Utilization of waste chloroorganic compounds

• Autorzy: Myszkowski J. , Milchert E. , Bartkowiak M. , Pełech R.
• Języki publikacji: EN

Abstrakty

EN

Efficient methods of utilization of waste chloroorganic compounds coming from waste water and the waste streams formed e.g. in the production of vinyl chloride by dichloroethane method and in the production of propylene oxide by chlorohydrin method have been presented. First the separation of chloroorganic wastes by the adsorption methods has been described in the article. Three valuable methods of hlorocompounds utilization have been then discussed. The first one is isomerization of 1,1,2-trichloroethane to 1,1,1- trichloroethane as the valuable product with less toxicity than a substrate. The second method is ammonolysis of waste 1,2-dichloropropane and 1,2,3-trichloropropane. The third described method is chlorolysis. This method can be used for the utilization of all types of waste chloroorganics.

Słowa kluczowe

EN

adsorption; amonolysis; chloroorganic compounds; isomerization; chlorolysis

PL

adsorpcja; amonolizy; związki chloroorganiczne; izomeryzacja; chloroliza

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2010
• Tom: Vol. 12, nr 3
• Strony: 36--39
• Opis fizyczny: Bibliogr. 13 poz., rys., tab.

Twórcy

autor

Myszkowski J.

autor

Milchert E.

autor

Bartkowiak M.

autor

Pełech R.

• West Pomeranian University of Technology, Szczecin, Institute of Chemical Organic Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland,

Bibliografia

• 1. Milchert, E. (1997). Technologies of the production of chloroorganic compounds. Waste utilization. Szczecin, WUPS. (in Polish)
• 2. Milchert, E., Bartkowiak, M., Pełech, R. (2008). Progress in selected technologies of chemical industry. Szczecin, WUPS. (in Polish)
• 3. Pełech, R., Milchert, E. & Wróbel, R. (2006). Adsorption dynamics of chlorinated hydrocarbons from multi-component aqueous solution onto activated carbon. J. Hazard. Mater. 137, 1479 – 1487. DOI: 5551 10.1016/j.jhazmat.2006.04.023S0304-3894(06)00394-3.
• 4. Pełech, R., Milchert, E. & Bartkowiak, M. (2006). Fixedbed adsorption of chlorinated hydrocarbons from multi-component aqueous solution onto activated carbon. Equilibrium column model. J. Colloid Interf. Sci. 296, 458 – 464. DOI: 11656 10.1016/j.jcis.2005.09.020 S0021-9797(05)00954-9.
• 5. Myszkowski, J., Pełech, R., Wróblewska, A. & Milchert, E. (2006). Creating the environmentaly friendly technologies by utilization of waste and wastewater. Przem. Chem. 85, 638 – 640. (in Polish)
• 6. Myszkowski, J., Milchert, E., PaŸdzioch, W. & Pełech, R., (2007). Formation of environmental friendly technology by sewage and by-products utilization, P.J. Chem. Tech. 9 (3), 118– 121.
• 7. Bartkowiak, M., Lewandowski, G. & Milchert, E., (2004). Technological parameters of the ammonolysis of waste 1,2-dichloropropane, Journal of Hazardous Materials, 106(2-3), 107 – 114. DOI: 10.1016/j.jhazmat.2003.10.003 S0304-3894(03)00381-9
• 8. Bartkowiak, M., Lewandowski, G., Milchert, E. & Pełech, R. (2006). Optimization of 1,2-diaminopropane preparation by the ammonolysis of waste 1,2-dichloropropane, Ind. Eng. Chem. Res. 45, 5681 – 5687. DOI: 10.1021/ie051134u.
• 9. Bartkowiak, M., Pełech, R. & Milchert, E., (2006). Ammonolysis of (3-chloropropyl)trimethoxysilane, J. Hazard. Mater. 136(3), 854 – 858. DOI: 5317 10.1016/j.jhazmat.2006.01.024 S0304-3894(06)00038-0.
• 10. Bartkowiak, M. & Milchert, E., (2003). Properties and applications of 1,2-diaminopropane and polypropylenepolyamines, Przem. Chem. 82, 277 – 281.
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• 12. Fathepure, B.Z., Tiedje, J.M. & Boyd, S.A., (1988). Reductive dechlorination of hexachlorobenzene to tri- and dichlorobenzenes in anaerobic sewage sludge, Appl. Env. Microbiol. 54(2), 327-330. DOI: 0099-2240/88/020327-04$02.00/0.
• 13. Booker, R.S. & Pavlostathis, S.G., (2000). Microbial reductive dechlorination of hexachloro-1,3-butadiene in a methanogenic enrichment culture, Water Res. 34(18), 4437-4445. DOI:10.1016/S0043-1354(00)00214-1.