Luminescent materials, recognition phases of the chemical sensors and heterogeneous catalysts prepared by sol-gel method

Kłonkowski, A. M.

Artykuł - szczegóły

Tytuł artykułu

Luminescent materials, recognition phases of the chemical sensors and heterogeneous catalysts prepared by sol-gel method

Autorzy

Kłonkowski A. M.

Identyfikatory

Warianty tytułu

Konferencja

International Conference on Sol-Gel materials SGM 2001, Rokosowo, Poland

Języki publikacji

Abstrakty

The sol-gel process enables one to prepare oxide xerogels at room temperature. By using this method, it is possible to encapsulate a wide variety of organic, complex (organometallic) molecules and metallic nanoparticles stabilized by organic ligands in the inorganic or inorganic/organic hybrid matrix. Studies of this new type of inorganic/organic composite have evolved towards the deliberate doping of the supramolecular species. This review gives three examples of how doped xerogel materials prepared by the sol-gel method are emerging as an important means of producing new materials. The first part of this review is devoted to luminescent materials which are based on the antenna effect and are composed of Eu(III) complex (luminescence centre) entrapped in xerogel matrix. In this case results of the experiments concerning the coordination sphere composition show that a cryptand ligand with aromatic groups and an aromatic co-ligand, settle efficient action the antenna effect and isolate the central ion from each efficient quenchers, as e.g. water molecules. Secondly, silica xerogel samples with entrapped series of three fluorescent chemosensors of the Ant-R-Ant type, where Ant is an anthryl group and R is a receptor (spacer) with donor atoms, were prepared as chemical recognition phases. The recognition phase with fluorosensor of the type Ant- N-O-O-N-Ant, where N and O are donor atoms, can be regenerated many times and seems to be most promising system for the fluorescent chemical sensor. In the third part of this paper, ligand protected metal nanoclusters as immobilized catalysts are the point of interest. This type of heterogeneous catalysts are much less investigated than the bare metal particles on supports. The main interest is focused on the function of the ligands.

Słowa kluczowe

sol-gel xerogel ligand organometallic

Wydawca

Oficyna Wydawnicza Politechniki Wrocławskiej

Czasopismo

Materials Science

Rocznik

2002

Tom

Vol. 20, No. 1

Strony

57--70

Opis fizyczny

Bibliogr. 88 poz.,

Twórcy

autor

Kłonkowski A. M.

