Acidic ionic liquids based on phosphonium chloride and metal chlorides – recyclable media and catalysts in the Diels-Alder reaction

• Autorzy: Janus E.
• Języki publikacji: EN

Abstrakty

EN

Acidic ionic liquids based on trihexyltetradecylphosphonium chloride . P 6.6.6.14 Cl and six different metal chlorides (YCl 3 , YbCl 3 , MgCl 2 , ZnCl 2 , CuCl 2 , InCl 3 ) were prepared. The molar fraction of metal chloride (X MClx ) used for the formation of acidic ionic liquids with P 6.6.6.14 Cl was changed in the range from 0.3 to 0.5. The high catalytic activity in the Diels-Alder reaction of cyclopentadiene and various �ż,s-unsaturated carbonyl compounds showed ionic liquids at X MClx.0.4. In general, the highest product yields and endo:exo ratios were achieved in the acidic ionic liquids formed from MgCl 2 , YCl 3 and YbCl 3 . Thermogravimetric analysis suggested that the prepared ionic liquids were thermally stable up to nearly 400�‹C. Additionally, they could be reused with only little loss of catalytic activity after the 4th recycle.

Słowa kluczowe

EN

acidic ionic liquids; Diels-Alder reaction; metal chlorides

PL

kwaśne ciecze jonowe; reakcja Dielsa-Adlera; chlorki metali

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2010
• Tom: Vol. 12, nr 2
• Strony: 33--37
• Opis fizyczny: Bibliogr. 8 poz., rys., tab.

Twórcy

autor

Janus E.

• West Pomeranian University of Technology, Department of Organic Chemical Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland,

Bibliografia

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