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Abstrakty
The results of the studies on the synthesis, mechanical and thermal properties of polypropylene composites with various amount of halloysite filler are presented. Halloysite (HNT) belongs to the silica type characterized by a two-layer 1:1 structure. This work was aimed to develop a method for the modification of halloysite in its prime use as a filler for polypropylene by extrusion. The composites contain 1, 3, 5 and 7 wt.% of HNT. The degree of crystallinity of the composites decrease with increasing halloysite content. The results confirm the expectations that composites of interesting physicochemical, mechanical and thermal properties can be obtained. The mechanical properties studied show that the filler modification method used leads to the synthesis of polymer composites of improved thermal and mechanical properties.
Czasopismo
Rocznik
Tom
Strony
61--65
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
Twórcy
autor
autor
- Industrial Chemistry Research Institute, ul. Rydygiera 8, 01-793 Warszawa, Poland, Agnieszka.Szczygielska@ichp.pl
Bibliografia
- 1. Sarbak, Z. (2005). Clay minerals. LAB Laboratorium, Aparatura, Badania, 3, 9–17 (in Polish).
- 2. Sarbak, Z. (2005). Natural silicates and aluminosilicates. LAB Laboratorium, Aparatura, Badania 2, 16–21 (in Polish).
- 3. Hendricks, S.B. & Jefferson, M.E. (1938). American Mineralogist, 23(12), 863–875.
- 4. Veerabadran, N.G., Price, R.R. & Lvov, Y.M. (2007). Nano: Brief Reports and Reviews, 2 (2), 115–120.
- 5. Ruiz-Hitzky, E., Ariga, K. & Lvov, Y. (2007). Bio-Inorganic Hybrid Nanomaterials, Wiley: London, Berlin, 14, pp. 419–441.
- 6. Lvov, Y.M., Shchukin, D.G., Möhwald, H. & Price, R.R. (2008). ACS Nano 2 (5), 814–820.
- 7. http://www.intermark.pl/haloizyt.html
- 8. Szczygielska, A. & Kijeński, J. (2010). The application of halloysite as a filler for modification of polypropylene. Part I. The characteristics of halloysite as a filler. Composites, 10(2), 181–185 (in Polish).
- 9. Ullmans's Encyclopedia of Industrial Chemistry 2002, (6th ed.) (Thermoplastic Materials).
- 10. Rothon, R.N. (2003), Particulate-filled polymer composites, Rapra Technology Ltd, (2nd ed.)
- 11. Kurzeja, L., Gibas, E. & Kubica, S. (2008). Polypropylene with powder carbon filler-shungite. Composites 8 (4), 414–418 (in Polish).
- 12. Jeziórska, R., (2008). Effect of poly(butylene terephthalate) functionalized with 2,2'-(1,3-phenylene)-bis(2-oxazoline) on the structure and properties of polyamide 6 blends with textile waste containing poly(ethylene terephthalate). Polimery, 53 (3), 201–207 (in Polish).
- 13. Du, M.L., Guo, B.C. & Jia, D.M. (2006). Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene), Eur. Polym J., 42, 6, 1362–1369. doi:10.1016/j.eurpolymj.2005.12.006.
- 14. NanturalNano Inc., NaturalNano successfully trials halloysite nanotubes in polypropylene, Plastics Additives & Compounding May/June 2007, 12.
- 15. Ning, N.-Y. (2007). Crystallization behavior and mechanical properties of polypropylene/halloysite composites, Polymer, 48, 25, 7374–7384.
- 16. Liu, M., Guo, B., Lei, Y., Du, M. & Jia, D. (2009). Benzothiazole sulfide compatibilized polypropylene/halloysite nanotubes composites, Appl. Surf. Sci., 255, 4961–4969. doi:10.1016/j.apsusc.2008.12.044.
- 17. Liu, M, Jia, Z., Liu, F., Jia, D. & Guo, B. (2010). Tailoring the wettability of polypropylene surfaces with halloysite nanotubes, J. Colloid Interf. Sci., 350, 186–193. doi:10.1016/j.jcis.2010.06.047.
- 18. Koszkul, J., Polypropylene and its composites, Monograph Czestochowa Uniwersity of Technology, 1997, 50, pp.87 (in Polish).
- 19. Collected Applications Thermal Analysis Thermoplastics, Mettler Toledo 2003, pp. 59–60.
- 20. Sorrentino, L. et al., (2009). Nano/microcomposites based on PP, nanoclay, and CaCO3, J. Appl. Polym. Sci., Wiley Periodicals, Inc., 113(5), 3362, doi: 10.1002/app.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS3-0020-0046