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Polyetherols from melamine cyanurate and ethylene carbobate – synthesis and application

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The results of the study on the reactions of melamine cyanurate with ethylene carbonate were presented. As a result of the reactions, polyetherols containing thermostabile 1,3,5-triazine and perhyroxo-1,3,5-triazine rings in their structure were obtained. Basic physical properties such as density, viscosity, hydroxyl number, weight changes were measured. The polyetherols were applied as a polyol component to receiving of thermoresistant polyurethane foams. Some of the properties of the obtained foams were investigated. The value of the apparent density is between 51 and 71 kg/m3, compressive strength 222–356 kPa and the content of the open pores between 14–33%. Thermal resistance was also studied by means of the TGA method. It was found that oxygen index of the selected compositions is between 20–22%.
Rocznik
Strony
42--46
Opis fizyczny
Bibliogr. 17 poz., rys., tab.
Twórcy
autor
autor
  • Department of Polyester, Epoxides and Polyurethanes, Industrial Chemistry Research Institute, ul. Rydygiera 8, 01-793 Warszawa, Poland, dorota.kijowska@ichp.pl
Bibliografia
  • 1. Casu, A., Camino, G., De Giorgi, M., Flath, D., Morone, V., Zenoni, R., Fire-retardant mechanistic aspects of melamine cyanurate in polyamide copolymer. Polym. Degrad. Stab., 58 (1997), 297–302, DOI:10.1016/S0141-3910(97)00061-X.
  • 2. Roland, W., Reinhard, B., Andreas, D. (2007). EP No. 1731559. European Patent Office.
  • 3. Morival, G., Hervy, C. (1988). US Patent No. 4786673. Washington, D.C.: U.S. Patent and Trademark Office.
  • 4. Kasowski, R., Martens, M. (2000). US Patent No. 3,025,419. Washington, D.C.: U.S. Patent and Trademark Office.
  • 5. Modesti, M., Lorenzetti, A., Simioni, F. and Checchin, M. (2001). Influence of different flame retardants on fire behaviour of modified PIR/PUR polymers. Polym. Degrad. Stab. 74(3), 475–479, DOI:10.1016/S0141-3910(01)00171-9.
  • 6. Zatorski, W., Brzozowski, Z. (2003). Pol. Patent No. 198605. Warsaw, Patent Office of The Republic of Poland.
  • 7. Mazo, G.Y., Ross, R.J., Kneller, J.F., Mazo, J. (1999). U.S. Patent No. 5,939,517. Washington, D.C.: U.S. Patent and Trademark Office.
  • 8. Klimiec, J., Fabisz, E., Researches on synthesis of propylene carbonate. Chem. Ind. 79 (10) 339–340 2000.
  • 9. Clements, J.H. Reactive Applications of Cyclic Alkylene Carbonates. Ind. Eng. Chem. Res. (2003). 42 (4), pp 663–674, DOI: 10.1021/ie020678i.
  • 10. Kowalski, P. (2004). Laboratory of Organic Chemistry; WNT: Warsaw, (in Polish).
  • 11. Kocot-Bończak, D. (1977). Laboratory Experiments in Physical Chemistry PZWL: Warsaw, (in Polish).
  • 12. Polish Committee for Standardization (1993). Polish Standards: Polyethers for polyurethanes – Test methods-Determination of hydroxyl number. PN-C-89052-03: Method A. Poland.
  • 13. Polish Committee for Standardization (1999). Polish (European) Standards: Products for thermal insulation for building – Determination of apparent density. PN-EN 1602. Poland.
  • 14. Polish Committee for Standardization (1998). Polish (European) Standards: Products for thermal insulation for building – Determination of behavior during compression. PN-EN 826. Poland.
  • 15. Polish Committee for Standardization (2005). Polish Standards: Rigid porous plastics – Determination of percentage volumetric content of open and closed cells. PN-ISO 4590. Poland.
  • 16. Polish Committee for Standardization (2006). Polish (European) Standards: Plastics – Determination of flammability by oxygen index – Part 2: Test at room temperature. PNEN ISO 4589-2. Poland.
  • 17. Mc Entire, E.E., Gipson, R.M. (1981). U.S. Patent No. 4 265 821 Washington, D.C.: U.S. Patent and Trademark Office.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS3-0020-0042
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