Synthesis and Spectral Studies of Ru(II) Carbonyl Schiff Base Complexes

• Autorzy: Prabhakaran B. , Santhi N. , Emayavaramban M.
• Języki publikacji: EN

Abstrakty

EN

The synthesis and characterization of hexa co-ordinated ruthenium(II) complexes of the type [Ru(CO)(B)(L)] (where B = PPh3, AsPh3, py or pip and L = dibasic tetradentate Schiff base ligand) were synthesized from the reaction of [RuHCl(CO)(B)(EPh3)2] (where E = P, B = PPh3, py or pip, E = As, B = AsPh3) with different tetradentate ligands. The ligands were derived by the condensation of 5-chloro-4-methyl-2-hydroxy benzophenone with ethylenediamine, propylenediamine and o-phenylene-diamine in 1:1 molar ratio. All the compounds have been characterized by elemental analysis and spectral (FT-IR, UV-VIS and 1H-NMR) methods. An octahedral environment around Ru(II) ion has been tentatively proposed for all the complexes.

Słowa kluczowe

EN

Schiff base; ruthenium(II) complexes; tetradentate ligands; octahedral environment

• Wydawca: Przedsiębiorstwo Wydawnictw Naukowych "DARWIN"
• Czasopismo: International Letters of Chemistry, Physics and Astronomy
• Rocznik: 2013
• Tom: Vol. 3
• Strony: 53--66
• Opis fizyczny: Bibliogr. 27 poz., tab.

Twórcy

autor

Prabhakaran B.

autor

Santhi N.

autor

Emayavaramban M.

• Department of Research & Development, Emcure Pharmaceuticals Ltd, Pune - 411057, India,

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