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Thermal decomposition of silica-methyltrimethoxysilane hybrid glasses studied by mass spectrometry

Wybrane pełne teksty z tego czasopisma
Identyfikatory
Warianty tytułu
Konferencja
7th Seminar Porous Glasses - Special Glasses PGL, 2005, Szklarska Poręba, Poland, September 10-14, 2005 r.
Języki publikacji
EN
Abstrakty
EN
Organically modified silicates (hybrid glasses) have attracted much attention in recent years because they are considered to be promising materials with easy tailorable new properties. The structure of hybrid glass is a silica network with incorporated organic particles or chains. A sol-gel process is a convenient method for preparing bulk glasses, as well as films and layers. The main advantage of the sol-gel technique is high homogeneity and purity of synthesised material. The sol-gel is the only method giving possibility to introduce organic molecules into the inorganic network on the molecular level. Incorporated organic molecules influence mechanical, optical and thermal properties of the silica network. Series of glasses with different amount of methyltrimethoxysilane have been prepared and characterised. Thermal decomposition of methyl modified silica hybrid glasses have been studied by DTA, FTIR and mass spectrometry.
Czasopismo
Rocznik
Strony
901--906
Opis fizyczny
Bibliogr. 10 poz.
Twórcy
autor
  • Faculty of Materials Science and Ceramics, AGH-University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków
autor
  • Faculty of Materials Science and Ceramics, AGH-University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków
autor
  • Faculty of Materials Science and Ceramics, AGH-University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków
Bibliografia
  • [1] Schmidt H., New type of noncrystalline solids between inorganic and organic materials, Journal of Non Crystalline Solids 73(1-3), 1985, pp. 681-91.
  • [2] Huang H.H., Orler B., Wilkes G.L., Structure-property behavior of new hybrid materials incorporating oligomeric species into sol-gel glasses. 3. Effect of acid content, tetraethoxysilane content, and molecular weight ofpoly(dimethylsiloxane), Macromolecules 20(6), 1987, pp. 1322-30.
  • [3] Guo L., Hyeon-Lee J., Beaucage G., Structural analysis of poly(dimethylsiloxane) modified silica xerogels, Journal of Non Crystalline Solids 243(1), 1996, pp. 61-9.
  • [4] Reisfeld R., Prospects of sol-gel technology towards luminescent materials, Optical Materials 16(1-2), 2001, pp. 1-7.
  • [5] PoPALL M., Buestrich R., Semrau G., Eichinger G., Andrei M., Parker W.O., Skaarup S., West K., New polymer lithium secondary batteries based on ORMOCER® electrolytes-inorganic-organic polymers, Electrochimica Acta 46(10-11), 2001, pp. 1499-508.
  • [6] Uhlmann D.R., Suratwala T., Davidson K., Boulton J.M., Teowee G., Sol-gel derived coatings on glass, Journal of Non Crystalline Solids 218, 1997, pp. 113-22.
  • [7] Messaddeq S.H., Pulcinelli S.H., Santilli C.V., Guastaldi A.C., Messaddeq Y.,Microstructure and corrosion resistance of inorganic-organic (ZrO2-PMMA) hybrid coating on stainless steel, Journal of Non Crystalline Solids 247, 1999, pp. 164-70.
  • [8] Nivens D.A., Zhang Y., Angel S.M., A fiber-optic pH sensor prepared using a base-catalyzed organo-silica sol-gel, Analytica Chimica Acta 376(2), 1998, pp. 235-45.
  • [9] NIST Chemistry WebBook, http://webbook.nist.gov/chemistry.
  • [10] CoLTHUP N.B., Daly L.H., Wiberley S.E., Introduction to Infrared and Raman Spectroscopy, Academic Press, N.Y. 1964.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW1-0020-0034
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