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Abstrakty
This work presents the study of the structural and optical properties of TiO2:Tb thin films deposited on Si (100) and SiO2 substrates by magnetron sputtering from metallic Ti-Tb mosaic target. Thin films were studied by means of scanning electron microscopy with energy disperse spectrometer (SEM-EDS), atomic force microscopy (AFM), X-ray diffraction (XRD) and the optical transmission method. From SEM-EDS the total amount of Tb concentration was determined. XRD analysis revealed the existence of crystalline TiO2 in the form of anatase and rutile, depending on Tb amount in the examined samples. The optical transmission method has shown that Tb doping shifts the fundamental absorption edge of TiO2 toward the longer wavelength region.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
335--340
Opis fizyczny
Bibliogr. 14 poz.
Twórcy
autor
autor
autor
autor
- Faculty of Microsystem Electronics and Photonics, Wrocław University of Technology, Janiszewskiego 11/17, 50-372 Wrocław, Poland
Bibliografia
- [1] DOMARADZKI J., BORKOWSKA A., KACZMAREK D., PROCIÓW E., Transparent oxide semiconductors based on TiO2 doped with V, Co and Pd elements, Journal of Non-Crystalline Solids 352(23–25), 2006, pp. 2324–7.
- [2] DIEBOLD U., The surface science of titanium dioxide, Surface Science Reports 48(5–8), 2003, pp. 53–229.
- [3] JIA CH., XIE E., PENG A., JIANG R., YE F., LIN H., XU T., Photoluminescence and energy transfer of terbium doped titania film, Thin Solid Films 496(2), 2006, pp. 555–9.
- [4] MOON B.K., JEONG J.H., YI S.-S., KIM S.C., CHOI H., KIM J.H., Anomalous Tb3+ luminous spectrum in the TiO2 nanocrystals, Optical Materials 28(6–7), 2006, pp. 676–80.
- [5] ZENG Q.G., DING Z.J., ZHANG Z.M., Synthesis, structure and optical properties of Eu3+/TiO2 nanocrystals at room temperature, Journal of Luminescence 118(2), 2006, pp. 301–7.
- [6] QI J., MATSUMOTO T., TANAKA M., MASUMOTO Y., Europium silicate thin films on Si substrates fabricated by a radio frequency sputtering method, Journal of Physics D: Applied Physics 33(6), 2000, pp. 2074–8.
- [7] CHANG C., MAO D., Long lasting phosphorescence of Sr4Al14O25:Eu2+, Dy3+ thin films by magnetron sputtering, Thin Solid Films 460(1–2), 2004, pp. 48–52.
- [8] DOMARADZKI J., KACZMAREK D., PROCIOW E.L., BORKOWSKA A., SCHMEISSER D., BEUCKERT G., Microstructure and optical properties of TiO2 thin films prepared by low pressure hot target reactive magnetron sputtering, Thin Solid Films 513(1–2), 2006, pp. 269–74.
- [9] THORNTON J.A., Influence of apparatus geometry and deposition conditions on the structure and topography of thick sputtered coatings, Journal of Vacuum Science and Technology 11(4), 1974, pp. 666–70.
- [10] MUSIL J., Low-pressure magnetron sputtering, Vacuum 50(3–4), 1998, pp. 363–72.
- [11] Powder Diffraction File, Joint Committee on Powder Diffraction Standards ASTM, Philadelphia, PA, 1967, Card 21-1272.
- [12] Powder Diffraction File, Joint Committee on Powder Diffraction Standards ASTM, Philadelphia, PA, 1967, Card 21-1276.
- [13] TAUC J., GRIROROVICI R., VANCU A., Optical properties and electronic structure of amorphous germanium, Physica Status Solidi A, 1966, pp. 627–37.
- [14] SWANEPOEL R., Determination of the thickness and optical constants of amorphous silicon, Journal of Physics E: Scientific Instruments 16(12), 1983, pp. 1214–22.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW6-0011-0002