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The photocatalytic reduction of carbon dioxide with hydrogen was studied by Temperature-Programmed Surface Reaction (TPSR). This process was carried out in a flow reactor that was especially designed and constructed for this purpose. Titanium dioxide (TiO2, Degussa P-25) was used as supports for platinum, ruthenium and nickel catalysts. The experimental results indicated that the activity of photoreduction of CO2 changes as follows: Ru/TiO2> Ni/TiO2>= Pt/TiO2> TiO2.
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1--2
Opis fizyczny
Bibliogr. 6 poz., rys., tab.
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autor
autor
autor
autor
- Technical University of Lodz, Institute of General and Ecological Chemistry, ul. Żeromskiego 116, 90-924 Łódź, Poland, ikocemba@p.lodz.pl
Bibliografia
- 1. Multi-author work (1994). Carbon dioxide chemistry: Environmental issues, The Society of Chemistry.
- 2. Kocemba., I. (2003). Apparatus for investigation of catalysts by temperature programmed methods – Peak4, Przem. Chem. 3 (82), 142 – 145 (in Polish).
- 3. Paryjczak, T. (1986). Gas chromatography in adsorption and catalysis. PWN, Warszawa (in Polish).
- 4. Kowalczyk, Z. (2008). Supported ruthenium catalysts for selective methanation of carbon oxides at very low COx/H2ratios. Appl. Catal. A, DOI: 342, 35 – 39, 10.1016/j.apcata.2007.12.040.
- 5. Borodziński, A. & Bonarowska, M. (1997). Relation between Crystallite Size and Dispersion on Supported Metal Catalysts. Langmuir, 13, 5613 – 5620, DOI: S0743-7463(96)02103-8 CCC: $14.00.
- 6. Linsebigler, A.L., Lu, G. & Yates, J.T. (1995). Photocatalysis on TiO2 Surfaces: Principles, Mechanisms and Selected Results. Chem. Rev., 95, 735 – 758, DOI: 0009-2665/95/0795-0735$15.50.
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BPS3-0016-0053