Coordination properties of the diethyl 2-quinolilmethylphosphonate ligand with chloride and nitrate transition-metal salts

Żurowska, B.; Mroziński, J.; Ochocki, J.

Artykuł - szczegóły

Tytuł artykułu

Coordination properties of the diethyl 2-quinolilmethylphosphonate ligand with chloride and nitrate transition-metal salts

Autorzy

Żurowska B. , Mroziński J. , Ochocki J.

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Abstrakty

A new series of the chloride and nitrate transition metal complexes containing the ligand diethyl 2-quinolylmethylphosphonate (2-qmpe) of general formula M(2-qmpe)(NO3)2 (M = Cu, Co), [Zn(2-qmpe)(H2O)2NO3]NO3ź H2O, [Ni(2-qmpe)(H2O)2NO3]NO3, M(2-qmpe)2Cl2 (M = Cu, Ni, Co, Pd) and M(2-qmpe)Cl2 (M = Co, Zn) were prepared. The complexes were identified and characterized by elemental analysis, spectroscopic and magnetic studies. Ligand containing two donor atoms, heterocyclic nitrogen and phosphoryl oxygen atoms exhibits different coordination properties. It was shown that the ligand binds in a bidentate chelate manner via the quinoline nitrogen and the phosphoryl oxygen atoms (complexes with 1:1 metal to ligand molar ratio) and it can also acts as a monodentate ligand coordinated through the nitrogen in the Pd(II) or oxygen atom in the Cu(II) and Co(II) complexes (complexes with 1:2 metal to ligand molar ratio). The magnetic behaviour of the Cu(II), Ni(II) and Co(II) and spectroscopic investigation of Zn(II) complexes suggests mononuclear structure of all the complexes and the existence of a weak intermolecular exchange coupling between magnetic centres inside crystal lattice.

Słowa kluczowe

N,O ligand transition metal complexes spectroscopy magnetism

Wydawca

De Gruyter

Czasopismo

Materials Science Poland

Rocznik

2007

Tom

Vol. 25, No. 4

Strony

1063--1074

Opis fizyczny

Bibliogr. 48 poz.

Twórcy

autor

Żurowska B.

autor

Mroziński J.

autor

Ochocki J.

Faculty of Chemistry, University of Wroclaw, ul. F. Joliot- Curie 14, 50-383 Wroclaw, Poland

