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Simulation and sensitivity analysis for biodiesel production in a reactive distillation column

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The conventional process for biodiesel production by transesterification is still expensive due to a need of high excess of alcohol required and its recovery by distillation. The use of a reactive distillation process can reduce the amount of alcohol in the feed stream as it works on a simultaneous reaction and separation. In the present study, a mathematical model has been developed for biodiesel production from triglycerides in a reactive distillation column, which has been validated with the reported data and CHEMCAD results. The effects of process parameters such as methanol to oil feed ratio, feed temperature, and reaction time have been investigated. The sensitivity analysis shows that yield of ester increases with methanol to oil ratio and number of stages, however, it decreases with fl ow rate. The MATLAB simulated results show that methanol to oil molar ratio of 5:1 produces 90% (by wt.) of methyl ester in a residence time of 4.7 minutes.
Rocznik
Strony
59--65
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
autor
  • Malaviya National Institute of Technology, Department of Chemical Engineering, Jaipur-302017, India, amadhunaresh@gmail.com
Bibliografia
  • 1. Fangrui, M. & Milford, A.H. (1999). Biodiesel production: a review. Bioresource Technology. 70 (1), 1-15. doi:10.1016/ S0960-8524(99)00025-5.
  • 2. Kiss, A.A., Dimian, A.C. & Rothenberg, G. (2008). Biodiesel by catalytic reactive distillation powered by metal oxides. Energy Fuels. 22 (1), 598-604.
  • 3. Giessler, S., Danilov, R.Y., Pisarenko, R.Y., Serafimov, L.A., Hasebe, S. & Hashimoto, I. (2001). Systematic structure generation for reactive distillation processes. Computers& Chemical Engineering. 25 (1), 49-60. doi:10.1016/S0098- 1354(00)00632-3.
  • 4. He, B.B., Singh, A.P. & Thompson, J.C. (2006). A novel continuous-flow reactor using reactive distillation for biodiesel production. Transactions of the ASABE. 49 (1), 107-112.
  • 5. Pai, R.A., Doherty, M.F. & Malone, M.F. (2002). Design of reactive extraction systems for bioproduct recovery. AIChEJournal. 48 (3), 514-526. DOI: 10.1002/aic.690480310.
  • 6. Chin, S.Y., Mohamed, A.R., Ahmad, A.L. & Bhatia, S. (2006). Esterification of palmitic acid with iso-propanol in a catalytic distillation column: Modeling and simulation studies. International Journal of Chemical Reactor Engineering. 4 (4), 32.
  • 7. Kiss, A.A., Omota, F., Dimian, A.C. & Rothenberg, G. (2006). The heterogeneous advantage: biodiesel by catalytic reactive distillation. Topics in Catalysis. 40 (1), 141-150. DOI: 10.1007/s11244-006-0116-4.
  • 8. Omota, F., Dimian, A.C. & Bliek, A. (2003). Fatty acid esterifi-cation by reactive distillation. Chemical Engineering Science. 58, 3159-3174. doi:10.1016/S0009-2509(03)00165-9.
  • 9. He, B.B., Singh, A.P. & Thompson, J.C. (2005). Experimental optimization of a continuous-flow reactive distillation reactor for biodiesel production. Transactions of the ASAE. 48 (6), 2237-2243.
  • 10. Bhatia, S., Ahmad, A.L., Mohamed, A.R. & Chin, S.Y. (2006). Production of isopropyl palmitate in a catalytic distillation column: Experimental studies. Chemical Engineering Science. 61 (22), 7436-7447. doi:10.1016/j.ces.2006.08.039.
  • 11. Singh, A.P., Thompson, J.C. & He, B.B. In A continuous--flow reactive distillation reactor for biodiesel preparation from seed oils, ASAE/CSAE Annual International Meeting, Ottawa, Ontario, Canada, 1-4 August, 2004; Ottawa, Ontario, Canada, 2004. Paper number 046071.
  • 12. Taylor, R. & Krishna, R. (2000). Modelling reactive distillation. Chemical Engineering Science. 55 (22), 5183-5229. doi:10.1016/S0009-2509(00)00120-2.
  • 13. Mattalana, L.G., Gutierrez, L.F. & Cardona C.A. In Biodiesel Production by reactive distillation, R Distillation - enpromer2005.eq.ufrj.br., 2005; 2005; pp 1-9.
  • 14. Thotla, S. & Mahajani, S. (2009). Reactive distillation with side draw. Chemical Engineering and Processing: Process Intensification. 48 (4), 927-937. DOI: 10.1016/j.cep.2008.12.007.
  • 15. Steinigeweg, S. & Gmehling, J. (2003). Esterification of a fatty acid by reactive distillation. Ind. Eng. Chem. Res. 42 (15), 3612-3619.
  • 16. He, B. (2006.). A novel continuous-fl ow reactor using reactive distillation for biodiesel production. A report, National Institute of Advanced Transport Technology, University of Idaho.
  • 17. Santandera, C.M.G., Sandra Marcela Gómez Rueda, Nívea De, Lima da Silvaa, Aline Carvalho da Costa, Rubens Maciel Filhoa, Regina, M. & Maciela., W. (2010). Simulation of the reactive distillation process for biodiesel production. 20th European Symposium on Computer Aided Process Engineering- ESCAPE20.
  • 18. Bambase, M.E., Nakamura, N., Tanaka, J. & Matsumura, M. (2007). Kinetics of hydroxide-catalyzed methanolysis of crude sunfl-ower oil for the production of fuel-grade methyl esters. Journal of Chemical Technology & Biotechnology. 82 (3), 273-280. DOI: 10.1002/jctb.1666.
  • 19. Gupta, S.K., Numerical methods for engineers. New Age International: New Delhi, 2006; p 422.
  • 20. Noureddini, H. & Zhu, D. (1997). Kinetics of transesterification of soybean oil. Journal of the American Oil Chemists’Society. 74 (11), 1457-1463. DOI: 10.1007/s11746-997-0254-2.
  • 21. Freedman, B., Butterfi eld, R.O. & Pyrde, E. (1986). Transesterifi cation kinetics of soybean oil. J. Am. Oil Chem. Soc. 63, 1375-1380. DOI: 10.1007/BF02679606.
  • 22. Darnoko, D. & Cheryan, M. (2000). Kinetics of palm oil transesterification in a batch reactor. Journal of the American Oil Chemists’ Society. 77 (12), 1263-1267. DOI: 10.1007/ s11746-000-0198-y.
  • 23. Simasatitkul, L., Siricharnsakunchai, P., Patcharavorachot, Y., Assabumrungrat, S. & Arpornwichanop, A. (2011). Reactive distillation for biodiesel production from soybean oil. Korean Journal of Chemical Engineering. 28 (3), 649-655. DOI: 10.1007/s11814-010-0440-z.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0067-0011
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