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The aim of the presented work was the removal of organic dye, Acid Red 18, from water using a novel reactor with the photoactive refill. Titanium dioxide was immobilized on the base material as a thin layer from the alcoholic suspension followed by thermal stabilization. The prepared coating exhibits high stability in repeated cycles of water treatment. The complete removal of colour was achieved in a relatively short time of 14 hours. The proposed reactor with the photoactive refill solves the problem of the necessity of the replacement of the reactor or parts of the reactor when the photocatalysts activity decreases. In the case of activity drop of the photocatalyst, only the photoactivve refill can be easily replaced.
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61--63
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Bibliogr. 11 poz., rys.
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autor
- Institute of Chemical and Environment Engineering, West Pomeranian University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, joanna.grzechulska@ps.pl
Bibliografia
- 1. Hoffman, M.R., Martin, S.T., Choi, W. & Bahnemann, D.W. (1995). Environmental Applications of semiconductor Photocatalysis. Chem. Rev. 95(1), 69 - 91. DOI: 10.1021/cr00033a004
- 2. Linsebigler, A.L., Lu, G. & Yates, Jr.J.T. (1995) Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results. Chem. Rev. 95(3), 735 - 758. DOI: 10.1021/cr00035a013
- 3. Schiavello, M. (1997). Heterogeneous photocatalysis. John Willey & Sons, Chichester, New York, Wienheim, Brisbane, Singapore, Toronto.
- 4. Mills, A. & LeHunte, S. (1997). An overview of semi-conductor photocatalysis. J. Photochem. Photobiol. A: Chem. 108(1), 1 - 35. DOI: 10.1016/S1010-6030(97)00118-4
- 5. Herrmann, J.-M. (1999). Heterogeneous photocatalysis: fundamentals and applications to the removal of various types of aqueous pollutants. Catal. Today 53(1), 115 - 129. DOI: 10.1016/S0920-5861(99)00107-8
- 6. Fujishima, A., Rao, T.N. & Tryk, D. (2000). Titanium dioxide photocatalysis. J. Photochem. Photobiol. C: Photochem. Rev. 1(1), 1 - 21. DOI: 10.1016/S1389-5567(00)00002-2
- 7. Kaneko, M. & Okura, I. (2002). Photocatalysis. Sc ience and Technology. Kodansha Ltd., Tokyo, Springer-Verlag Berlin Heidelberg, New York.
- 8. Fernández, A., Lassaletta, G., Jiménez, V.M., Justo, A., González-Elipe, A.R., Herrmann, J.-M., Tahiri, H. & Ait-Ichou, Y. (1995). Preparation and characterization of TiO2 photocatalysts supported on various rigid supports (glass, quartz and stainless steel). Comparative studies of photocatalytic activity in water purification. Appl. Catal. B: Environ. 7(1-2), 49 - 63. DOI: 10.1016/0926-3373(95)00026-7
- 9. Grzechulska, J. & Morawski, A.W. (2003). Photocatalytic labyrinth flow reactor with immobilized P25 TiO2 bed for removal of phenol from water. Appl. Catal. B: Environ. 46(2), 415 - 419. DOI: 10.1016/S0926-3373(03)00265-0
- 10. Balasubramanian, G., Dionysiou, D.D., Suidan, M.T., Baudin, I. & Laîné, J.-M., Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation of organic contaminants in water. (2004). Appl. Catal. B: Environ. 47(2), 73 - 84. DOI: 10.1016/j.apcatb.2003.04.002
- 11. Venkata Subba Rao, K., Subrahmanyam, M. & Boule, P. (2004). Immobilized TiO2 photocatalyst during long-term use: decrease of its activity. Appl. Catal. B: Environ. 49(4), 239 - 249. DOI: 10.1016/j.apcatb.2003.12.017.
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BPS2-0050-0071