Influence of e-beam irradiation on the chemical and crystal structure of poly(aliphatic/aromatic-ester) multiblock thermoplastic elastomers

• Autorzy: El Fray M. , Piątek-Hnat M. , Puskas J. E. , Foreman-Orlowski E.
• Języki publikacji: EN

Abstrakty

EN

Poly(aliphatic/aromatic-ester) (PED) multiblock copolymers belong to the class of thermoplastic elastomers (TPEs), characterized by a physical network of semi-crystalline hard segments. The PEDs were modified with e-beam to create an additional network structure. Polymers were evaluated using SEC, WAXS, DSC and quasi-static tensile tests. E-beam irradiation induced a significant increase of molecular weight and tensile strength of the PEDs. This effect, together with the diminished degree of crystallinity can be explained by the formation of chemical crosslinks, which are located in the hard phase segments.

Słowa kluczowe

EN

biopolymers; thermoplastic elastomers; e-beam irradiation; multiblock polyesters; DSC

PL

biopolimery; elastomery termoplastyczne; poliestry multiblokowe; DSC

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2012
• Tom: Vol. 14, nr 2
• Strony: 70--74
• Opis fizyczny: Bibliogr. 11 poz., rys., tab.

Twórcy

autor

El Fray M.

autor

Piątek-Hnat M.

autor

Puskas J. E.

autor

Foreman-Orlowski E.

• Biomaterials and Microbiological Technologies, West Pomeranian University of Technology, Szczecin, ul Pulaskiego 10, 70-322 Szczecin, Poland,

Bibliografia

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