Meso-tetraphenylporphyriniron(iii) chloride catalyzed oxidation of aniline and its substituents by magnesium monoperoxyphthalate in aqueous acetic acid medium

• Autorzy: Raja M. , Kulandaivelu K.
• Języki publikacji: EN

Abstrakty

EN

The catalytic properties of the fi rst generation catalyst meso-tetraphenylporphyriniron(III) chloride and magnesium monoperoxyphthalate (MMPP) as oxidant have been studied in the oxidation of aniline and its substituents in acetic acid medium. The thermodynamic parameters for the oxidation have been determined and discussed. It confi rms the Exner relationship (only at the low range of temperatures) and also some of the activation parameters to the isokinetic relationships. The magnesium monoperoxyphthalate oxidation with 18 ortho- meta- and para-substituted anilines fulfi lls with isokinetic relationship but not to any of the linear free energy relationships. The reaction mechanism and the rate law were proposed.

Słowa kluczowe

EN

Aniline oxidation; kinetics; mechanism; magnesium monoperoxyphthalate; meso-tetraphenylporphyriniron(III) chloride; catalyst

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2012
• Tom: Vol. 14, nr 4
• Strony: 35--41
• Opis fizyczny: Bibliogr. 26 poz., tab., rys.

Twórcy

autor

Raja M.

autor

Kulandaivelu K.

• Sona College of Technology, Department of Chemistry, Salem – 636005, Tamilnadu, India,

Bibliografia

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