Faculty of Chemistry, University of Gdań sk, 80-952 Gdań sk, Poland

Bibliografia

1. L.L. Hench and J.K. West, Chem. Rev. 90 (1990), 33.
2. C.J. Brinker, G. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing. Academic Press, San Diego 1989.
3. Sol-Gel Technology. L.C. Klein (Ed.), Noyes Publications, Park Ridge NJ 1988.
4. L.C. Klein, Annu. Rev. Mater. Sci. 15 (1985), 227.
5. B. Dunn, J.I. Zink, J. Chem. Mater. 1 (1991), 903.
6. N. Sabbatini, M. Guardigli, Coord. Chem. Rev. 123 (1993), 201.
7. G.A. Crosby, R.E. Whan, R.M. Alire, J. Chem. Phys. 34 (1961), 741.
8. L.R. Melby, N.J. Rose, E. Abramson, J.C. Caris, J. Am. Chem. Soc. 86 (1964), 5117.
9. J.L. Kropp, M.W. Windsor, J. Chem. Phys. 42 (1965), 1590.
10. W.R. Dawson, J.L. Kropp, M.W. Windsor, J. Chem. Phys. 45 (1966), 2410.
11. J. Kleinerman, J. Chem. Phys. 42 (1969), 1590.
12 .J.-M. Lehn, C.O. Roth, Helv. Chim. Acta 74 (1991), 572.
13. D. Levy, R. Reisfeld, D. Avnir, Chem. Phys. Lett. 109 (1984), 596.
14. X.P. Fan, W.Q. Wang, G.H. Xiong, Mater. Sci. B21 (1993), 55.
15. M.J. Lockhead, K.L. Bray, J. Non-Cryst. Solids 170 (1994), 143.
16. X.P. Fan, W.Q. Wang, G.H. Xiong, Mater. Lett. 27 (1996), 177.
17. X.P. Fan, M.Q. Wang, Z.Y. Wang, Z.G. Hong, Mater. Res. Bull. 32 (1997), 1119.
18. K. Czarnobaj, M. Elbanowski, Z. Hnatejko, A.M. Kłonkowski, S. Lis, M. Pietraszkiewicz, Spectrochim. Acta A, 54 (1998), 2183.
19. A.M. Kłonkowski, S. Lis, Z. Hnatejko, K. Czarnobaj, M. Pietraszkiewicz, M. Elbanowski, J. Alloys Compd., 300-301 (2000), 55.
20. Z. Hnatejko, A.M. Kłonkowski, S. Lis, K. Czarnobaj, M. Pietraszkiewicz, M. Elbanowski, Mol. Cryst. Liq. Cryst. A, 354 (2000) 207.
21. W.T. Carnal, in: Handbook on the Physics and Chemistry of Rare Earths. K.A. Gschneider, L. Eyring, (Eds.),, vol. 3, North-Holland, Amsterdam 1979, p. 237.
22. R. Reisfeld, Struct. Bonding , Springer Verlag, Berlin 1975, 22, 123.
23. W. Stręk, J. Chem. Phys., 76 (1982), 5856.
24. F.K. Freed, Top. Appl. Phys., 15 (1976), 23; G. Stein, E. Wurzburg, J. Chem. Phys. 62 (1975), 208.
25. Y. Haas, G. Stein, J. Phys. Chem., 75 (1971), 3677.
26. B.Yan, H. Zhang, S.Wang, J. Ni, J. Photochem. Photobiol. A. Chem., 112 (1998), 231.
27. A.M. Kłonkowski, S. Lis, M. Pietraszkiewicz, Z. Hnatejko, K. Czarnobaj, M. Elbanowski, Chem. Mat., in press.
28. V. Balzani, F. Scandola, Supramolecular Photochemistry. Ellis Harwood, London 1991, p. 73.
29. R.A. Bissell, A.P. de Silva, H.Q.N. Gunaratne, P.L. M. Lynch, G.E.M. Maguire, K.R.A.S. Sundanayake, Chem. Soc. Rev., 1992, 187.
30. A.P. de Silva, H.Q.N. Gunaratne, T. Gunnlaugsson, A.J.M. Huxley, C.P. McCoy, J.T. Rademacher, T.E. Rice, Chem. Rev., 97 (1997), 1515.
31. L. Fabbrizzi, M. Licchelli, P. Pallavicini, A. Perotti, D. Sacchi, Angew. Chem., Int. Ed. Engl., 33 (1994), 1975.
32. L. Fabbrizzi, , I. Faravelli, G. Francese, M. Licchelli, A. Taglietti, Chem. Commun., 1998, 971.
33. L. Fabbrizzi, G. Francese, M. Licchelli, A. Taglietti, Chem. Commun., 1997, 581.
34. A.W. Czarnik, Acc. Chem. Res., 27 (1994), 302.
35. Fluorescent Chemosensors for Ion and Molecule Recognition. A.W. Czarnik (Ed.), Amer. Chem. Soc., Washington DC 1993.
36. B. Valeur, in: Topics in Fluorescence Spectroscopy. J.R. Lakowicz (Ed.), Plenum Press, New York 1994, vol. IV, p. 21.
37. A.W. Czarnik, in: Topics in Fluorescence Spectroscopy. J.R. Lakowicz (Ed.), Plenum Press, New York 1994, vol. IV, p. 49.
38. J.-M. Lehn, Angew.Chem., Int. Ed. Engl., 27 (1988), 89.
39. A.P. de Silva, H.Q.N. Guanaratne, C.P. McCoy, Nature, 364 (1993), 42.
40. P. Ghosh, P.K. Bharadwaj, S. Mandal, S. Ghosh, J. Am. Chem. Soc., 118 (1996), 1553 and references therein.
41. Fernandez-Gutierrez, A. Munoz de la Pena, in: Molecular Luminescence Spectroscopy: Methods and Applications. S.G. Schulman (Ed.), Wiley, New York 1985, p. 371.
42. A.W. Czarnik, Chem. Biol., 2 (1995), 423.
43. A.W. Varnes, R.B. Dodson, E.L. Wehry, J. Am. Chem. Soc., 94 (1972), 946 and references therein.
44. K. Rurack, U. Resch, M. Senoner, S. Dachne, J. Fluoresc., 3 (1993), 141.
