNA A., KUBIAK M., Polyhedron, 23 (2004), 1785.
• [33] SCHAFFER C.E., JORGENSEN C.K., Mol. Phys., 9 (1965), 401.
• [34] SCHAFFER C.E., Struct. Bonding (Berlin), 5 (1968), 68.
• [35] LARSEN E., MAR G.N.L., J. Chem. Educ., 51 (1974), 633.
• [36] ATANASOV M.A., HITCHMAN M.A., Inorg. Chem., 32 (1993), 3973 and references therein.
• [37] AKITSU T., KOMORITA S., URUSHIYAMA A., Bull. Chem. Soc. Jpn., 74 (2001), 851.
• [38] ATTANASIO D., COLLAMATI I., ERCOLANI C., J. Chem. Soc. Dalton Trans., (1974), 1319.
• [39] PROTASIEWYCK G.M., NUNES F.S., Spectrochim. Acta A, 65 (2006), 549.
• [40] ELLIOTT H., HATHAWAY B.J., SLADE R.C., J. Chem. Soc. A, (1966), 1443.
• [41] KAHN O., Molecular Magnetism, VCH, Weinheim, Germany, 1993.