Solvent-free synthesis and spectral linearity of some (E)-2-(substituted benzylideneamino)-N-(3-chloro-4-fluorophenyl)-hexahydro-2H cyclopenta[b]thiophene-3-carboxamides

Thirunarayanan, G.; Sekar, K. G.

Artykuł - szczegóły

Tytuł artykułu

Solvent-free synthesis and spectral linearity of some (E)-2-(substituted benzylideneamino)-N-(3-chloro-4-fluorophenyl)-hexahydro-2H cyclopenta[b]thiophene-3-carboxamides

Autorzy

Thirunarayanan G. , Sekar K. G.

Treść / Zawartość

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Abstrakty

Some (E)-2-(substituted benzylideneamino)-N-(3-chloro-4-fluorophenyl)-hexahydro-2H-cyclopenta[b]thiophene-3-carboxamide derivatives have been synthesized by SiO2:H3PO4 catalyzed solvent-free condensation of 2-amino-N-(3-chloro-4-fluorophenyl)-hexahydro-2H-cyclopenta [b]thiophene-3-carboxamide and various substituted benzaldehydes in microwave irradiation. The yield of the imine-carboximido derivatives has been found to be more than 85 %. The purity of all imine-carboximido derivatives has been checked using their physical constants and spectral data. The spectral data of the imine-carboximido derivatives such as infrared ? (cm-1) of CO, NH, C-N, C-Cl, C-F, C=N, and the NMR chemical shifts (?, ppm) of NH, CH, CO and C=N have been correlated with Hammett substituent constants, F and R parameters. From the results of statistical analysis, the effects of substituent on the above spectral group absorptions have been discussed.

Słowa kluczowe

Solvent-free condensation SiO2-H3PO4 Imine-carboximido derivatives IR and NMR spectra Hammett correlations

Wydawca

Przedsiębiorstwo Wydawnictw Naukowych "DARWIN"

Czasopismo

International Letters of Chemistry, Physics and Astronomy

Rocznik

2013

Tom

Vol. 8, iss. 2

Strony

160--174

Opis fizyczny

Bibliogr. 72 poz., rys., tab., wykr.

Twórcy

autor

Thirunarayanan G.

autor

Sekar K. G.

Department of Chemistry, Annamalai University, Annamalainagar - 608002, India., drkgsekar@yahoo.co.in

Bibliografia

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