Bibliografia

[1] SYAMAL A., MAURYA M.R., Coord. Chem. Rev., 95 (1985), 95.
[2] KUHAR V.P., HUDSON H.R., [in:] Aminophosphonic and Aminophosphinic Acids. Chemistry and Biological Activity, V. P. Kukhar, H.R. Hudson (Eds.), Wiley, London, 1999.
[3] ARANOWSKA K., GRACZYK J., CHĘCIŃSKA L., PAKULSKA W., OCHOCKI J., Pharm., 61 (2006), 457.
[4] ZIĘBA R., MALINOWSKA K., WIEWIÓROWSKI M., GRACZYK J., Acta Pol. Pharm., 57 (2000), 136.
[5] CHĘCIŃSKA L., WAŁECKA M., OCHOCKI J., ARANOWSKA K., Acta Cryst., E 59,( 2003), 350.
[6] BRZEZIŃSKA-BŁASZCZYK E., MIŃCIKIEWICZ M., OCHOCKI J., Eur. J. Pharmacol., 298, (1996), 155.
[7] KOSTKA B., OCHOCKI J., Pharm., 51 (1996), 990.
[8] OCHOCKI J., KOSTKA K., ŻUROWSKA B., MROZIŃSKI J., GAŁDECKA E., GAŁDECKI Z., REEDIJK J.,J. Chem. Soc. Dalton Trans., (1992), 2955.
[9] TUŠEK-BOŽIĆ L., FURLANI A., STARCIA V., DE CLERCQ E., BALZARINI J., J. Inorg. Biochem., 72 (1998), 201.
[10] BLOEMINK M.J., DORENBOS J.P., HEETEBRIJ R.J., KEPLER B.K., REEDIJK J., ZAHN H., Inorg. Chem., 33 (1994), 1127.
[11] LIPPERT B., An Inorganic Perspective of Life, NATO ASI Series, Kluwer, Dordrecht, 1995, p. 179.
[12] The IUPAC-recommended names for diethyl 2-pyridylmethylphosphonate and diethyl 2-quinolylmethylphosphonate are diethyl pyridyl-2-ylmethylphosphonate and diethyl quinolyl-2-ylmethylphosphonate, respectively.
[13] ŻUROWSKA B., MROZIŃSKI J., OCHOCKI J., Mater. Sci., 18, 1992.
[14] OCHOCKI.J., ŻUROWSKA.B., MROZIŃSKI.J., REEDIJK.J., Proc. III Symphosium on Inorganic Biochemistry and Molecular Biophysics, VI International Scientific School on Biological Macromolecules, 1991, p.212.
[15] ŻUROWSKA B., MROZIŃSKI J., CIUNIK Z., OCHOCKI J., J. Mol. Struct. 791 (2006), 98
[16] OCHOCKI J., ŻUROWSKA B., MROZIŃSKI J., KOOIJMAN H., SPEK A.L., REEDIJK J., Eur. J. Inorg. Chem. 169 (1998).
[17] ŻUROWSKA B., OCHOCKI J., MROZIŃSKI J., CIUNIK Z., REEDIJK J., Inorg. Chim. Acta 357 (2003), 755.
[18] FIGGIS B.N., NYHOLM R.S., J. Chem. Soc., (1958), 4190.
[19] KÖNIG E., Magnetic Properties of Coordination and Organometallic Transition Metal Compounds, Springer, Berlin, 1966.
[20] CARLIN R.L., Magnetochemistry, Springer, Berlin, 1986.
[21] Tip for Ni(II), an Co(II), calculated as N= 8N2/10Dq.
[22] EARNSHAW A., Introduction to Magnetochemistry, Academic Press, London, 1968.
[23] WITTEVEEN H.T., REEDIJK J., J. Solid State Chem., 10, (1974), 151.
[24] CLARK R.J.H., WILIAMS C.S.W., Inorg. Chem., 4 (1965), 350.
[25] TUŠEK-BOŽIĆ L., MATIJASIĆ I., BOCELLI G., CALESTANI G., FURLANI A., STARCIA V., PAPAIOANNOU A., J. Chem. Soc. Dalton Trans., 195 (1991).
[26] NAKAMOTO K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, 1986.
[27] CURTIS N.F., CURTIS Y.M., Inorg. Chem., 4 (1965), 804.
[28] NUTTALL R.H., TAYLOR D.W., J. Chem. Soc. Chem. Commun., (1968), 1417.
[29] KLEIJWEGT G.J., WIESMEIJER W.G.R., VAN DRIEL G.J., DRIESSEN W.L., REEDIJK J., NOORDIK J.H., J. Chem. Soc. Dalton Trans., (1985), 2177.
[30] NEENAN T.X., DRIESSEN W.L., HASNOOT J.G., J.REEDIJK, Inorg. Chim. Acta, 247 (1996),43.
[31] ADAMS D.M..Metal–Ligand and Related Vibration, Edward Arnold, London, 1967. [32] FERRARO J.R., Low Frequency Vibrations of Inorganic and Coordination Compounds, Plenum, New York, 1971.
[33] CLARK R.J.H., Halogen Chemistry, Vol. 3, V. Guttman (Ed.), Academic Press, New York , 1967. 1074 B. ŻUROWSKA et al.
[34] REEDIJK J., SIEDLE A.R, VELAPOLDI R.A, HEST J.A.M, Inorg. Chim. Acta, 74 (1983), 109 and references therein.
[35] LEVER A.B.P., Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1986.
[36] REEDIJK J., VAN LEEUWEN P.W.N.M., GROENEVELD W.L., Recl. Trav. Chim. Pays Bas., 87 (1968), 129.
[37] REEDIJK J., DRIESSEN W.L., GROENEVELD W.L., Recl. Trav. Chim. Pays Bas., 88 (1969), 1095.
[38] MASLEJOVA A., UHRINOVA S., MROZIŃSKI J., ŻUROWSKA B., MUNOZ M.C., JULVE M., Inorg. Chim. Acta, 255, 343 (1997),.
[39] WEST D.X., HARTLEY R., J. Inorg. Nucl. Chem., 43 (1969), 957.
[40] COTTON F.A., GOODGAME M., J. Am. Chem. Soc., 83 (1961),1777.
[41] LEVER A.B.P., NELSON S.M., J. Chem Soc. A, (1966), 859.
[42] COTTON .F.A., GOODGAME D.M ., GOODGAME M., J. Am. Chem. Soc., 83 (1961), 4690.
[43] LEVER A.B., J. Chem. Ed., 45 (1968), 711.
[44] KOKOSZKA G.F., GORDON G., Trans. Met. Chem., 5 (1969), 181.
[45] DISSOUKY A.EL., REFAAT L.S., Inorg. Chim. Acta, 87 (1984), 213.
[46] HATHAWAY B.J., BILLING D.E., Coord. Chem. Rev., 5 (1970), 143.
[47] REEDIJK J., Trans. Met. Chem., 6 (1981), 195.
[48] FIGGIS F.N., LEVIS J., Progress Inorg. Chem., 6 (1964), 37.

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Bibliografia

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