A new polyphosphazene-based catalyst for the oxidation of alkenes

• Autorzy: Burczyk A. , Pielichowski J. , Bogdał D.
• Języki publikacji: EN

Abstrakty

EN

In the current work we present synthesis of novel polymeric catalysts and oxidation reactions that represent their catalytic properties. As a support polyphosphazenes were used. The structures of these compounds were investigated by means of IR, EA, 'H NMR, TGA. Oxidation reactions of alkenes were carried out on synthesized polyphosphazene catalyst at atmospheric pressure in the presence of molecular oxygen. Epoxides and ketones were obtained as main product with very high selectivity and high yields.

Słowa kluczowe

EN

oxidation; polyphosphazene based-catalyst; alkenes

PL

utlenianie; polifosfazeny; katalizatory polifosfazenowe; alkeny

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2003
• Tom: Vol. 5, nr 3
• Strony: 96--97
• Opis fizyczny: Bibliogr. 12 poz., rys., tab.

Twórcy

autor

Burczyk A.

autor

Pielichowski J.

autor

Bogdał D.

• Cracow University Of Technology, Departament Of Polymer Chemistry And Technology, 31-155 Kraków, Warszawska 24, Poland

Bibliografia

• (1) H.R. Allcock, lnorganic and organometallic polymers, ACS Symp., 1994, 572, 208.
• (2) H.R. Allcock, Polymer, 1980, 21, 673.
• (3) H.R. Allcock, Polym. Mater. Sci. Eng., 1997, 76, 49.
• (4) H. Ma, H. Li, H. Zhang, J. Wang, F. Li, X. Tang, Materials Chem. And Physics , 2002, 73, 93 - 96.
• (5) R. De Jaeger, M. Gleria, Prog. Polym. Sci., 1998, 23, 179.
• (6) A. Hanusek, D. Bogdał, J. Pielichowski, Annais of the Polish Chemical Society 2001, 214.
• (7) H. R. Allcock, M. Napierala, D. Olmeijer, S. Best, K. Merz, Macromol., 1999, 32, 732.
• (8) J. C. Hutchisan, R. Bissessur, D. F. Shriver, Chem. Mater., 1996, 8, 1597
• (9) M. A. Olshavsky, H. R. Allcock, Chem. Mater., 1997, 9, 1367 .
• (10) R. Graves, P. N. Pintauro, J., Appl. Pol. Sci., 1998, 68, 827.
• 11) H. R. Allcock, Chem. Mater., 1994, 6, 1476.
• (12) H. AIlcock, S. Kuharcik, C. Reed, M. Napierala, Macromol. 1996, 29, 3384.