Coordination behaviour of N,N'-diallylpiperazinium(+2) and N-allylhexamethylenetetraminium in their crystalline pi-complexes with ionic copper(I) salts

• Autorzy: Shkurenko O. , Kinzhybalo V. , Lis T. , Ciunik Z. , Myskiv M.
• Języki publikacji: EN

Abstrakty

EN

This brief review discusses the coordination behaviour of π-coordinated copper(I) in the structures of [Cu2(μ-dapp)(NH2SO3)4]·2H2O (1), [C4H12N2][Cu2(μ-dapp)(NH2SO3)6]·2H2O (2), [Cu2(μ-dapp)(H2O)6] (SiF6)2·2H2O (3), [Cu2(μ-dapp)(NO3)4(H2O)2]·2H2O (4), [Cu(μ-ahmta)(NO3)(H2O)](NO3)·H2O (5), and [Cu(μ-ahmta)(H2O)2](BF4)2·H2O (6) complexes (dapp = N,N′-diallylpiperazinium(2+), ahmta = N-allylhexamethylenetetraminium), obtained as single crystals by means of an alternating current electrochemical technique. The above π-complexes are formed respectively by CuSO3NH2, Cu2SiF6, CuNO3, and CuBF4 salts, unknown in a free state.

Słowa kluczowe

EN

diallylpiperazinium(2+); N-allylhexamethylenetetraminium; copper complexes

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2005
• Tom: Vol. 23, No. 3
• Strony: 743--756
• Opis fizyczny: Bibliogr. 30 poz., rys., tab.

Twórcy

autor

Shkurenko O.

autor

Kinzhybalo V.

autor

Lis T.

autor

Ciunik Z.

autor

Myskiv M.

• Department of Chemistry, Ivan Franko National University, Kyryla and Mefodiya 6, 79005 Lviv, Ukraine 50-383 Wroclaw,,

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