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Removal of Ni(II) from aqueous solutions using fly ash and montmorillonite

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Adsorption of toxic metal ions like Ni(II) on heat treated montmorillonite, fly ash and impregnated fly ash was studied in terms of different parameters like initial metal ion concentrations, pH and temperature. Impregnated fly ash (IFAA1) showed much higher levels of adsorption capacity as compared to fly ash and heat-treated montmorillonite. The various rate parameters of the adsorption process have also been determined. Equilibrium adsorption model was arrived, based on Langmuir isotherm and the corresponding constants have been evaluated. Thermodynamic studies have also been carried out and values of standard free energy (AG°), enthalpy (AH°) and entropy (AS°) were calculated. The adsorption was found to be exothermic by these studies.
Rocznik
Strony
6--10
Opis fizyczny
Bibliogr. 25 poz., rys., tab.
Twórcy
autor
  • Applied Chemistry Division,Department of Chemical Technology,University of Mumbai,Matunga, Mumbai - 400019, India *To whom Correspondence should be addressed.fax No.- +91-22-414 56 14
autor
  • Applied Chemistry Division,Department of Chemical Technology,University of Mumbai,Matunga, Mumbai - 400019, India *To whom Correspondence should be addressed.fax No.- +91-22-414 56 14
Bibliografia
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  • (4) Huang C. R., Wu M. H., The removal of chromium by adsorption. J. Wat. Poll. Control Fed, 1975, 47, 2437
  • (5) Neufeld R. D., Hermann E. R., Heavy metal removal by activated sludge. J. Wat. Poll. Control Fed, 1975, 47, 310.
  • (6) Weltrowski M., Martel B., Morcellet M., J. Appl. Polym. Sci, 1996, 59, 647.
  • (7) Chu T. J., Steiner G. R., McEntyre C. L., Removal of complex copper- ammonia ions from aqueous solutions with fly ash. J. Wat. Pollut. Control Fed, 1978, 50, 2157.
  • (8) Jain K. K., Singh V. N. & Prasad G., Applications of fly ash instead of activated carbon for oxalic acid removal. J. Chem. Tech. Biotech, 1979, 29, 36.
  • (9) Jain K. K., Singh V. N. & Prasad G., Applications of Langmuir isotherm for oxalic acid adsorption by fly ash & activated carbon. Indian J. Chem, 1980, 19A, 154.
  • (10) Rathore H. S., Sharma S. K., Agarwal M., Adsorption of some organic acids on fly ash impregnated with hydroxides of Al, Cd, Cu, Fe and Ni, Environ. Pollution (Serics B), 1985, 10, 249.
  • (11) Sandell E. B, Colorimetric determination of traces of metals, Interscience Pub, N. Y, 1944.
  • (12) Vogel A. I., Text Book of Qualitative Chemical Analysis, fifth ed., ELBS Publication, London, 1989.
  • (13) Hair M. L., IR Spectroscopy in Surface Chemistry, Academic Press, London, 1967.
  • (14) Anirudhan T. S., Sreedhar M. K., Adsorption Thermodynamics of Co(ll) on Polysulphide treated sawdust, Indian. J. Chem. Tech, 1998, 5, 41.
  • (15) Bhattacharya A. K., Venkobachar C., Removal of cadmium (II) by Iow cost adsorbents. J. Envior. Eng, 1984, 110(1), 110.
  • (16) Yadava K. P., Tyagi B. S., Singh Y. N., Removal of As (III) from aqueous solution by adsorption on china clay. J. Environ. Tech. Lett, 1988, 9(11), 1233.
  • (17) Weber W. J., Morris J. C, Kinetic of adsorption on carbon on solution. J. Sanit. Eng. Div, ASCE, 1963, 89 (SA2), 31.
  • (18) Yadava K. P., Tyagi B. S., Singh Y. N., Fly ash for the treatment of water enriched in lead(ll). J. Envion. Sci. Health, 1989, A24 (7), 783.
  • (19) Brindley, G. W. & Moll, W. F., Jr., Am. Mineralogist, 50, 120, 1335 (1965).
  • (20) Meng. X., Letterman R., Modeling Ion Adsorption on Aluminium Hydroxide Modified Silica, Environ. Sci. Tech, 1993, 27, 1924.
  • (21) Lothenbach B., Furrer G., Schulin R., Immobilization of Heavy Metal by Polynuclear Aluminium and Montmorillonite Compounds. Environ. Sci. Technol, 1997, 31, 1452.
  • (22) Harsh J. B., Doner H. E., Soil. Sci. Soc. Am. J, 1984, 48, 1034.
  • (23) Keizer P., Bruggenwert M. G. M., In Interactions at the Soil Colloid-Soil Solution Interface G. H. Bolt, M. F. De boodt, M. H. B. Hayes, M. B. McBride, Eds: Kluwer Academic Publisher: Dordrecht, 1991, 177.
  • (24) Yadava K. R, Tyagi B. S., & Singh Y. N., Effect of Temperature on the removal of Lead(Il) by adsorption on China Clay and Wollastonite. J. Chem. Tech. Biotech, 1991, 51, 47.
  • (25) Elliot H. A., Huang C. P., Adsorption characteristic of some Cu(ll) complexes on alumino silicates, Water Res, 1981, 15, 849.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS3-0002-0059
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