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Investigation of the aging of epitaxial LaNiO3-x films by X-ray photoelectron spectroscopy

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Języki publikacji
EN
Abstrakty
EN
The X-ray photoelectron spectroscopy (XPS) was performed to study surface and volume composition, valence states and the concentration of hydroxyl groups in epitaxial LaNiO3?x thin films after aging in air. The existence of at least few different forms of oxygen as lattice oxide, hydroxyl groups and adsorbed water in the samples is shown by XPS characterization. The lanthanum and nickel exist in oxide and hydroxide chemical states. The concentration of hydroxyl groups increases at the surface but it is distributed through the volume as well. It was found that the surface Ni/La concentration ratio is close to the stoichiometric bulk value.
Czasopismo
Rocznik
Strony
235--243
Opis fizyczny
Bibliogr. 18 poz.,
Twórcy
autor
autor
autor
  • Semiconductor Physics Institute, 01108 Vilnius Lithuania
Bibliografia
  • [1] PAJACZKOWSKA A., GLOUBOKOV A., Synthesis, growth and characterization of tetragonal ABCO4 crystals, Progress in Crystal Growth and Characterization of Materials 36(1–2), 1998, pp. 123–62.
  • [2] NOVOSSELOV A.V., ZIMINA G.V., FILARETOV A.A., SHLYAKHTINB O.A., KOMISSAROVA L.N., PAJACZKOWSKA A., On the synthesis and thermodynamic properties of SrLaGaO4-SrLaAlO4 solid solutions, Materials Research Bulletin 36(10), 2001, pp. 1789–98.
  • [3] VENGALIS V., OGINSKAS A.K., LISAUSKAS V., BUTKUT R., MANEIKIS A., DAPKUS L., JASUTIS V., SHIKTOROV N., Growth and investigation of the La1–xCaxMnO3/(LaNiO3, RuO2) heterostructures, [In] Thin Films Deposition of Oxide Multilayers. Industrial-Scale Processing: Proceedings of the International Conference, Vilnius, Lithuania, 2000, pp. 45–8.
  • [4] CHOISNET J., ABADZHIEVA N., STEFANOV P., KLISSURSKI D., BASSAT J.M., RIVES V., MINCHEV L., X-ray photoelectron spectroscopy, temperature-programmed desorption and temperature-programmed reduction study of LaNiO3 and La2NiO4 + catalysts for methanol oxidation, Journal of the Chemical Society Faraday Transactions 90(13), 1994, pp. 1987–91.
  • [5] BARBERO J., PEÑA M.A., CAMPOS-MARTIN J.M., FIERRO J.L.G., ARIAS P.L., Support effect in supported Ni catalysts on their performance for methane partial oxidation, Catalysis Letters 87(3–4), 2003, pp. 211–8.
  • [6] SIEGMANN H.S., SCHLAPBACH L., BRUNDLE C.R., Self-restoring of the active surface in the hydrogen sponge LaNi5, Physical Review Letters 40(14), 1978, pp. 972–5.
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  • [8] YAN-LI LI, NUO-FU CHEN, JIAN-PING ZHOU, SHU-LIN SONG, LI-FENG LIU, ZHI-GANG YIN, CHUN-LIN CAI, Effect of the oxygen concentration on the properties of Gd2O3 thin films, Journal of Crystal Growth 265(3–4), 2004, pp. 548–52.
  • [9] BRUNDLE C.R., [In] Electronic Structure and Reactivity of Metal Surfaces, E.G. Derouane, A.A. Lucas [Eds.], Plenum, New York 1975, pp. 389–457.
  • [10] LU J.M., HWANG W.S., YANG J.S., Effects of substrate temperature on the resistivity of non-stoichiometric sputtered NiOx films, Surface and Coatings Technology 155(2–3), 2002, pp. 231–5.
  • [11] LORENZ P., FINSTER J., WENDT G., SALYN J.V., ZUMADILOV E.K., NEFEDOV V.I., ESCA investigations of some NiO/SiO2 and NiO-Al2O3 /SiO2 catalysts, Journal of Electron Spectroscopy and Related Phenomena 16(4), 1979, pp. 267–76.
  • [12] DE ASHA A.M., CRITCHLEY J.T.S., NIX R.M., Molecular adsorption characteristics of lanthanum oxide surfaces: the interaction of water with oxide overlayers grown on Cu(111), Surface Science 405(2–3), 1998, pp. 201–14.
  • [13] MOULDER J.F., STICHLE W.F., SOBOL P.E., BOMBEN K.D., Handbook of X-ray Photoelectron Spectroscopy, Physical Electronics Inc., Eden Prairie, USA 1995.
  • [14] MICKEVIČIUS S., GREBINSKIJ S., BONDARENKA V., VENGALIS B., ŠLIUŽIENĖ K., ORLOWSKI B.A., OSINNIY V., DRUBE W., Investigation of epitaxial LaNiO3–x thin films by high-energy XPS, Journal of Alloys and Compounds 423(1–2), 2006, pp. 107–11.
  • [15] BARR T.L., An ESCA study of the termination of the passivation of elemental metals, Journal of Physical Chemistry 82(16), 1978, pp. 1801–10.
  • [16] SUZUKI C., KAWAI J., TAKAHASHI M., VLAICU A.-M., ADACHI H., MUKOYAMA T., The electronic structure of rare-earth oxides in the creation of the core hole, Chemical Physics 253(1), 2000, pp. 27–40.
  • [17] MULLICA D.F., LOK C.K.C., PERKINS H.O., YOUNG V., X-ray photoelectron final-state screening in La(OH)3 : a multiplet structural analysis, Physical Review B: Condensed Matter 31(6), 1985, pp. 4039–42.
  • [18] DALLERA C., GIARDA K., GHIRINGHELLI G., TAGLIAFERRI A., BRAICOVICH L., BROOKES N.B., Charge-transfer excitations in lanthanum compounds measured by resonant inelastic X-ray scattering at the M5 edge, Physical Review B: Condensed Matter and Materials Physics 64(15), 2001, pp. 153104/1–4.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW7-0002-0067
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