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Results of pervaporation (PV) of sucrose and calcium chloride spent solutions were presented. Additionally, osmotic membrane distillation (OMD) of sucrose solutions was investigated. It was found that the regeneration of spent sucrose solution for the reuse is possible by using PV or OMD processes. However, OMD process produces another spent stream i.e. CaCl2. Pervaporation membranes showed fluxes in the range of 0.5 - 0.9 kg m^-2 h^-1 in contact with 40° Brix sucrose solution, whereas OMD water permeate fluxes were in the range of 4 - 5 kg m^-2 h^-1 for the same feed concentration. Two different hybrid processes were suggested: i) pretreatment followed by OMD reconcentration of spent sucrose solution and independently PV for CaCl2 regeneration; ii) membrane pretreatment (MP) followed by PV of sucrose solution. Based on the experimental results, the membrane areas for both systems were calculated and compared. MP-PV system seems to be a better solution for the spent mixtures management.
Czasopismo
Rocznik
Tom
Strony
41--45
Opis fizyczny
Bibliogr. 22 poz., rys.
Twórcy
autor
autor
autor
autor
- Nicolaus Copernicus University, Faculty of Chemistry, ul. Gagarina 7, 87-100 Toruń, kujawski@chem.umk.pl
Bibliografia
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- 3. Marouzé, C., Giroux, F., Collignan, A. & Rivier, M. (2001). Equipment design for osmotic treatments. J. Food Eng. 49, 207-221.
- 4. Gallart-Jornet, L., Barat, J. M., Rustad, T., Erikson, U., Escriche, I. & Fito, P. (2007). A comparative study of brine salting of Atlantic cod (Gadus morhua) and Atlantic salmon (Salmo salar). J. Food Eng. 79, 261-270. DOI: 10.1016/j.jfoodeng.2006.01.053.
- 5. Bellagha, S., Sahli, A., Farhat, A., Kechaou, N. & Glenza, A. (2007). Studies on salting and drying of sardine (Sardinella aurita): Experimental kinetics and modeling. J. Food Eng. 78, 947-952. DOI: 10.1016/j.jfoodeng.2005.12.008.
- 6. Emam-Djomeh, Z., Djelveh, G. & Gros, J.-B. (2001). Osmotic dehydration of foods in a multicomponent solution. Part I. Lowering of solute uptake in agar gels: diffusion considerations. Lebensm.-Wiss. u.-Technol. 34, 312-318. DOI: 10.1006/fstl.2001.0776.
- 7. Dalla Rosa, M. & Giroux, F. (2001). Osmotic treatments (OT) and problems related to the solution management. J. Food Eng. 49, 223-236.
- 8. Moreira, R., Chenlo, F. & Pereira, G. (2003). Viscosities of ternary aqueous solutions with glucose and sodium chloride employed in osmotic dehydration operation. J. Food Eng. 57, 173-177.
- 9. Rastogi, N. K., Raghavarao, K. S. M. S., Niranjan, K. & Knorr, K. (2002). Recent developments in osmotic dehydration: methods to enhance mass transfer. Trends Food Sci. Technol. 13, 48-59.
- 10. Kumar, A., Croteau, S. & Kutowy, O. (1999). Use of membranes for energy effcient concentration of dilute streams. Appl. Energy 64, 107-115.
- 11. Cuperus, F. P. (1998). Membrane processes in agrofood. State-of-the-art and new opportunities. Sep. Purif. Technol. 14, 233-239.
- 12. Scordino, M., Di Mauro, A., Passerini, A. & Maccarone, E. (2007). Highly purified sugar concentrate from a residue of citrus pigments recovery process. LWT - Food Sci. Technol. 40, 713-721. DOI: 10.1016/j.lwt.2006.03.007.
- 13. Warczok, J., Ferrando, M., López, F., Pihlajamäki, A. & Güell, C. (2007). Reconcentration of spent solutions from osmotic dehydration using direct osmosis in two configurations. J. Food Eng. 80, 317-326. DOI: 10.1016/j.jfoodeng.2006.06.003.
- 14. Warczok, J., Gierszewska, M., Kujawski, W. & Güell, C. (2007). Application of osmotic membrane distillation for reconcentration of sugar solutions from osmotic dehydration. Sep. Purif. Technol. 57, 425-429. DOI: 10.1016/j.seppur.2006.04.012.
- 15. Romero Barranco, C., Brenes Balbuena, M., García García, P. & Garrido Fernández, A. (2001). Management of spent brines or osmotic solutions. J. Food Eng. 49, 237-246.
- 16. Shao, P. & Huang, R. Y. M. (2007). Review. Polymeric membrane pervaporation. J. Membr. Sci. 287, 162-179. DOI:10.1016/j.memsci.2006.10.043.
- 17. Gryta, M. (2005). Osmotic MD and other membrane distillation variants. J. Membr. Sci. 246, 145-156. DOI:10.1016/j.memsci.2004.07.029.
- 18. Bessarabov, D. & Twardowski, Z. (2006). New opportunities for osmotic membrane distillation. Membr. Technol. 2006, 7-11.
- 19. Kujawski, W. & Krajewski, S. R. (2007). Influence of inorganic salt on the effectiveness of liquid mixtures separation by pervaporation. Sep. Purif. Technol. 57, 495-501. DOI:10.1016/j.seppur.2006.09.020.
- 20. Timmermans, J. (Ed.) (1960). The Physico-chemical Constans of Binary Systems in Concentrated Solutions. Vol 4. Systems with inorganic + organic or inorganic compounds. New York, USA: Interscience Publishers Inc.
- 21. Meites, L. (Ed.) (1963). Handbook of Analytical Chemistry. New York, USA: McGraw-Hill Book Company Inc.
- 22. Chapman, P. D., Oliveira, T., Livingston, A. G. & Li, K. (2008). Review. Membranes for the dehydration of solvents by pervaporation. J. Membr. Sci. 318, 5-37. DOI:10.1016/j.memsci.2008.02.061.
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Bibliografia
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