Novel catalytic method synthesis of calix[4]pyrroles using Preyssler and Wells-Dawson heteropolyacids

• Autorzy: Gharib A. , Jahangir M. , Scheeren J.(H.)W.
• Języki publikacji: EN

Abstrakty

EN

A catalytic synthesis of calix[4]pyrroles and N-confused calix[4]pyrroles by reaction of dialkyl or cycloalkyl ketones with pyrrole was performed using Preyssler, sodium30-tungsto pentaphosphate, [NaP5W30O110]14- and Wells-Dawson heteropolyacids as acidic catalysts. The process occurred under mild, eco-friendly and environmental friendly conditions and as a reusable, green catalyst at room temperature for 6 hours. The results showed that the yield for this synthesis is excellent with the use of Preyssler and Wells-Dawson type tungstophosphoric heteropolyacid, H6[P2W18O62], catalysts. The synthesis reaction of calix[4]pyrroles and N-confused calix[4]pyrroles was developed using different solvents and the best yields were obtained in chloroform.

Słowa kluczowe

EN

calix[4]pyrrole; heteropoly acid; Preyssler; Wells-Dawson; catalysis; N-confused calix[4]pyrrole

PL

kaliks[4]pirole; heteropolikwasy; kataliza

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2011
• Tom: Vol. 13, nr 2
• Strony: 70--73
• Opis fizyczny: Bibliogr. 25 poz., schem., tab.

Twórcy

autor

Gharib A.

autor

Jahangir M.

autor

Scheeren J.(H.)W.

• Department of Chemistry, Islamic Azad University, Mashhad, IRAN,

Bibliografia

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