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By combining the van der Waals' equation of state and the Free Length Theory of Jacobson, a new theoretical model is developed for the prediction of internal pressure of pure liquids and liquid mixtures. It requires only the molar volume data in addition to the ratio of heat capacities and critical temperature. The proposed model is simple, reliably accurate and capable of predicting internal pressure of pure liquids with an average absolute deviation of 4.24% in the predicted internal pressure values compared to those given in literature. The average absolute deviation in the predicted internal pressure values through the proposed model for the five binary liquid mixtures tested varies from 0.29% to 1.9% when compared to those of literature values.
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Tom
Strony
1--7
Opis fizyczny
Bibliogr. 18 poz., tab.
Twórcy
autor
autor
autor
autor
autor
- Department of Chemistry, Government Arts College, C.Mutlur, Chidambaram-608102, India, nsaanthi@gmail.com
Bibliografia
- [1] J. H. Hildebrand, R. L. Scott, Solubility of Non-electrolytes, III Edn., Reinhold Publ. Corpn., New York, (1950) p.121.
- [2] J. H. Hildebrand, R. L. Scott, Regular Solutions, Prentice-Hall, Englewood Cliffs, New Jersey, 1962.
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- [7] S. C. Srivastava, N. Berkowitz, Can. J. Chem. 41 (1963) 1787.
- [8] B. Jacobson, Acta Chem. Scand. 6 (1952) 1485.
- [9] B. Jacobson, J. Chem. Phys. 20 (1952) 927.
- [10] N. Santhi, “Ultrasonic velocity, free volume and internal pressure of liquids and liquid mixtures” Ph.D. Thesis in Chemistry, Annamalai University, Annamalainagar (1998).
- [11] A. P. Srivastava, S. N. Dubey, Acoustics Lett. 8(11) (1985) 191.
- [12] T. M. Aminabhavi, et al., Indian J. Technol. 31 (1993) 27.
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- [14] N. Manohara Murthy, G. Nagabhushanam, Acustica 54 (1984) 225.
- [15] V. Hyder Khan, G. Ravindranath, J. Anjaneyulu, Acustica 71 (1990) 14.
- [16] G. Nagabhushanam, N. Manohara Murthy, Acustica 65 (1988) 295.
- [17] R. L. Blokhra, R. Kumar, Acustica 68 (1989) 161.
- [18] K. Malakondaiah, S. V. Subramanyam, Acoustics Lett. 11(3) (1987) 48.
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BPS2-0066-0034