Spectroscopic studies of the copper-cadmium halide photochromic glasses

• Autorzy: Marczuk K. , Mirowska N.
• Konferencja: 7th Seminar Porous Glasses - Special Glasses PGL, 2005, Szklarska Poręba, Poland, September 10-14, 2005 r.
• Języki publikacji: EN

Abstrakty

EN

The spectra of optical absorption, luminescence excitation and photoluminescence in the range of 200-750 nm in the Cu-Cd-photochromic glasses were measured. As a matrix of photochromic glass the sodium-borosilicate glass was used. The absorption within the UV wavelength range (200-300 nm) is connected to various structural defects of the matrix glass. The changes of the optical absorption and photoluminescence excitations resulting from the UV radiation in the Cu-Cd-photochromic glasses have been analysed. It was noticed the share of the matrix glass structure components in creation of the colour centers stable of room temperature.

Słowa kluczowe

EN

copper-cadmium photochromic glass; optical absorption; luminescence excitation; structure defects

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2005
• Tom: Vol. 35, nr 4
• Strony: 859--867
• Opis fizyczny: Bibliogr.18 poz.

Twórcy

autor

Marczuk K.

• Institute of Physics, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław

autor

Mirowska N.

• Institute of Physics, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław

Bibliografia

• [1] Araujo R.J., Borrelli N.F., Diffusion-model interpretation of the darkening and fading of photochromic glasses, Journal of Applied Physics 47(4), 1976, pp. 1370-3.
• [2] Tick P.A., Nolan D.A., Polarization effects in stretched copper cadmium chloride photochromic glasses, Journal of Non-Crystalline Solids 33(3), 1979, pp. 383-90.
• [3] Kraevskii S.L., Solinov V.F., Zyabnev A.M., Spectral Hole Burning in the Exciton Line of CuCl Microcrystals in Glasses and the Nature of Photochromic Effect, Glass Physics and Chemistry 24(6), 1998, pp. 501-7 (original: Fizika i Khimiya Stekla 24(6), 1998, pp. 711-20).
• [4] Trotter D.M. Jr., Schreus J.W.H., Tick P.A., Copper-cadmium halide photochromic glasses: evidence for a colloidal darkening mechanism, Journal of Applied Physics 53(7), 1982, pp. 4657-72.
• [5] Tsekhomskii V.A., Fotokhromnye oksidnye stekla, Fizika i Khimiya Stekla 4(1), 1978, pp. 3-21 (in Russian).
• [6] Rysiakiewicz-Pasek E., Marczuk K., Ziemba B., Studies of the properties of copper-cadmium photochromic glasses, Optica Applicata 30(4), 2000, pp. 671-6.
• [7] Marczuk K., Ziemba B., Badanie kinetyki odbarwiania szkła fotochromowego halogenkowo -miedziowo-kadmowego, Ceramika 54, 1997, pp. 155-60.
• [8] Golubkov V.V., Tsekhomskii V.A., Role of sodium chloride in the formation of a light-sensitive phase in copper halide photochromic glass, Soviet Journal of Glass Physics and Chemistry 12(2), 1986, pp. 111-19 (original: Fizika i Khimiya Stekla 12(2), 1986, pp. 206-15).
• [9] Golubkov V.V., Ekimov A.I., Onushchenko A.A., Tsekhomskii V.A., Growth kinetics of CuCl microcrystals in a glassy matrix, Soviet Journal of Glass Physics and Chemistry 7(4), 1981, pp. 265-9 (original: Fizika i Khimiya Stekla 7(4), 1981, pp. 397-401).
• [10] Golubkov V.V., Tsekhomskii V.A., Composition and structure of copper halide phase in sodium and potassium aluminoborosilicate glasses, Glass Physics and Chemistry 24(1), pp. 41-6 (original: Fizika i Khimiya Stekla 24(1), 1998, pp. 63-71).
• [11] Gross E.F., Kaplanskij A.A., Spektroskopicheskoe issledovaniepogloshcheniia i liuminestsentsii khloristoi medi, vvedennoi v kristall kamennoi soli, Optika i Spektroskopiya 2(2), 1957, pp. 204-9 (in Russian).
• [12] Ekimov A.I., Onushchenko A.A., Tsekhomskii V.A., Eksitonnoe pogloshchenie kristallami CuCl v ctekloobraznoi matritse, Fizika i Khimiya Stekla 6(4), 1980, pp. 511-2.
• [13] Valov P.m., Gracheva L.V., Leiman V.I., Negovorova T.A., Tsekhomskii V.A., Exciton luminescence of CuCl microcrystals in glass, Fizika i Khimiya Stekla 19(4), 1993, pp. 578-85 (in Russian).
• [14] Trukhin A.N., Boganov A.G., Praulin'sh A.M., Nature of luminescence centers (396and 280 nm) in vitreous silica, Soviet Journal of Glass Physics and Chemistry 5(3), 1979, pp. 307-13 (original: Fizika i Khimiya Stekla 5(3), 1980, pp. 346-53).
• [15] Tohmon R., Shimogoichi Y., Munekuni S., Ohki Y., Nagasawa K., Sakurai Y., Hama Y., Red luminescence in pure silica glass, Proceedings of the SPIE 1128, 1989, pp. 198-204.
• [16] Belous V.M., Dolbinova E.A., Orlovskaya N.A., Tsekhomskii V.A., Luminescent study of photochromic glasses based on a silver halide, Zhurnal Prikladnoi Spektroskopii 20(6), 1974, pp. 1000-5.
• [17] Kraevskii S.L., Zyabnev A.M., Solinov V.F., Radiation-induced formation of color centers and Cl2 molecules in phosphate and halide-containingphosphate glasses, Glass Physics and Chemistry 23(1), 1997, pp. 74-9 (original: Fizika i Khimiya Stekla 23(1), 1997, pp. 108-15).
• [18] Kraevskij S.L., Solinov V.F., Zyabnev A.M., Abdrashitova E.I., Optical and electron paramagnetic resonance spectra of defects induced by ultraviolet irradiation in glasses containing oxides of cadmium and zinc, Fizika i Khimiya Stekla 21(4), 1995, pp. 330-44 (in Russian).