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A series containing twelve substituted styryl 2-phenothiazenyl ketones have been synthesized. The electrochemical potentials of carbonyl and vinyl groups were measured. These potentials are correlated with Hammett substituent constants, F and R parameters. From the results of statistical analyses, the effects of substituent on the group reduction potentials have been discussed. The insect antifeedant activities of these chalcones have been studied using 4th instar larvae Achoea Janata L with castor leaf discs.
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Tom
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66--75
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
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- Post Graduate and Research Department of Chemistry, Government Arts College, C-Mutlur-608102, Chidambaram, India., drgtnarayanan@gmail.com
Bibliografia
- [1] Zuman P, Substituent Effects in Organic Polarography, Plenum Press, New-York. 1967.
- [2] Boykin D W, Ash M L, Berin F L O, J. Org. Chem., 1972, 37(1), 106-110.
- [3] Alston J A, Fry A J, Electrochim. Acta., 49(3), (2004) 455-459.
- [4] Morealeda D, Abed D E, Pellissier H, Santelli M, J. Mol. Struct.(TheoChem). 760(1-3), (2006) 113-119.
- [5] (a). Arulkumaran R, Vijayakumar S, Sundararajan R, Sakthinathan S P, Kamalakkannan D, Suresh R, Ranganathan K, Vanangamudi G, Thirunarayanan G, Int. Lett. Chem. Phys. Astro. 4 (2012)17-38. (b). Sivakumar M, Phrabu sreeneivasan S, Kumar V, Doble M, Bioorg. Med. Chem. Lett. 17(10), (2007) 3169-3172.
- [6] Lahtchev K L, Batovska D I, Parushev St P, Ubiyvock V M, Sibirny A A, Eur. J. Med. Chem. 43(10), (2008) 2220-2228.
- [7] El-Subbagh Hussein I, Abu-Zaid S M, Mahran M A, Badria Farid A, Al-Obaid A M, J. Med. Chem., 43 (2000) 2915-2920.
- [8] Thirunarayanan G, Surya S, Srinivasan S, Vanangamudi G, Sathyendiran V, Spectrochim. Acta Part A., 75 (2010) 152-156.
- [9] Deng J, Sanchez T and Lalith Q A M, Bioorg. Med. Chem.15(14), (2007) 4985-5002.
- [10] Lin Y M, Zhon Y, Flavin M T, Zhon M, Ne W, Chen F C, Bioorg. Med. Chem. 10(8), (2002) 2795-2802.
- [11] Weber M W, Hunsaker L A, Abcouwer S F, Decker L M, Vander Jagat D L, Bioorg. Med. Chem. 13 (2005) 3811-3820.
- [12] Arulkumaran R, Sundararajan R, Vanangamudi G, Subramanian M, Ravi K, Sathiyendiran V, Srinivasan S, Thirunarayanan G, IUP. J. Chem., 3(1), (2010) 82-98.
- [13] Thirunarayanan G, Vanangamudi G, Spectrochim. Acta., 2011, 81A, 390-396.
- [14] Thirunarayanan G, J. Indian Chem. Soc., 85(4), (2008) 447-451.
- [15] Ranganthan K, Arulkumaran K, Kamalakannan D, Vanangamudi G, Thirunarayanan G, Iup. J. Chem., 4(2), (2011) 60-70.
- [16] Thirunarayanan G, Vanangamudi G, Sathiyendiran V, Ravi K, Indian J. Chem., 50B(4), (2011) 593-604.
- [17] Thirunarayanan G, IUP. J. Chem.,. 5(1), (2012) 41-53.
- [18] Swain C G, Lupton Jr E C, J. Am. Chem. Soc., 90(16), (1968) 4328-4337.
- [19] Dethler V G, Chemical insect attractants and repellents, Blackistan, Philadeciphia, 1947.
- [20] Thirunarayanan G, J. Saudhi Chem Soc., 2011, doi10.1016/j.jscs.2011.12.003.
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BPS2-0066-0025