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Organic-inorganic hybrid electrolytes for thin film metal oxide electrochromic coatings

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Języki publikacji
EN
Abstrakty
EN
Sol-gel derived lithium salt (LiClO4) doped organic-inorganic hybrid electrolytes have been obtained from the tetraethyl orthosilicate (TEOS) and poly(ethylene oxide) (PEO), propylene oxide (PO), ethyl acetoacetate (EAA), propylene carbonate (PC), polyvinyl alcohol (PVA) precursors and have been investigated for morphology and structural properties by SEM/EDS and FTIR spectroscopy. The hybrid materials obtained were amorphous, with structural properties influenced by organic ingredients which had been used, and with the ionic conductivities of 10-4-10-3 Scm-1. When used as electrolytes in the WO3-based thin-film electrochromic coatings, they have proved to be suitable for low-temperature electrochemical applications.
Czasopismo
Rocznik
Strony
887--894
Opis fizyczny
Bibliogr. 24 poz.
Twórcy
  • Institute of Glass and Ceramics, Cravow Branch, ul. Lipowa 3, 30-702 Kraków
  • Faculty of Materials Science and Ceramics, AGH University of Mining and Metallurgy, al. Mickiewicza 30, 30-059 Kraków, Poland
  • Institute of Physics, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
autor
  • Institute of Glass and Ceramics, Cravow Branch, ul. Lipowa 3, 30-702 Kraków
Bibliografia
  • [1] Brodd R.J., Bullock K.R., Leising R.A., Middaugh R.L., Miller J.R., Takeuchi E., Batteries, 1977 to 2002, Journal of the Electrochemical Society 151(3), 2004, pp. K1-11.
  • [2] Zhang J.-G., Benson D.K., Tracy C.E., Deb S.K., Czanderna A.W., Crandall R.S., Optimization study of solid-state electrochromic devices based on WO3/lithium-polymer electrolyte/V2O5 structures, Journal of the Electrochemical Society 141(10), 1994, pp. 2795-800.
  • [3] Gläser H.J., Large Area Glass Coating, Von Ardenne Anlagentechnik GMBH, Dresden 2000.
  • [4] Fan J., Marzke R.F., Sanchez E., Angell C.A., Conductivity and nuclear spin relaxation in superionic glasses, polymer electrolytes and the new polymer-in-salt electrolyte, Journal of Non-Crystalline Solids 172-174, 1994, pp. 1178-89.
  • [5] Shin J.H., Passerini S., PEO-LiN(SO2CF2CF3)2polymer electrolytes, Journal of the Electrochemical Society 151(2), 2004, pp. A238-45.
  • [6] Wang C., Sakai T., Watanabe O., Hirahara K., Nakanishi T., All solid-state lithium-polymer battery using a self-cross-linking polymer electrolyte, Journal of the Electrochemical Society 150(9), 2003, pp. A1166-70.
  • [7] Haas K.-H., Amberg-Schwab S., Rose K., Functionalized coating materials based on inorganic -organicpolymers, Thin Solid Films 351(1-2), 1999, pp. 198-203.
  • [8] Quaranta A., Carturan S., Maggioni G., Ceccato R., Della Mea G., Probing the chemical environment of 3-hydroxyflavone doped ormosils by a spectroscopic study of excited state intramolecular proton transfer, Journal of Non-Crystalline Solids 322(1-3), 2003, pp. 1-6.
  • [9] Dahmouche K., Atik M., Mello N.C., Bonagamba T.J., Panepucci H., Aegerter M.A., JUDEINSTEIN P., Investigation of new ion-conducting ORMOLYTES: structure and properties, Journal of Sol-Gel Science and Technology 8(1-3), 1997, pp. 711-15.
  • [10] Miyake N., Wainright J.S., Savinell R.F., Evaluation of a sol-gel derived Nafion/silica hybrid membrane for proton electrolyte membrane fuel cell applications: I. Proton conductivity and water content, Journal of the Electrochemical Society 148(8), 2001, pp. A898-904.
  • [11] Nakajima H., Nomura S., Sugimoto T., Nishikawa S., Honma I., High temperature proton conducting organic/inorganic nanohybrids for polymer electrolyte membrane, Journal of the Electrochemical Society 149(8), 2002, pp. A953-9.
  • [12] Dahmouche K., Santilli C.V., Da Silva M.A., Ribeiro C.A., Pulcinelli S.H., Craievich A.F., Silica-PEG hybrid ormolytes: structure and properties, Journal of Non-Crystalline Solids 247, 1999, pp. 108-13.
  • [13] Gunzler H., Gremlich H.-U., IR Spectroscopy - An Introduction, Wiley-VCH Verlag GmbH, Weinheim 2002.
  • [14] Ying J.Y., Benziger J.B., Navrotsky A., Structural evolution of alkoxide silica gels to glass: effect of catalyst pH, Journal of the American Ceramic Society 76(10), 1993, pp. 2571-82.
  • [15] Munro B., Ion-conducting properties of SiO2 gels containing lithium salt, Glass Science and Technology - Glastechnische Berichte 68(4), 1995, pp. 123-32.
  • [16] Primeau N., Vautey C ., Langlet M. , The effect of thermal annealing on aerosol-gel deposited SiO2 films: a FTIR deconvolution study, Thin Solid Films 310(1-2), 1997, pp. 47-56.
  • [17] Pereira A.P.V., Vasconcelos W.L., Orefice R.L., Novelmulticomponentsilicate-poly(vinylalcohol) hybrids with controlled reactivity, Journal of Non-Crystalline Solids 273(1-3), 2000, pp. 180-5.
  • [18] JiTiANU A., Britchi a., Deleanu C., Badescu v., Zaharescu M., Comparative study of the sol-gel processes starting with different substituted Si-alkoxides, Journal of Non-Crystalline Solids 319(3), 2003, pp. 263-79.
  • [19] Sreekanth T., Jaipal Reddy M., Subramanyam S., Subba Rao U.V., Ion conducting polymer electrolyte films based on (PEO+KNO,) system and its application as an electrochemical cell, Materials Science and Engineering B : Solid State Materials for Advanced Technology 64(2), 1999, pp. 107-12.
  • [20] ŻELAZOWSKA E., Ziemba B., Lachman W., Counter electrodes for WO3-based electrochromic coatings, Optica Applicata 30(4), 2000, pp. 663-70.
  • [21 ] Walker CH.W. Jr, Salomon M. , Improvement of ionic conductivity in plasticized PEO-based solid polymer electrolytes, Journal of the Electrochemical Society 140(12), 1993, pp. 3409-12.
  • [22] Yang X.Q., Lee H.S., Hanson L.K., McBreen J., Xu Z.S., Skotheim T.A., Okamoto Y., Lu F., X-ray absorption studies of the effect of plasticizers on ion-pair dissociation in a poly(ethylene oxide)-potassium salt complex, Journal of the Electrochemical Society 142(1), 1995, pp. 46-51.
  • [23] Yoffe A.D., Electronic properties of low dimensional solids: The physics and chemistry of layer type transition metal dichalcogenides and their intercalate complexes, Solid State Ionics 39(1-2), 1990, pp. 1-7.
  • [24] Doi A., Free volumes in several ion-conducting glasses, Journal of Non-Crystalline Solids 246(1-2), 1999, pp. 155-8.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW1-0020-0032
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