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Tytuł artykułu

Microwave assisted synthesis using catalysts on controlled pore glass carriers

Wybrane pełne teksty z tego czasopisma
Identyfikatory
Warianty tytułu
Konferencja
7th Seminar Porous Glasses - Special Glasses PGL, 2005, Szklarska Poręba, Poland, September 10-14, 2005 r.
Języki publikacji
EN
Abstrakty
EN
Due to their beneficial features, TRISOŽ-controlled pore glass carriers are very well suited for the preparation of catalysts for application in technically important reactions, e.g., C-C-coupling processes of the Suzuki-reaction type or highly selective hydrogenations. We describe here the development of first experiments with an effective and sustainable catalyst system in microwave-assisted syntheses. An essential advantage of porous catalysts prepared using microwave conditions is their reusability after reaction for further processes. The results are promising as regards the inception of a scalable reaction system for application in synthetic reactions using microwave energy.
Czasopismo
Rocznik
Strony
745--752
Opis fizyczny
Bibliogr. 19 poz.
Twórcy
autor
  • VitraBio GmbH, Trobach 2, D-96523 Steinach, Germany
autor
  • VitraBio GmbH, Trobach 2, D-96523 Steinach, Germany
autor
  • Thuringian Institute of Process Engineering for Environment and Energy (VTI) Saalfeld, Wittmannsgereuther Str. 101, D-07318 Saalfeld, Germany
  • Institute of Technical Chemistry and Environmental Chemistry, Friedrich-Schiller-University of Jena, Lessingstr. 12, D-07743 Jena, Germany
autor
  • Institute of Technical Chemistry and Environmental Chemistry, Friedrich-Schiller-University of Jena, Lessingstr. 12, D-07743 Jena, Germany
autor
  • Institute of Technical Chemistry and Environmental Chemistry, Friedrich-Schiller-University of Jena, Lessingstr. 12, D-07743 Jena, Germany
Bibliografia
  • [1] Li J., Mau A.W.-H., Strauss C.R., The use of palladium on porous glass for catalytic coupling reactions, Chemical Communications, No. 14, 1997, pp. 1275-6.
  • [2] Pon R.T., Current Protocols in Nucleic Acid Chemistry, [Eds.] Beaucage S.L., Glick G.D., Bergstrom D.E., Jones R.A., Wiley, New York, 2000, p. 311, 321.
  • [3] http://www.vitrabio-gmbh.com
  • [4] Füllstoff auf Siliziumdioxid-Basis, Verfahren zu seiner Herstellung und seiner Verwendung, EP 0 802 221 A1, Heraeus Kulzer GmbH, 1997.
  • [5] Nüchter M., Müller U., Ondruschka B., Tied A., Lautenschläger W., Microwave-assisted chemical reactions, Chemical Engineering and Technology 26(12), 2003, pp. 1207-16.
  • [6] Nüchter M., Ondruschka B., Bonrath W., Gum A., Microwave assisted synthesis - a critical technology overview, Green Chemistry 6(3), 2004, pp. 128-41.
  • [7] Freitag J., Nüchter M., Ondruschka B., Oxidation of styrene and cyclohexene under microwave conditions, Green Chemistry 5(3), 2003, pp. 291-5.
  • [8] Tietze L.F., Ila H., Bell H.P., Enantioselective palladium-catalyzed transformations, Chemical Reviews 104(7), 2004, pp. 3453-516.
  • [9] Li C.J., "Befreite" Suzuki-Reaktion: Kupplung in Wasser bei hoher Temperatur ohne Übergangsmetallreagens, Angewandte Chemie 115(40), 2003, pp. 5004-6.
  • [10] Miyaura N., Suzuki A., Palladium-catalyzed cross-coupling reactions of organoboron compounds, Chemical Reviews 95(7), 1995, pp. 2457-83.
  • [11] Suzuki A., Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, Journal of Organometallic Chemistry 576(1-2), 1999, pp. 147-68.
  • [12] Wang Y., Sauer D.R., Use of polymer-supported Pd reagents for rapid and efficient Suzuki reactions using microwave heating, Organic Letters 6(16), 2004, pp. 2793-6.
  • [13] Kabalka G.W., Wang L., Pagni R.M., Hair C.M., Namboodiri V., Solventless Suzuki coupling reactions on palladium-doped potassium fluoride alumina, Synthesis, No. 2, 2003, pp. 217-22.
  • [14] Tzschucke C.C., Bannwarth W., Fluorous-silica-supported per fluoro-tagged palladium complexes catalyze Suzuki couplings in water, Helvetica Chimica Acta 87(11), 2004, pp. 2882-9.
  • [15] González-Arellano C., Corma A., Iglesias M., Sánchez F., Improved palladium and nickel catalysts heterogenised on oxidic supports (Silica; MCM-41, ITQ-2, ITQ-6), Advanced Synthesis and Catalysis 346(11), 2004, pp. 1316-28.
  • [16] Nagel U., Roller C., The influence of non-coordinated stereocenters on the enantioselective hydrogenation, Zeitschrift für Naturforschung 53b(2), 1998, pp. 211-23.
  • [17] Nagel U., Roller C., Enantioselective catalytic hydrogenation of unfunctionalized ketones, Zeitschrift für Naturforschung 53b(3), 1998, pp. 267-70.
  • [18] Will H., Scholz P., Ondruschka B., Microwave assisted heterogeneous gas-phase catalysis, Chemical Engineering and Technology 27(2), 2004, pp. 113-22.
  • [19] Reetz M.T., Maase M., Redox-controlled size-selective fabrication of nanostructured transition metal colloids, Advanced Materials 11(9), 1999, pp. 773-7.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW1-0020-0014
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