Epoksydacja związków allilowych nadtlenkiem wodoru w obecności katalizatorów tytanowo-silikalitowych

Wróblewska, A.

Artykuł - szczegóły

Tytuł artykułu

Epoksydacja związków allilowych nadtlenkiem wodoru w obecności katalizatorów tytanowo-silikalitowych

Autorzy

Wróblewska A.

Identyfikatory

Warianty tytułu

Epoxidation of allylic compounds with hydrogen peroxide over titanium silicalite catalysts

Języki publikacji

Abstrakty

The results for epoxidation of allylic compounds: allyl alcohol, methallyl alcohol, methallyl chloride, 2-buten-1-ol and 1-buten-3-ol with 30% hydrogen peroxide were presented. The epoxidations were performed over earlier obtained titanium silicalite catalysts: microporous (TS-1, TS-2 and Ti-Beta) and mesoporous (Ti-MCM-41 and Ti-MCM-48). There were applied two methods of epoxidation: at increased pressure (autogenic pressure) in autoclave and at atmospheric pressure in glass reactor. At the beginning for each compound there were performed preliminary investigations. It was done by experimental investigations of the influence of each independent factor (parameter) on the course of the process at constant values remaining independent factors. The influence of the following technological parameters was investigated: temperature, the molar ratio allylic compound/hydrogen peroxide, methanol concentration (solvent), catalyst concentration and the reaction time. On the basis of these investigations the best technological parameters of epoxidation for each allylic compound not only at autogenic, but also at atmospheric pressure were established. These results were generalized and the general dependences for epoxidation of allylic compounds over titanium silicalite catalysts were presented. Than the correction of preliminary established ranges of process parameters for selected allylic compounds was made and next there were performed for them the optimizations with help of mathematical method of experimental planning (rotatable-uniform design). The established optimal parameters were close to the best parameters obtained in preliminary investigations, but the best parameters of the process usually allowed to carry out the process in milder conditions at the same or close values functions describing the process. The comparison between the methods at atmospheric pressure and autogenic pressure showed a lot of similarities in course of both processes - the similarity in values not only the best parameters but also the functions describing the process. Although the pressure method allowed to perform the process in broader range of temperature and pressure, the method at atmospheric pressure was chosen as the best. The method needs lower capital spending connected with performing of the process. At the end of this work there was proposed the simplified technological scheme of epoxides production, it took also into consideration the stage of products separation and regeneration of catalyst.

Słowa kluczowe

katalizatory tytanowo-silikalitowe epoksydy epoksydacja

epoxides catalysts

Wydawca

Wydawnictwo Uczelniane Politechniki Szczecińskiej

Czasopismo

Prace Naukowe Politechniki Szczecińskiej. Instytut Technologii Chemicznej Organicznej

Rocznik

2008

Tom

Nr 608 (5)

Strony

5--116

Opis fizyczny

Bibliogr. 246 poz., rys., tab.

Twórcy

autor

Wróblewska A.

Instytut Technologii Chemicznej Organicznej Politechniki Szczecińskiej

Bibliografia

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