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Effective nuclear charge of an ion

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
An analysis of the effective nuclear charge of ions based on linear relationships of the reciprocal of an ionic radius or the square root of ionisation energy and the nuclear charge of the ion has been carried out. It has been demonstrated that the effective nuclear charge of an ion is significantly different from its formal charge. The obtained character of the relationship indicates that the postulated parameter can be employed to determine differences in properties of ions. It has also been shown that the differences occurring in the calculated effective nuclear charges of the ion permit one to differentiate its states. Namely, values based on ionisation enthalpy characterise ions of a given coordination number in a crystal lattice.
Słowa kluczowe
Wydawca
Rocznik
Strony
35--45
Opis fizyczny
Bibliogr. 18 poz.
Twórcy
autor
  • Cracow University of Technology, Institute of Chemical Engineering and Physical Chemistry, ul. Warszawska 24, 31-155 Kraków, Poland
autor
  • Cracow University of Technology, Institute of Chemical Engineering and Physical Chemistry, ul. Warszawska 24, 31-155 Kraków, Poland
autor
  • Cracow University of Technology, Institute of Chemical Engineering and Physical Chemistry, ul. Warszawska 24, 31-155 Kraków, Poland
Bibliografia
  • [1] MOSELEY H.G.J., Phil. Mag., 26 (1913), 1024; 27 (1914), 703.
  • [2] SLATER J.C., Phys. Rev., 36 (1930), 57.
  • [3] CLEMENTI E., RAIMONDI D.L., J. Chem. Phys., 38 (1963), 2686.
  • [4] BURNS G., J. Chem. Phys., 41 (1964), 1521.
  • [5] PAULING L., J. Am. Chem. Soc., 49 (1927), 765.
  • [6] ALLRED A.L., ROCHOW E.G., J. Inorg. Nuclear Chem., 5 (1958), 264.
  • [7] CATLOW C.R.A., MACKRODT W.C., Computer Simulation of Solids: Lecture Notes in Physics, 166, Springer-Verlag, Berlin, 1982.
  • [8] ALLEN M.P., TILDESLEY D.J., Computer Simulation of Liquids, Clarendon Press, Oxford, 1987.
  • [9] CATLOW C.R.A, Computer Modelling in Crystalography, Acad. Press, London, 1997.
  • [10] STOKŁOSA A., ZAJĘCKI J., KUREK S., Materials Sci.-Poland, 22 (2004), 17.
  • [11] HUHEERY J.E., KEITER E.A., KEITER R.L., Inorganic Chemistry: Principles of Structure and Reactivity, 4th Edition, Harper Collins, New York, 1993.
  • [12] Chemical Rubber Company Handbook of Chemistry and Physics, 79th Edition, D.R. Lide (Ed.), CRC Press, Boca Raton, Florida, USA, 1998.
  • [13] Lange’s Handbook of Chemistry, 14th Edition, J.A. Dean (Ed.), McGraw-Hill, New York, 1992.
  • [14] WINTER M., WebElements, University of Sheffield, England, (www.webelements.com).
  • [15] SHANNON R.D., Acta Cryst. A32 (1976), 751.
  • [16] SHANNON R.D., PREWITT C.T., Acta Cryst. B 25 (1969), 925; B 26 (1970), 1046.
  • [17] PEARSON W.B., J. Phys. Chem. Solids, 23 (1962), 103.
  • [18] PHILIPS J.C., Rev. Mod. Phys., 42 (1970), 317.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0003-0003
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