Evaluation of chemical and physico-chemical indicators of water and bottom macrofauna the Resko Lake on the basis of the European Union Water Framework Directive

• Autorzy: Daniszewski P. , Konieczny R.
• Języki publikacji: EN

Abstrakty

EN

We carried out a detailed study of the kinetics of oxidation of N'-ferrocenylmethyl-N'-phenylbenzohydrazide (FcX) to ferrocenium ion (FcX+) in aqueous and organic mediums. This study using cyclic (CV) and rotating disk electrode (RDE) voltammetry showed that the FcX/FcX+ redox couple is reversible. The N'-ferrocenylmethyl-N'-phenylbenzohydrazide and ferrocenium ion diffusion coefficients (D) were calculated from these results. In addition, the electron transfer rate constant and the exchange current density for the oxidation of ferrocene were determined. A comparison of the kinetic data obtained from the two electrochemical techniques appears to show that the data from the RDE experiments are more reliable because they are collected under strict mass transport control. Have studied lake close to neutral pH - 7.67 to 7.73. All lakes in accordance with the classification of the European Union Water Framework Directive have been included in the first class. The concentration in the surface layer of Ptot. Lake is little differentiated, is at level II quality class according to the classification of the European Union Water Framework Directive. Tested water lakes were changing the concentration of the PO43-diss - these concentrations correspond to water quality from III. The increase of the concentrations of phosphorus in the Lake may indicate a decrease in the amount of oxygen in the waters of the shallow and changes their status to release phosphorus compounds accumulated redox in sediment bottom. In the case of nitrogen-compounds nitrates and nitrites values for these indicators were at level I and II class in all the surveyed lakes in accordance with the classification of the European Union Water Framework Directive. Indicator, which indicates the high productivity of Lake is the biochemical oxygen demand (BOD5). The level of this indicator values on the studied Lake was on level III class. In the remaining Lake oxygen concentration was similar (continued in I class). Fauna of the Resko Lake bottom during summer stagnation was poor in terms of quality, which proves its considerable biological degradation. In terms of the concentration in the test macrozoobenthos Lake dominated, and Oligochaeta, Diptera larvae.

Słowa kluczowe

EN

water; lake; chemical and physico-chemical indicators; macrozoobenthos; European Union Water Framework Directive

• Wydawca: Przedsiębiorstwo Wydawnictw Naukowych "DARWIN"
• Czasopismo: International Letters of Chemistry, Physics and Astronomy
• Rocznik: 2013
• Tom: Vol. 5
• Strony: 86--96
• Opis fizyczny: Bibliogr. 58 poz., tab., rys.

Twórcy

autor

Daniszewski P.

autor

Konieczny R.

• Department of Invertebrate Zoology and Limnology, University of Szczecin, 13 Waska Street, 71-415 Szczecin, Poland,

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