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Red-emitting LiEuW2O8 phosphor for white emitting diodes prepared by sol-gel process

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Scheelite-type LiEuW2O8 (LEW) phosphors with the optical function of color conversion from near-UV to red were prepared by sol-gel method using a lithium acetate dehydrate, europium(III) nitrate pentahydrate, and tungsten(VI) chloride as starting materials. Viscous mixing sol was prefired at 300 °C for 120 min in air and then white powder precursor was finally annealed at 500-800 °C for 240 min in Ar. From an X-ray diffraction analysis, all the samples are isostructural and belong to the tetragonal system of scheelite-type. The main emission peak is 5D0 › 7F2 transitions of Eu3+ at 615 nm, other transitions from the 5D0 › 7F1, 5D0 › 7F3 and 5D0 › 7F4 located at 570-700 nm range are weak. The characteristic emission of WO4-2 in LEW is quenched absolutely and only red-light emission of Eu3+ appears. Crystallinity, surface properties and red-emission by near-ultraviolet (395 nm) were improved by high-temperature annealing.
Słowa kluczowe
Czasopismo
Rocznik
Strony
375--382
Opis fizyczny
bibliogr. 17 poz.,
Twórcy
autor
autor
autor
autor
  • Department of Biomedical Engineering, Nambu University, 864-1 Wolgye-dong, Gwangsan-gu, Gwangju 506-824, Korea
Bibliografia
  • [1] KIM T., KANG S., Potential red phosphor for UV-white LED device, Journal of Luminescence 122–123(1–2), 2007, pp. 964–966.
  • [2] WANG X.-X., XIAN Y.-L., SHI J.-X., SU Q., GONG M.L., The potential red emitting Gd2–yEuy (WO4 )3–x (MoO4 )x phosphors for UV InGaN-based light-emitting diode, Materials Science and Engineering B: Solid-State Materials for Advanced Technology 140(1–2), 2007, pp. 69–72.
  • [3] NAKAMURA S., MUKAI T., SENOH M., High-brightness InGaN/AlGaN double-heterostructure blue--green-light-emitting diodes, Journal of Applied Physics 76(12), 1994, pp. 8189–8191.
  • [4] LU C.-H., HONG H.-C., JAGANNATHAN R., Sol–gel synthesis and photoluminescent properties of cerium-ion doped yttrium aluminium garnet powders, Journal of Materials Chemistry 12(8), 2002, pp. 2525–2530.
  • [5] KANG Y.C., LENGGORO I.W., PARK S.B., OKUYAMA K., YAG:Ce phosphor particles prepared by ultrasonic spray pyrolysis, Materials Research Bulletin 35(5), 2000, pp. 789–798.
  • [6] NISHIDA T., BAN T., KOBAYASHI N., High-color-rendering light sources consisting of a 350-nm ultraviolet light-emitting diode and three-basal-color phosphors, Applied Physics Letters 82(22), 2003, pp. 3817–4319.
  • [7] WU H., ZHANG X., GUO C., XU J., WU M., SU Q., Three-band white light from InGaN-based blue LED chip precoated with green/red phosphors, IEEE Photonics Technology Letters 17(6), 2005, pp. 1160–1162.
  • [8] KASUYA R., ISOBE T., YAMAO S., Glycothermal synthesis of scheelite-type LiEuW2O8 nanophosphors and their structural characterization, Japanese Journal of Applied Physics, Part 1 46(9A), 2007, pp. 5879–5884.
  • [9] VAN UITERT L.G., JOHNSON L.F., Energy transfer between rare-earth ions, Journal of Chemical Physics 44(9), 1966, pp. 3514–3522.
  • [10] VAN VLIET J.P.M., BLASSE G., BRIXNER L.H., Luminescence properties of alkali europium double tungstates and molybdates AEuM2O8, Journal of Solid State Chemistry 76(1), 1988, pp. 160–166.
  • [11] WANG J., JING X., YAN C., LIN J., LIAO F., Influence if fluoride on f-f transitions of Eu3+ in LiEuM2O8 (M = Mo, W), Journal of Luminescence 121(1), 2006, pp. 57–61.
  • [12] KLEVSTOV P.V., KLEVTSOVA R.F., Polymorphism of the double molybdates and tungstates of mono-and trivalent metals with the composition M+R3+(EO4 )2, Journal of Structural Chemistry 18(3), 1977, pp. 339–355.
  • [13] GÜRMEN E., DANIELS E., KING J.S., Crystal structure refinement of SrMoO4 , SrWO4 , CaMoO4 , and BaWO4 by neutron diffraction, Journal of Chemical Physics 55(3), 1971, pp. 1093–1097.
  • [14] SIVAKUMAR V., VARADARAJU U.V., Intense red-emitting phosphors for white light emitting diodes, Journal of the Electrochemical Society 152(10), 2005, pp. H168–H171.
  • [15] SHI S., LIU X., GAO J., ZHOU J., Spectroscopic properties and intense red-light emission of (Ca, Eu, M)WO4 (M = Mg, Zn, Li), Spectrochimica Acta A 69(2), 2008, pp. 396–399.
  • [16] CHIU C.-H., WANG M.-F., LEE C.-S., CHEN T.-M., Structural, spectroscopic and photoluminescence studies of LiEu(WO4 )2–x(MoO4 )x as a near-UV convertible phosphor, Journal of Solid State Chemistry 180(2), 2007, pp. 619–627.
  • [17] YANG P., YAO G.-Q., LIN J.-H., Photoluminescence and combustion synthesis of CaMo4 doped with Pb2+, Inorganic Chemistry Communications 7(3), 2004, pp. 389–391.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0011-0034
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