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Silica-based versus silica-titania sol-gel materials - comparison of the physical properties: surface tension, gelation time, refractive index and optical transmittance

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Knowledge of the physical parameters and optical constants of sols and sol-gel materials is important in view of their possible applications. In this work, silica and silica-titania sols were examined. Gelation time, surface tension, refractive index and optical transmittance were measured. The sol-gel materials were produced from the silica precursor Si(OC2H5)4 mixed with the titanium dioxide precursor Ti(OC2H5)4 and 96% ethyl alcohol. It was stated that the surface tension of pure silica sols is much higher than in case of silica-titania sols. The refractive index of fresh samples is lower than of stored sols. The transmittance is highest for the fresh samples and it decreases with gelation time; however, this effect is stronger for silica-titania materials. By manipulating with the solvent content and titania addition, the required refractive index may be obtained.
Czasopismo
Rocznik
Strony
211--220
Opis fizyczny
Bibliogr. 26 poz.
Twórcy
autor
autor
  • Bio-Optics Group, Institute of Biomedical Engineering and Instrumentation, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
Bibliografia
  • [1] ALMEIDA R.M., RODRIGUES A.S., Photonic bandgap materials and structures by sol–gel processing, Journal of Non-Crystalline Solids 326–327, 2003, pp. 405–409.
  • [2] OGAWA T., MURATA N., YAMAZAKI S., Development of anti-fogging mirror coated with SiO2-ZrO2-colloidal SiO2 film by the sol–gel process, Journal of Sol–Gel Science and Technology 27(2), 2003, pp. 237–238.
  • [3] QUE W., SUN Z., LAM Y.L., CHAN Y.C., KAM C.H., Effect of titanium content on properties of sol–gel silica-titania films via organically modified silane precursors, Journal of Applied Physics D: Applied Physics 34(4), 2001, pp. 471–476.
  • [4] NOCUŃ M., SIWULSKI S., LEJA E., JEDLIŃSKI J., Structural studies of TEOS-tetraethoxytitanate based hybrids, Optical Materials 27(9), 2005, pp.1523–1528.
  • [5] LENZA R.F.S., VASCONCELOS W.L., Synthesis of titania-silica materials by sol–gel, Materials Research 5(4), 2002, pp. 497–502.
  • [6] GHENNE E., DUMONT F., BUESS-HERMAN C., Stability of TiO2 hydrosols synthesized by hydrolysis of titanium tetraethoxide, Colloids and Surfaces A: Physicochemical and Engineering Aspects 131(1–3), 1998, pp. 63–67.
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  • [12] NELSON S.O., Measurement and calculation of powdered mixture permittivities, IEEE Transactions on Instrumentation and Measurement 50(5), 2001, pp. 1066–1070.
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  • [14] SMITH C., Modified silica transmits vacuum UV, Laser Focus World 37(7), 2001.
  • [15] Technical data and specifications on porous silica glass provided by Geltech, Inc., Alachua, Florida, in the form of sales brochure, 1991.
  • [16] LAM K.S., LO D., WONG K.H., Wideband tuning of a XeCl laser-pumped dye-doped sol–gel silica laser, IEEE Photonics Technology Letters 7(3),1995, pp. 306–308.
  • [17] DAOUD W.A., XIN J.H., Low temperature sol–gel processed photocatalytic titania coating, Journal of Sol–Gel Science and Technology 29(1), 2004, pp. 25–29.
  • [18] Polish norm PN-A-79528-18:2000: Spirit (ethyl alkohol). Methods of tests – UV test.
  • [19] ULATOWSKA A., KUDRAWIEC R., PODBIELSKA H., BRYJA L., MISIEWICZ J., Transmittance examination in sol–gel derived matrices for optoelectronic applications, Optical Materials 17(1–2), 2001, pp. 247–250.
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  • [22] SAKKA S. [Ed.], Sol–Gel Science and Technology: Topics in Fundamental Research and Applications, Springer, 2003, p.138.
  • [23] WENXIU QUE, ZHOU Y., LAM Y.C., CHAN C., SUN Z., CHENG S.D., LI H.P., KAM C.H., Structure and characteristics of sol–gel derived silica-titania hard optical coatings via organically modified silane precursor, Journal of Materials Science Letters 19(14), 2000, pp. 1247–1249.
  • [24] GUGLIELMI M., MARTUCCI A., ALMEIDA R.M., VASCONCELOS H.C., YEATMAN E.M., DAWNAY E.J.C., FARDAD M.A., Spinning deposition of silica and silica-titania optical coatings: A round robin test, Journal of Materials Research 13(3), 1998, pp. 731–738.
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  • [26] AEGERTER M.A., MENNIG M. [Eds.], Sol–Gel Technologies for Glass Producers and Users, Kluwer Academic Publishers, Boston 2004, p. 220.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0011-0019
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