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Warianty tytułu
Języki publikacji
Abstrakty
This paper presents the effects of mixing on the course of complex chemical reactions in relation to the manufacturing of pure products at high reaction selectivity, and designing mixing strategies using complex, homogeneous test reaction systems. As an example, the competitive-consecutive and parallel reaction test system including a simultaneous diazo-coupling between 1- and 2-naphtols and diazotized sulphanilic acid is considered. The effect of mixing on the reaction selectivity is interpreted using mechanistic modeling and a new closure scheme. The new closure represents an extension of the conditional PDF closure applied before to simple reaction schemes.
Czasopismo
Rocznik
Tom
Strony
1--5
Opis fizyczny
Bibliogr. 4 poz., rys.
Twórcy
autor
autor
- Warsaw University of Technology, Faculty of Chemical and Process Engineering, ul. Waryńskiego 1, 00-645 Warszawa, baldyga@ichip.pw.edu.pl
Bibliografia
- 1. Bałdyga, J. & Bourne, J.R. (1999). Turbulent mixing and chemical reactions. Chichester: Wiley.
- 2. Bałdyga, J., Henczka, M. & Makowski, Ł. (2001). Effects of mixing on parallel chemical reactions in a continuousflow stirred-tank reactor. Trans IChemE. 79, 895-900. DOI: 10.1205/02638760152721109
- 3. Bałdyga, J., Kowalski, A., Cooke, M. & Jasińska, M. (2007). Investigations of micromixing in a rotor-stator mixer. Chemical and Proces Engineering. 28, 867-877.
- 4. Bourne, J.R., Kut, O.M., Lenzner, J. & Maire, H. (1990). Kinetics of diazo coupling between 1-naphtol and diazotized sulphanilic acid. Ind. Eng. Chem. Res., 29, 1761-1765. DOI: 10.1021/ie00105a004
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0052-0074