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Synthesis, characterization and analytical applications of chelating resin containing orcinol

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A chelating resin based on Salicylic acid-Formaldehyde copolymer, containing Orcinol (SFO), has been synthesized and characterized on the basis of Elemental Analysis, Particle Size Distribution, FT-IR Analysis, XRD, SEM and Optical Photographs. The Physico-Chemical properties have been studied. This resin is highly stable in acidic and alkaline solutions and has been studied as a chelating sorbent for heavy metal ions and transition metal ions. The Exchange capacity order is Ni(II) > Cu(II) > Zn(II) > Cd(II) > Pb(II). The effect of nature and concentration of different electrolytes on distribution coefficient (Kd) for metal ions have been investigated. Separation of synthetic mixtures containing Cu(II)-Pb(II), Ni(II)-Cd(II) and Brass constituents has been carried out using a column prepared from the synthesized chelating resin. The developed procedure was also tested for the removal of Cd(II) and Pb(II) from natural water of Purna River near by Navsari, Gujarat, India. Keywords
Rocznik
Strony
88--96
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
Twórcy
autor
autor
autor
autor
  • Department of Chemistry, Veer Narmad South Gujarat University, Swat, Gujarat, India, bhavna606@gmail.com
Bibliografia
  • 1. Rao, G.P.C., Rao, M.M., & Veni, S.S. (2006). Preconcentration of total chromium on Dowex 50WX8 resin loaded with 2-amino-benzenethiol. International Journal of Environmental Analytical Chemistry.86 (14), 1095–1103. DOI:10.1080/03067310600847369.
  • 2. Cheng, C., Jin, N.W., Li, X, & Ai M.L. (2012). Preparation of new hyper cross-linked chelating resin for adsorption of Cu2+ and Ni2+ from water. Chinese Chemical Letters.23(2), 245–248. DOI:10.1016/j.cclet.2011.10.019.
  • 3. Chandra, D., Kumar, D.S., & Bhaumik, A. (2010). A fluorophore grafted 2D-hexagonal mesoporous organosilica: excellent ion exchanger for the removal of heavy metal ions from wastewater. Microporous Mesoporous Material.128, 34–40. DOI:10.1016/j.micromeso.2009.07. 024.
  • 4. Park, I.H., & Kim, K.M. (2005). Preparation of chelating resins containing a pair of neighboring carboxylic acid groups and the adsorption characteristics for heavy metalions. Separation Science and Technology. 40, 2963–2986. DOI:10.1080/01496390500338060.
  • 5. Gurnule, W.B., & Patel, D.B. (2011). Metal ion binding properties of a copolymer resin: synthesis, characterization, and its applications. Polymer bulletin. 66, 803–820. DOI 10.1007 /s00289-010-0385-8.
  • 6. Singh, D.K., & Srivastava, M. (2006). Synthesis Characteristic and Analytical Applications of New chelating resin containing p-Bromophenylhydromaxic acid. Journal of Liquid Chromatography & Related Technologies. 29(10), 1433–1440. DOI: 10.1080/10826070600674828.
  • 7. Mohan, S., & Sreelakshmi, G. (2008). Fixed bed column study for heavy metal removal using phosphate treated rice husk. Journal of Hazardous Material. 153, 75–82. DOI: 10.1016/j.jhazmat.2007.08.021.
  • 8. Dogan, C.E. & Akcin, G. (2007). Solid phase extraction and determination of lead in water sample using silica gel homogeneously modifi ed by thiosalicylic acid. Analytical Letter. 40(13), 2524–2543. DOI: 10.1080/00032710701585016.
  • 9. Helfferich, F (1962). Ion Exchange Resin. McGraw Hills, New York.
  • 10. Kunin, R. (1958). Ion Exchange Resin. (2nd edition) Wiley London.
  • 11. Vogel, S. (2009). Textbook of Qualitative Chemical Analysis. 6th edition Cambridge University Press, Cambridge.
  • 12. Shah, B.A., Shah, A.V., & Shah, P.M. (2008). Metal ions uptake by chelating resin derived from o-substituted benzoic acid and its synthesis, characterization and properties. Macromolecular Symposia. 274, 81–90. DOI: 10.1002/masy.200851412.
  • 13. Sun, C., Qu, R., Ji, C., Wang, Q., Sun, Y., & Cheng, G. (2006). A chelating resin containing S, N and O atoms: Synthesis and adsorption properties for Hg(II). European Polymer Journal. 42(1), 188–194. DOI: 10.1016/j.eurpolymj.2005.06.024.
  • 14. Samal, S., Acharya, S., Dey, R.K., & Ray, A.R. (2003). Synthesis, characterization and metal ion uptake studies of chelating resin derived from formaldehyde / furfuraldehyde condensed phenolic schiff base of 4, 4’-diaminophenylmethane and o hydroxyacetophenone. Journal of Applied Polymer Science. 88 (2), 570–581. DOI: 10.1002/app.11715.
  • 15. Shah, B.A., Shah, A.V., & Patel, N.B. (2008). A benign approach of microwave assisted synthesis of copolymer with improved thermal, spectral and ion exchange properties. Iranian Polymer Journal.17 (1), 3–17. http://journal.ippi.ac.ir/journals.php?tab=1&v=17&n=1.
  • 16. Shah, B.A., Shah, A.V., & Shah, P.M. (2010). Selectivesorption of heavy metal ions from aqueous solutions using m-cresol based chelating resin and its analytical applications. Iranian Journal of Chemistry and Chemical Engineering 29(2), 49–58. http:// www. sid.ir/en/ VEWSSID /J_ pdf/84320105407.pdf.
  • 17. Bhatt, R.R., & Shah, B.A. (2007). Studies of Chelation Ion-exchange Properties of Copolymer Resin Derived fromSalicylic Acid and its Analytical Applications Iranian polimer journal.16 (3), 173–184. http://journal.ippi.ac.ir/journals.php?tab= 1&v=16&n=3.
  • 18. Rivas, B.R., Peric, I.M., & Villegas, S. (2010). Synthesis and metal ion uptake properties of water-insoluble functional copolymers: removal of metal ions with environmental impact. Polymer Bulletin.65 (9), 917–928. DOI: 10.1007/s00289-010-0304-z.
  • 19. Demirbas, A., Pehivan, E., Gode, F., Altun, T., & Arslan, G. (2005). Adsorption of Cu(II), Zn(II), Ni(II),Pb(II) and Cd(II) from aqueous solution on Amberlite IR-120 synthetic resin. Journal of Colloid and Interface Science. 282:20-25. DOI: 10.1016/j.jcis.2004.08.147.
  • 20. Bajpal, A.K., & Rai, L. (2010). Removal of chromium ion from aqueous solution by biosorption on to ternary biopolimer microspheres. Indian Journal of Chemical Technology. 17:17-27. http://nopr.niscair.res.in/bitstream/123456789/7271/1/IJCT%2017%281%29%2017-27.pdf.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0065-0050
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