Thiolato-bridged copper complexes with N,N,S-tridentate ligands

• Autorzy: Kotera T. , Fujita A. , Mikuriya M. , Handa M.
• Języki publikacji: EN

Abstrakty

EN

Thiolato-bridged complexes [CuII2(apaet)Cl3] and [CuI3CuII3(apampt)3Cl6] (Hapaet = 2-[(3-aminopropyl)amino]ethanethiol, Hapampt = 1-[(3-aminopropyl)amino]-2-methylpropane-2-thiol), have been synthesized and characterized by infrared and electronic absorption spectra and temperature dependence of magnetic susceptibilities. X-ray crystallography of the latter complex reveals a localized mixed-valence structure which is supported by the spectroscopic and electrochemical data. Magnetic susceptibility data show that a strong antiferromagnetic interaction is operating between CuII ions in both the complexes.

Słowa kluczowe

EN

thiolato-bridged complexes; mixed-valence complexes; Cu; hexanuclear complexes

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Materials Science
• Rocznik: 2003
• Tom: Vol. 21, No. 2
• Strony: 171--179
• Opis fizyczny: Bibliogr. 29 poz.,

Twórcy

autor

Kotera T.

• Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Japan

autor

Fujita A.

• Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Japan

autor

Mikuriya M.

• Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Japan

autor

Handa M.

• Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan

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