45.J.A. Kemlo, T.M. Shepherd, Chem. Phys. Lett., 47 (1977), 158.
46. R.S. Davidson, Adv. Phys. Org. Chem., 19 (1983), 1; Photoinduced Electron Transfer. M.A. Fox (Ed.), Parts A-D, Elsevier, Amsterdam 1988.
47. A.J. Bryan, A.P. de Silva, S.A. de Silva, R.A.D.D. Rupasinghe, K.R.A.S. Sandanayake, Biosensors, 4 (1989), 169.
48. Chemical Sensors, T. Edmont (Ed.), Blackie, Glasgow 1988.
49. P. Roper, Am. Ind. Hygiene Assoc. J., 35 (1974), 438.
50. Molecular Luminescence Spectroscopy: Methods and Applications. S.G. Schulman (Ed.), Wiley, New York 1989.
51. G. Serra, A. Schirone, R. Boniforti, Anal. Chim. Acta, 232 (1990), 337.
52. T. Nakagama, M. Yamada, T. Hobo, Anal. Chim. Acta, 231 (1990), 7.
53. R. Zusman, C. Rottman, M. Ottolenghi, D. Avnir, J. Non-Cryst. Solids, 122 (1990), 107.
54. B. Dunn, J.I. Zink, J. Chem. Mater., 1 (1991), 903.
55. S. Braun, S. Rappoport, R. Zusman, D. Avnir, M. Ottolenghi, Mater. Lett., 10 (1990), 1.
56. D. Levy, B.I. Kuyavskaya, I. Zamir, M. Ottolenghi, D. Avnir, O. Lev, J. Sep. Sci. Technol., 27 (1991), 589.
57. J.C. Pouxviel, B. Dunn, J.I. Zink, J. Phys. Chem., 93 (1989), 2134.
58. A. Salma-Schwok, D. Avnir, M. Ottolenghi, J. Am. Chem. Soc., 113 (1991), 3984.
59. B.D. MacCraith, C.M. McDonagh, G. O’Keefe, A.K. McEvoy, T. Butler, F.R. Sheridan, Sensor Actuat. BChem., 29 (1995), 51.
60. O.S. Wolfbeis, R. Reisfeld, I. Oehme, Structure Bonding, 85 (1996), 51.
61. R. Ostaszewski, A.M. Kłonkowski, K. Kledzik, Supramol. Chem., 12 (2000), 131.
62. A.M. Kłonkowski, K. Kledzik, R. Ostaszewski, J. Incl. Phenom. Mol., 35 (1999), 165.
63. A.M. Kłonkowski, K. Kledzik, R. Ostaszewski, in: Coordination Chemistry of the Turn of the Century,
G. Ondrejovic, A. Sirota (Eds.), Slovak Technical University Press, Bratislava 1999, p. 289.
64. A.M. Kłonkowski, K. Kledzik, R. Ostaszewski, J. Jezierska, J. Mater. Chem., in the press.
65. For a summarizing review containing ca. 400 references see L.N. Lewis, Chem. Rev., 93 (1993), 813.
66. G. Schmid, S. Emde, V. Maihack, M. Meyer-Zaika, St. Peschel, J. Mol. Catal. A, 107 (1996), 95.
67. G. Schmid, V. Maihack, F. Lantermann, St. Peschel, J. Chem. Soc., Dalton Trans., 1996, 589.
68. G. Schmid, M. Bäumle, M. Geerkens, I. Heim, C. Osemann, T. Sawitowski, Chem. Soc. Rev., 28 (1999), 179.
69.J.S. Bradley, in: Clusters and Colloids. G. Schmid (Ed.), VCH Publishers, Weinheim 1994.
70. G. Schmid, Chem. Rev., 92 (1992), 1709.
71. H. Liu, N. Toshima, J. Chem. Soc., Chem. Commun., 1992, 1095.
72. J.S. Bradley, Chem. Mater., 5 (1993), 254.
73. K. Torigoe, K. Esumi, Langmuir, 9 (1993), 1664.
74. C. Larpent, F. Brisse-Le Menn, H. Patin, Mol. Catal., 65 (1991), L35.
75. T. Sato, S. Kuroda, A. Takami, Y. Yonezawa, H. Hada, Appl. Organomet. Chem., 5 (1991), 261.
76. T. Sato, J. Appl. Phys., 68 (1990), 1297.
77. T. Sato, J. Chem. Soc., Faraday Trans. 1, 83 (1987), 1559.
78. H. Hirai Y. Nakao, N. Toshima, Chem. Lett., 5 (1978), 545.
79. M. Ohtaki, M. Komiyama, H. Hirai, N. Toshima, Macromolecules, 24 (1991), 5567.
80. N. Toshima, J. Phys. Chem., 95 (1991), 7448.
81. N. Toshima, J. Phys. Chem., 96 (1992), 9927.
82. H. Hirai, Y. Nakao, N. Toshima, Chem. Lett., 9 (1982), 905.
83. N. Toshima, M. Ohtaki, T. Teranishi, Reactive Polym., 15 (1991), 135
84. H. Bö nnemannW. Brijoux, R. Brinkmann, E. Dinjus, Th. Joussen, B. Korall, Angew. Chem., 103 (1991), 1344; Angew. Chem. Int. Ed. Engl., 30 (1991), 1312.
85. H. Bö nnemannW. Brijoux, R. Brinkmann, R. Fretzen, Th. Joussen, R. Kö ppler, B. Korall, P. Neiteler, J. Richter, J. Mol. Catal., 76 (1994), 129.
86. H. Bö nnemann, W. Brijoux, R. Brinkmann, E. Dinjus, R. Fretzen, Th. Joussen, B. Korall, J. Mol. Catal., 74 (1992), 323.
87. H. Bö nnemann, R. Brinkmann, P. Neiteler, Appl. Organomet. Chem., 8 (1994), 361.
88. H. Bö nnemann, W. Brijoux, in: Advanced Catalysts and Nanostructured Materials. Modern Synthetic Methods. W.R. Moser (Ed.), Academic Press, San Diego 1996, Chap. 7.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BPW7-0006-0007